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Electron and positron scattering from perfluorocyclobutane (c-C{sub 4}F{sub 8}) molecules

Journal Article · · Physical Review. A
 [1];  [2];  [1]; ;  [3]
  1. Graduate School of Sciences, Kyushu University, Fukuoka 812-8581 (Japan)
  2. Department of Applied Science, Yamaguchi University, Ube 755-8611 (Japan)
  3. Physics Department, Sofia University, Chiyoda-ku, Tokyo 102-8554 (Japan)

Total cross sections (TCSs) are experimentally investigated for 0.8-600-eV electron and 0.7-600-eV positron scattering from c-C{sub 4}F{sub 8} molecules using a linear transmission time-of-flight method, and a comparative study of the results is carried out in this paper. Electron-scattering differential cross sections (DCS) measurements carried out for energies 1.5-100 eV are used for a combined TCS and DCS discussion. These DCS results help to offer a better understanding of some of the structures observed in the TCSs. Fingerprints of a low-energy resonance, consistent with large electron attachment cross sections near 0 eV, have been observed below 2 eV where TCSs show a continually rising trend. Another resonance peak at {approx}8.5 eV, attributed to dissociative electron attachment with the production of fragmented ions, and a broader one at 16-40 eV, have also been observed. Except for the pronounced shoulder at {approx}40 eV, there is good qualitative agreement between the TCS result and the integrated cross-section results. Although electron TCSs are found to be generally larger than positron TCSs in the 3-120-eV ranges, these two TCSs, however, show a tendency towards merging above 120 eV.

OSTI ID:
20650420
Journal Information:
Physical Review. A, Journal Name: Physical Review. A Journal Issue: 3 Vol. 71; ISSN 1050-2947; ISSN PLRAAN
Country of Publication:
United States
Language:
English