Constitutional and thermal defects in nickel aluminides

Conference · Thu Jul 01 04:00:00 EDT 1999

OSTI ID:20001616

Korzhavyi, P A; Abrikosov, I A; Johansson, B

The formation energies of intrinsic point defects and the interaction energies of possible defect pairs in NiAl are calculated from first principles within an order-N, locally self-consistent Green's function method in conjunction with the multipole electrostatic corrections to the atomic sphere approximation. The theory correctly reproduces the ground-state properties of the off-stoichiometric NiAl alloys. The constitutional defects (antisite Ni atoms in Ni-rich and Ni vacancies in Al-rich NiAl) are shown to form ordered structures in the ground state, in which the defects of the same kind tend to avoid each other at the shortest separation distance on their sublattice. A mean-field theory is applied to calculate the equilibrium concentrations of thermal defects. The statistics of thermal defects is interpreted in terms of dominant composition-conserving complex defects which are shown to be triple defects in Ni-rich and nearly stoichiometric NiAl. In the Al-rich region a novel thermal excitation dominates where two constitutional Ni vacancies are replaced by one antisite Al atom. The number of vacancies, as well as the total number of point defects decrease with temperature in Al-rich NiAl. The boundary between the two regions is treated analytically. The vacancy concentration exhibits a minimum in its temperature dependence at the boundary. Similar analysis is applied to study constitutional and thermal defects in Ni{sub 3}Al as a function of concentration is in excellent agreement with recent experimental data.

• Research Organization: Uppsala Univ. (SE)
• OSTI ID: 20001616
• Report Number(s): CONF-981104--; ISBN 1-55899-458-0; ISSN 1067-9995
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ALUMINIUM ALLOYS
FORMATION FREE ENERGY
GROUND STATES
INTERMETALLIC COMPOUNDS
MATHEMATICAL MODELS
NICKEL ALLOYS
POINT DEFECTS
QUANTUM MECHANICS
STOICHIOMETRY
THEORETICAL DATA