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Evolution of bias field and offset piezoelectric coefficient in bulk lead zirconate titanate with fatigue

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.1847712· OSTI ID:20636812
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  1. Institute of Materials Science, Darmstadt University of Technology, 64287 Darmstadt (Germany)
Hysteresis loops of the piezoelectric coefficient, d{sub 33}=f(E{sub 3}), are measured on virgin and fatigued lead zirconate titanate ceramics. Four parameters are directly extracted from the measurements: internal bias field E{sub b}, offset piezoelectric coefficient d{sub offset}, coercive field E{sub c}, and remnant piezoelectric coefficient d{sub r}. The reduction in d{sub r} displays the decreasing switchable polarization with fatigue cycling. E{sub b} and d{sub offset} are found to be linearly related. After thermal annealing, both offsets disappear, while the increase in E{sub c} and the reduction in d{sub r} withstand annealing. The microscopic entities responsible for the offsets are less stable than those for reduced switching.
OSTI ID:
20636812
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 1 Vol. 86; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English