The reaction of acid mine drainage with fly ash from coal combustion
The placement of alkaline fly ash in abandoned, reclaimed or active surface coal mines is intended to reduce the amount of acid mine drainage (AMD) produced at such sites by neutralization, inhibition of acid forming bacteria, encapsulation of the pyrite or water diversion. A continuing concern with this application is the potential release of trace elements from the fly ash when it is placed in contact with AMD. To investigate the possible release of antimony, arsenic, barium, boron, cadmium, chromium, cobalt, copper, lead, nickel, selenium, and zinc from fly ash, a series of column leaching tests were conducted. A one kg fly ash sample, placed in a 5-cm by 1 m acrylic columns, was leached at a nominal rate of 250 mL/d for between 30 and 60 days. The leachant solutions were deionized water, and dilute solutions of sulfuric acid and ferric chloride. Leaching tests have been completed on 28 fly ash samples. leachate data, analyzed as the mass extracted with respect to the concentration in the solid, indicate that the release of trace elements is variable, with only barium and zinc extracted at greater than 50 pct of the amount present in the original sample. As a comparison, water quality changes have been monitored at three sites where fly ash grout was injected after reclamation to control AMD. When compared before and after grouting, small increases in pH and decreases in acidity at discharge points were observed. Concentrations of trace metals were found to be comparable in treated and untreated areas. When grouted and ungrouted areas were compared, the effect of the fly ash was shown to be localized in the areas of injection. These studies indicated that when fly ash is used as a reagent to control of AMD, the release of trace elements is relatively small.
- Research Organization:
- Department of Energy, Pittsburgh, PA (US)
- OSTI ID:
- 20023297
- Resource Relation:
- Conference: 16th Annual National Meeting of the American Society for Surface Mining and Reclamation, Scottsdale, AZ (US), 08/13/1999--08/19/1999; Other Information: PBD: [1999]; Related Information: In: Mining and reclamation for the next millennium. Proceedings of the 16th annual national meeting of the American Society for Surface Mining and Reclamation, by Bengson, S.A.; Bland, D.M. [eds.], 745 pages.
- Country of Publication:
- United States
- Language:
- English
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