The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation

Journal Article · Thu Sep 01 04:00:00 EDT 2005 · Cement and Concrete Research

DOI:https://doi.org/10.1016/j.cemconres.2004.10.042· OSTI ID:20706231

Yip, C K ^[1]; Lukey, G C ^[1]

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1. Department of Chemical and Biomolecular Engineering, University of Melbourne, Victoria 3010 (Australia)

Scanning electron microscopy was used to study the effects of the addition of ground granulated blast furnace slag (GGBFS) on the microstructure and mechanical properties of metakaolin (MK) based geopolymers. It was found that it is possible to have geopolymeric gel and calcium silicate hydrate (CSH) gel forming simultaneously within a single binder. The coexistence of these two phases is dependent on the alkalinity of the alkali activator and the MK / GGBFS mass ratio. It has been found that the formation of CSH gel together with the geopolymeric gel occurs only in a system at low alkalinity. In the presence of high concentrations of NaOH (> 7.5 M), the geopolymeric gel is the predominant phase formed with small calcium precipitates scattered within the binder. The coexistence of the two phases is not observed unless a substantial amount of a reactive calcium source is present initially. It is thought that voids and pores within the geopolymeric binder become filled with the CSH gel. This helps to bridge the gaps between the different hydrated phases and unreacted particles; thereby resulting in the observed increase in mechanical strength for these binders.

• OSTI ID: 20706231
• Journal Information: Cement and Concrete Research, Journal Name: Cement and Concrete Research Journal Issue: 9 Vol. 35; ISSN 0008-8846; ISSN CCNRAI
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ACID NEUTRALIZING CAPACITY
BINDERS
BLAST FURNACES
CALCIUM SILICATES
GELS
HYDRATES
MECHANICAL PROPERTIES
MICROSTRUCTURE
SCANNING ELECTRON MICROSCOPY
SLAGS
SODIUM HYDROXIDES
VOIDS