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Incorporation of nonadiabatic transition into wave-packet dynamics

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.2074457· OSTI ID:20723155
; ;  [1]
  1. Department of Theoretical Studies, Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan)
Nonadiabatic wave-packet dynamics is factorized into purely adiabatic propagation and instantaneous localized nonadiabatic transition. A general formula is derived for the quantum-mechanical local nonadiabatic operator which is implemented within the framework of the R-matrix method. The operator can be used for incorporating the nonadiabatic transition in semiclassical wave-packet dynamics.
OSTI ID:
20723155
Journal Information:
Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 14 Vol. 123; ISSN JCPSA6; ISSN 0021-9606
Country of Publication:
United States
Language:
English

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