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Initiation and growth of the discontinuous precipitation reaction at [0 1 1] symmetric tilt boundaries in Cu-Be alloy bicrystals

Journal Article · · Acta Materialia
 [1];  [1];  [1];  [1]
  1. Department of Mechanical Systems Engineering, Kanazawa University, 2-40-20 Kodatsuno, Kanazawa 920-8667 (Japan)

The initiation and growth of discontinuous precipitation (DP) at [0 1 1] symmetric tilt boundaries in Cu-0.75 wt% Be alloy bicrystals have been studied. Transmission electron microscopy revealed that {gamma} precipitates tended to nucleate at a boundary in such a manner that their habit plane, (1 1 2){sub {alpha}} or (4 4 5){sub {alpha}}, with one of the adjoining grains lay as close as possible to the boundary. The habit plane with a low energy formed on both sides of the precipitates behind an initially migrating boundary, indicating the importance of the existence of the low-energy habit plane for the initial boundary migration. The incubation period to initiate DP and cell growth rate for a boundary show a good correlation with the energy of the boundary. A kinetic analysis of DP using the models of Turnbull, and Petermann and Hornbogen has yielded boundary diffusion data. A higher-energy boundary has a higher diffusivity with a smaller activation energy.

OSTI ID:
20637158
Journal Information:
Acta Materialia, Journal Name: Acta Materialia Journal Issue: 4 Vol. 53; ISSN 1359-6454; ISSN ACMAFD
Country of Publication:
United States
Language:
English

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