Spatiotemporal Studies of Soluble Inorganic Nanostructures with X‐rays and Neutrons

Yin, Jia‐Fu; Amidani, Lucia; Chen, Jiadong; Li, Mu; Xue, Binghui; Lai, Yuyan; Kvashnina, Kristina; Nyman, May; Yin, Panchao

doi:10.1002/ange.202310953

Spatiotemporal Studies of Soluble Inorganic Nanostructures with X‐rays and Neutrons

Journal Article · Tue Oct 10 00:00:00 EDT 2023 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.202310953· OSTI ID:2067629

Yin, Jia‐Fu ^[1]; Amidani, Lucia ^[2]; Chen, Jiadong ^[1]; Li, Mu ^[3]; Xue, Binghui ^[1]; Lai, Yuyan ^[1]; Kvashnina, Kristina ^[2]; Nyman, May ^[4]; ^[1]

State Key Laboratory of Luminescent Materials and Devices South China Advanced Institute for Soft Matter Science and Technology South China University of Technology Guangzhou 510640 China
The Rossendorf Beamline at ESRF The European Synchrotron CS40220, 38043 Grenoble Cedex 9 France, Institute of Resource Ecology Helmholtz Zentrum Dresden-Rossendorf (HZDR) P.O. Box 510119 01314 Dresden Germany
Institute of Advanced Science Facilities Shenzhen 518107 China
Department of Chemistry Oregon State University Corvallis OR, 97330 USA

Abstract

This Review addresses the use of X‐ray and neutron scattering as well as X‐ray absorption to describe how inorganic nanostructured materials assemble, evolve, and function in solution. We first provide an overview of techniques and instrumentation (both large user facilities and benchtop). We review recent studies of soluble inorganic nanostructure assembly, covering the disciplines of materials synthesis, processes in nature, nuclear materials, and the widely applicable fundamental processes of hydrophobic interactions and ion pairing. Reviewed studies cover size regimes and length scales ranging from sub‐Ångström (coordination chemistry and ion pairing) to several nanometers (molecular clusters, i.e. polyoxometalates, polyoxocations, and metal‐organic polyhedra), to the mesoscale (supramolecular assembly processes). Reviewed studies predominantly exploit 1) SAXS/WAXS/SANS (small‐ and wide‐angle X‐ray or neutron scattering), 2) PDF (pair‐distribution function analysis of X‐ray total scattering), and 3) XANES and EXAFS (X‐ray absorption near‐edge structure and extended X‐ray absorption fine structure, respectively). While the scattering techniques provide structural information, X‐ray absorption yields the oxidation state in addition to the local coordination. Our goal for this Review is to provide information and inspiration for the inorganic/materials science communities that may benefit from elucidating the role of solution speciation in natural and synthetic processes.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0010802

OSTI ID:: 2067629

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 1 Vol. 136; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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