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Crystallization and nanoindentation behavior of a bulk Zr-Al-Ti-Cu-Ni amorphous alloy

Journal Article · · Journal of Materials Research
DOI:https://doi.org/10.1557/JMR.2000.0114· OSTI ID:20216856
 [1];  [2];  [2];  [3]
  1. Department of Chemical and Biochemical Engineering and Materials Science, University of California, Irvine, California 92697 (United States)
  2. Chemistry and Materials Science, Lawrence Livermore National Laboratory, P.O. Box 808, L-350, Livermore, California 94551-9900 (United States)
  3. Metals and Ceramics Division, P.O. Box 2008, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6376 (United States)

The crystallization and nanoindentation behavior of a Zr-10Al-5Ti-17.9Cu-14.6Ni (at.%) bulk amorphous alloy (BAA) were studied. Resulting from the kinetic nature of phase transformation in multicomponent alloys, the crystallization path is complex. Despite the complexity of different crystallization paths, the main final crystallized product in the Zr-based BAA is Zr{sub 2}Cu. Young's modulus and hardness of the BAA were found to increase with an increase in annealing temperature. The observed mechanical properties were correlated with the microstructure of the material. Also, in the present paper, both the observed crystallization and nanoindentation behavior are compared with existing data. Zr-based BAAs exhibit a ratio of hardness to Young's modulus (H/E ratio) of about 1/10, suggesting the interatomic bonding in the alloys is close to being covalent. (c) 2000 Materials Research Society.

OSTI ID:
20216856
Journal Information:
Journal of Materials Research, Journal Name: Journal of Materials Research Journal Issue: 3 Vol. 15; ISSN JMREEE; ISSN 0884-2914
Country of Publication:
United States
Language:
English

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