Catalytic graphitization of carbon aerogels by transition metals

Journal Article · Tue May 02 04:00:00 EDT 2000 · Langmuir

DOI:https://doi.org/10.1021/la991080r· OSTI ID:20075544

Maldonado-Hodar, F J; Moreno-Castilla, C; Rivera-Utrilla, J; Hanzawa, Y; Yamada, Y

Carbon aerogels and Cr-, Fe-, Co-, and Ni-containing carbon aerogels were obtained by pyrolysis, at temperatures between 500 and 1,800 C, of the corresponding aerogels prepared by the sol-gel method from polymerization of resorcinol with formaldehyde. All samples were characterized by mercury porosimetry, nitrogen adsorption, X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy. Results obtained show that carbon aerogels are, essentially, macroporous materials that maintain large pore volumes even after pyrolysis at 1,800 C. For pyrolysis at temperatures higher than 1,000 C, the presence of the transition metals produced graphitized areas with three-dimensional stacking order, as shown by HRTEM, XRD, and Raman spectroscopy. HRTEM also showed that the metal-carbon containing aerogels were formed by polyhedral structures. Cr and Fe seem to be the best catalysts for graphitization of carbon aerogels.

• Research Organization: Univ. de Granada (ES)
• OSTI ID: 20075544
• Journal Information: Langmuir, Journal Name: Langmuir Journal Issue: 9 Vol. 16; ISSN LANGD5; ISSN 0743-7463
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
CAPACITIVE ENERGY STORAGE EQUIPMENT
CARBON
CATALYSTS
CHROMIUM
COBALT
GELS
IRON
NICKEL
PORE STRUCTURE