Hybrid redox polyether melts based on polyether-tailed counterions
Journal Article
·
· Journal of the American Chemical Society
Interesting ionic materials can be transformed into room temperature molten salts by combining them with polyether-tailed counterions such as polyether-tailed 2-sulfobenzoate (MePEG-BzSO{sub 3}{sup {minus}}) and polyethertailed triethylammonium (MePEG-Et{sub 3}N{sup +}). Melts containing ruthenium hexamine, metal trisbipyridines, metal trisphenanthrolines, and ionic forms of aluminum quinolate, anthraquinone, phthalocyanine, and porphyrins are described. These melts exhibit ionic conductivities in the 7 x 10{sup {minus}5} to 7 x 10{sup {minus}10} {Omega}{sup {minus}1} cm{sup {minus}1} range, which permit microelectrode voltammetry in the undiluted materials, examples of which are presented.
- Research Organization:
- Univ. of North Carolina, Chapel Hill, NC (US)
- Sponsoring Organization:
- US Department of Energy
- OSTI ID:
- 20014080
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 4 Vol. 121; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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