Single crystal synthesis and magnetic properties of a Shastry-Sutherland lattice compound BaNd2ZnS5

Billingsley, Brianna R.; Marshall, Madalynn; Shu, Zhixue; Cao, Huibo; Kong, Tai

doi:10.1103/physrevmaterials.6.104403

Single crystal synthesis and magnetic properties of a Shastry-Sutherland lattice compound BaNd2 ZnS5

Journal Article · Fri Oct 07 00:00:00 EDT 2022 · Physical Review Materials

DOI:https://doi.org/10.1103/physrevmaterials.6.104403· OSTI ID:1997628

Billingsley, Brianna R. ^[1]; Marshall, Madalynn ^[2]; Shu, Zhixue ^[1]; ^[2]; ^[1]

University of Arizona, Tucson, AZ (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

In this study, single crystals of a Shastry-Sutherland magnetic semiconductor, BaNd₂ ZnS₅, were synthesized through a high-temperature solution growth technique. Physical properties were characterized by powder and single crystal x-ray diffraction, temperature- and field-dependent magnetization, and temperature-dependent specific heat measurements. BaNd₂ ZnS₅ orders antiferromagnetically at 2.9 K, with magnetic moments primarily aligned within the $ab$ -plane. Magnetic isothermal measurements show metamagnetic transitions at ~ 15 kOe for the [110] direction and ~ 21 kOe for the [100] direction. Estimated magnetic entropy suggests a double ground state for each neodymium ion.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1997628

Journal Information:: Physical Review Materials, Journal Name: Physical Review Materials Journal Issue: 10 Vol. 6; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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