Navigating the complexities of solvent and binder selection for solution processing of sulfide solid-state electrolytes

Mills, Anna; Tsai, Wan-Yu; Brahmbhatt, Teerth; Self, Ethan C.; Armstrong, Beth L.; Hallinan, Daniel T.; Nanda, Jagjit; Yang, Guang

doi:10.1557/s43579-023-00423-5

Navigating the complexities of solvent and binder selection for solution processing of sulfide solid-state electrolytes

Journal Article · Fri Aug 18 00:00:00 EDT 2023 · MRS communications

DOI:https://doi.org/10.1557/s43579-023-00423-5· OSTI ID:1999399

^[1]; Tsai, Wan-Yu ^[2]; Brahmbhatt, Teerth ^[2]; Self, Ethan C. ^[2]; Armstrong, Beth L. ^[2]; Hallinan, Daniel T. ^[3]; Nanda, Jagjit ^[4]; ^[2]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Florida A & M University, Tallahassee, FL (United States); Florida State University, Tallahassee, FL (United States); SLAC
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Florida A & M University, Tallahassee, FL (United States); Florida State University, Tallahassee, FL (United States)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

We introduce a paradigm of solvent and binder selection for solution-processing Li₆PS₅Cl solid-state electrolyte particles based on Hansen solubility parameters. Treatment of the Li₆PS₅Cl in selected solvents results in particle morphological change, but crystallographic structure remains intact. Although solution processing reduced the Li₆PS₅Cl ionic conductivity, it promotes interfacial stability by alleviating reduction of the solid electrolyte in contact with Li metal. In conclusion, these findings have the potential to enhance the stability, structural integrity, and performance of sulfide solid-state electrolytes in practical applications.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-76SF00515; AC05-00OR22725

OSTI ID:: 1999399

Alternate ID(s):: OSTI ID: 2006927

Journal Information:: MRS communications, Journal Name: MRS communications Journal Issue: 6 Vol. 13; ISSN 2159-6867

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

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