[C{sub 2}N{sub 2}H{sub 10}]{sub 1.5}[Nd(SO{sub 4}){sub 3}(H{sub 2}O)].2H{sub 2}O: The first organically templated neodymium sulfate with a layer structure
- State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)
The first organically templated neodymium sulfate has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction analysis. [C{sub 2}N{sub 2}H{sub 10}]{sub 1.5}[Nd(SO{sub 4}){sub 3}(H{sub 2}O)].2H{sub 2}O crystallizes in the monoclinic space group P2{sub 1}/c with crystal data a=6.5896(5)A, b=26.539(3)A, c=9.9889(8)A, {beta}=104.399(5){sup o}, V=1692.0(2)A{sup 3}, Z=4. Refinement gave R{sub 1}[I>2{sigma}(I)]=0.0471, and wR{sub 2}[I>2{sigma}(I)]=0.0899. The compound exhibits an infinite zigzag anionic layer structure, which consists of {l_brace}Nd(SO{sub 4}){sub 3}(H{sub 2}O){r_brace}{sup 3-} structural units connected together to form interesting eight-membered rings via corner-sharing and edge-sharing modes. The compound has the antiferromagnetic behavior and exhibits intense photoluminescence upon photo-excitation at 450nm.
- OSTI ID:
- 20725865
- Journal Information:
- Journal of Solid State Chemistry, Vol. 178, Issue 4; Other Information: DOI: 10.1016/j.jssc.2004.11.019; PII: S0022-4596(04)00625-5; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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