Sterically crowded gallium amidinate complexes
The sterically crowded gallium amidinate complexes {l{underscore}brace}{sup t}BuC(NR{prime}){sub 2}{r{underscore}brace}GaX{sub 2} (X = Cl, Me, Et, CH{sub 2}Ph; R{prime} = {sup i}Pr, Cy, {sup t}Bu) have been synthesized in good yield. X-ray crystallographic analyses show that the steric interactions between the {sup t}Bu and R{prime} groups influence the R{prime}{single{underscore}bond}N{single{underscore}bond}Ga angle and the steric environment at gallium.
- Research Organization:
- Univ. of Iowa, Iowa City, IA (US)
- Sponsoring Organization:
- US Department of Energy
- DOE Contract Number:
- FG02-88ER13935
- OSTI ID:
- 20003991
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 22 Vol. 18; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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