Fluctuations of chemical composition of austenite and their consequence on shape memory effect in Fe-Mn-(Si, Cr, Ni, C, N) alloys

Journal Article · Mon Sep 20 04:00:00 EDT 2004 · Acta Materialia

DOI:https://doi.org/10.1016/j.actamat.2004.06.036· OSTI ID:20634775

Bliznuk, V V ^[1]; Gavriljuk, V G ^[1]; Kopitsa, G P ^[2]; Grigoriev, S V ^[2]; Runov, V V ^[2]

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1. G.V. Kurdyumov Institute for Metal Physics, National Academy of Sciences, Vernadsky Blvd., 36, UA-03680, Kiev 142 (Ukraine)
2. Petersburg Nuclear Physics Institute, Russian Academy of Sciences, Gatchina 188300 (Russian Federation)

Polycrystalline samples of shape memory iron-based alloys containing 17, and 30 mass% Mn and alloyed with Si, Cr, Ni, C, N were studied by means of small angle scattering of polarized neutrons (SAPNS). A direct correlation between chemical homogeneity of the Fe-Mn, Fe-Mn-Si, Fe-Mn-Si-Cr, Fe-Mn-Si-Cr-Ni solid solutions and the values of reversible strain caused by the {gamma} {yields} {epsilon} {yields} {gamma} martensitic transformation was found. The addition of silicon to the Fe-Mn alloys significantly improves chemical homogeneity of the fcc solid solution on the scale of larger than several nm, which correlates with the essential increase of reversible strain. A similar to silicon but weaker effect was observed in the case of nitrogen addition to the Fe-Mn-Si-Cr, Fe-Mn-Si-Cr-Ni alloys. Based on the obtained experimental data and in consistency with the previously expressed idea by Sade et al., the positive effect of silicon and nitrogen on chemical homogeneity and SME in Fe-Mn alloys is attributed to the short-range atomic ordering induced by these elements.

• OSTI ID: 20634775
• Journal Information: Acta Materialia, Journal Name: Acta Materialia Journal Issue: 16 Vol. 52; ISSN 1359-6454; ISSN ACMAFD
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
AUSTENITE
CHEMICAL COMPOSITION
CHROMIUM ALLOYS
EXPERIMENTAL DATA
FCC LATTICES
IRON BASE ALLOYS
MANGANESE ALLOYS
NEUTRON DIFFRACTION
NEUTRONS
NICKEL ALLOYS
NITROGEN ADDITIONS
PHASE TRANSFORMATIONS
POLYCRYSTALS
SHAPE MEMORY EFFECT
SILICON ALLOYS
SMALL ANGLE SCATTERING
SOLID SOLUTIONS
STRAINS