A novel hybrid crystal of chiral racemic complexes coexisting with two kinds of polyoxomolybdates: synthesis and structure of [Co(bpy){sub 3}]{sub 2}[Mo{sub 6}O{sub 19}] [{beta}-(H{sub 2}Mo{sub 8}O{sub 26})].4H{sub 2}O
Journal Article
·
· Journal of Solid State Chemistry
- Department of Chemistry, Northeast Normal University, Number 138, Renmin Street, Changchun City, Jilin province 130024 (China)
- State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Physical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)
A novel polyoxometalate-based organic-inorganic hybrid compound, [Co(bpy){sub 3}]{sub 2} [Mo{sub 6}O{sub 19}] [{beta}-(H{sub 2}Mo{sub 8}O{sub 26})].4H{sub 2}O (1), have been hydrothermally synthesized and structurally characterized by elemental analysis, single-crystal X-ray diffraction, IR and X-ray photoelectron spectra. Compound 1 represents the first example that racemic complexes coexisting with two kinds of polyoxomolybdate anions in the same crystal architecture, which should be of rare chance that four kinds of complexes crystallizes into a compound.
- OSTI ID:
- 20725813
- Journal Information:
- Journal of Solid State Chemistry, Vol. 178, Issue 3; Other Information: DOI: 10.1016/j.jssc.2004.11.034; PII: S0022-4596(04)00631-0; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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