Influence of aging on transformation characteristics in shape memory CuZnAl alloys

Journal Article · Tue Feb 01 04:00:00 EST 2000 · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science

DOI:https://doi.org/10.1007/s11661-000-0270-4· OSTI ID:20015612

Kayali, N; Zengin, R; Adiguezel, O

Shape memory alloys exhibit superelasticity when they are deformed in a temperature range where the thermoelastic martensite forms on application of a strain. The martensite persists upon removal of the applied strain, and the alloy recovers the original shape on heating over the reverse-transformation temperature after removing the strain. The {beta}-phase CuZnAl alloys have {beta}-type superlattice in the parent case, and M9R or M18R martensites occur on quenching the alloys from the homogenization temperature. The basal plane of martensite is exposed to hexagonal distortion with martensitic transformation as well as the monoclinic distortion in the crystal structure, and splittings are observed in some selected diffraction-peak pairs due to the differences in atom sizes in lattice points. These pairs have a great importance as ordering criteria and satisfy a special relation between Miller indices. The present text reports the variation of the differences in interplane spacings ({Delta}d) between some selected planes upon the further aging at room temperature at which alloys are fully martensitic. The decrease of {Delta}d during the aging implies that the monoclinic distortion decreases. The mass increases are caused by the oxidation upon heating the alloys at high temperatures close to the betatizing temperature at free atmosphere.

• Research Organization: Firat Univ., Elazig (TR)
• OSTI ID: 20015612
• Journal Information: Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, Journal Name: Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science Journal Issue: 2 Vol. 31; ISSN MMTAEB; ISSN 1073-5623
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
AGING
ALUMINIUM ALLOYS
COPPER ALLOYS
CRYSTAL-PHASE TRANSFORMATIONS
MARTENSITE
MONOCLINIC LATTICES
SHAPE MEMORY EFFECT
STRAINS
ZINC ALLOYS