Electrolytes for lithium batteries with carbon and/or silicon anodes

Xu, Wu; Zhang, Ji-Guang; Jia, Hao; Zhang, Xianhui; Cao, Xia; Chae, Sujong; Yi, Ran; Li, Qiuyan; Kwak, Won-Jin; Li, Xiaolin

Electrolytes for lithium batteries with carbon and/or silicon anodes

Patent · Tue May 30 00:00:00 EDT 2023

OSTI ID:1998429

Xu, Wu; Zhang, Ji-Guang; Jia, Hao; Zhang, Xianhui; Cao, Xia; Chae, Sujong; Yi, Ran; Li, Qiuyan; Kwak, Won-Jin; Li, Xiaolin

Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, or a combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830; EE0008444

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 11,664,536

Application Number:: 17/144,600

OSTI ID:: 1998429

Country of Publication:: United States

Language:: English

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