Two-electron atomic systems confined within spheroidal boxes
Journal Article
·
· International Journal of Quantum Chemistry
The direct variational method is used to estimate some interesting physical properties of the He atom and the Li{sup +} ion confined within impenetrable spheroidal boxes. A comparative investigation f the ground=state energy, pressure, polarizability, dipole, and quadrupole moments with those of the He atom inside boxes with paraboloidal walls is made. The overall results show a similar qualitative behavior. However, for Li{sup +} there are quantitative differences on such properties due to its major nuclear charge, as expected. The trial wave function is constructed as a product of two hydrogenic wave functions adapted to the geometry of the confining boxes.
- Research Organization:
- Univ. de Sonora (MX)
- OSTI ID:
- 20015664
- Journal Information:
- International Journal of Quantum Chemistry, Journal Name: International Journal of Quantum Chemistry Journal Issue: 2 Vol. 77; ISSN IJQCB2; ISSN 0020-7608
- Country of Publication:
- United States
- Language:
- English
Similar Records
Variational calculations for the hydrogen atom confined in spaces with paraboloidal and spheroidal boundaries
Addendum to 'Electron structure of a dipole-bound anion confined in a spherical box': The case of a finite dipole
Hydrogen atom within spherical boxes with penetrable walls
Journal Article
·
Wed Apr 05 00:00:00 EDT 1995
· International Journal of Quantum Chemistry
·
OSTI ID:450669
Addendum to 'Electron structure of a dipole-bound anion confined in a spherical box': The case of a finite dipole
Journal Article
·
Sun Nov 30 23:00:00 EST 2003
· Physical Review. A
·
OSTI ID:20640552
Hydrogen atom within spherical boxes with penetrable walls
Journal Article
·
Sun Jul 01 00:00:00 EDT 1979
· J. Chem. Phys.; (United States)
·
OSTI ID:6214072