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Germanium FCC structure from a colloidal crystal template

Journal Article · · Langmuir
DOI:https://doi.org/10.1021/la991412s· OSTI ID:20080273
Here, the authors show a method to fabricate a macroporous structure in which the pores, essentially identical, arrange regularly in a face-centered cubic (FCC) lattice. The result is a network of air spheres in a germanium medium. This structure presents the highest dielectric contrast ({epsilon}{sub Ge}/{epsilon}{sub air} = 16) ever achieved in the optical regime in such periodic structures, which could result in important applications in photonics. The authors employ solid silica colloidal crystals (opals) as templates within which a cyclic germanium growth process is carried out. Thus, the three-dimensional periodicity of the host is inherited by the guest. Afterward, the silica is removed and a germanium opal replica is obtained.
Research Organization:
Univ. Politecnica de Valencia (ES)
OSTI ID:
20080273
Journal Information:
Langmuir, Journal Name: Langmuir Journal Issue: 10 Vol. 16; ISSN LANGD5; ISSN 0743-7463
Country of Publication:
United States
Language:
English

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