Effects of the open-shell electronic structure in 4d photoionization and Auger decay of atomic Sn

Journal Article · Thu Jan 01 04:00:00 EST 2004 · Physical Review. A

DOI:https://doi.org/10.1103/PhysRevA.69.012702· OSTI ID:20640604

Huttula, M; Kukk, E; Heinaesmaeki, S; Jurvansuu, M; Aksela, H; Aksela, S ^[1]; Fritzsche, S ^[1]

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1. Department of Physical Sciences, University of Oulu, P.O. Box 3000, 90014 University of Oulu (Finland)

Effects of the open-shell electronic structure of atomic Sn on the 4d photoelectron and Auger electron spectra have been studied by both theory and experiment. The 5p and 4d photoelectron spectra and the 4d{sup -1}{yields}5p{sup -2} Auger spectrum have been measured from atomic tin using synchrotron radiation for excitation. Relativistic Dirac-Fock calculations have been carried out for the energies and intensities of photoelectron and Auger electron transitions from each thermally populated initial state level. It has been shown by a comparison of the experimental and theoretical spectra that the weakly populated excited neutral states, negligible in the direct photoionization process, play an important role in the formation of the Auger spectrum of the open-shell atoms.

• OSTI ID: 20640604
• Journal Information: Physical Review. A, Journal Name: Physical Review. A Journal Issue: 1 Vol. 69; ISSN 1050-2947; ISSN PLRAAN
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
ATOMS
AUGER ELECTRON SPECTROSCOPY
COMPARATIVE EVALUATIONS
DECAY
ELECTRON SPECTRA
ELECTRONIC STRUCTURE
ELECTRONS
EXCITATION
EXCITED STATES
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
PHOTON-ATOM COLLISIONS
RELATIVISTIC RANGE
SYNCHROTRON RADIATION
TIN