skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Tunable thermal expansion behavior in the intermetallic YbGaGe

Journal Article · · Physical Review. B, Condensed Matter and Materials Physics
; ; ; ; ; ; ; ;  [1]
  1. Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

We investigate the effects of carbon and boron doping on the thermal expansion of the hexagonal (P6{sub 3}/mmc) intermetallic YbGaGe. X-ray powder diffraction was used to measure the lattice constants on pure and doped (C or B at nominal levels of 0.5%) samples from T{approx}10 K to T{approx}300 K. Also measured were resistivity, specific heat, and magnetic susceptibility. While the pure YbGaGe samples exhibit positive thermal volume expansion (V{sub 300K}-V{sub 10K})/V{sub 300K}=0.94, the volume expansion in the lightly C- or B-doped samples changes slope and tends toward zero-volume expansion. Such a strong response to light doping suggests that the underlying mechanism for the reported zero-volume expansion is substitutional disorder, and not the previously proposed valence fluctuations.

OSTI ID:
20718993
Journal Information:
Physical Review. B, Condensed Matter and Materials Physics, Vol. 71, Issue 17; Other Information: DOI: 10.1103/PhysRevB.71.174304; (c) 2005 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1098-0121
Country of Publication:
United States
Language:
English