Understanding and Controlling Photothermal Responses in MXenes

Guzelturk, Burak; Kamysbayev, Vladislav; Wang, Di; Hu, Huicheng; Li, Ruiyu; King, Sarah B.; Reid, Alexander H.; Lin, Ming-Fu; Wang, Xijie; Walko, Donald A.; Zhang, Xiaoyi; Lindenberg, Aaron; Talapin, Dmitri V.

doi:10.1021/acs.nanolett.2c05001

Understanding and Controlling Photothermal Responses in MXenes

Journal Article · Tue Mar 14 00:00:00 EDT 2023 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.2c05001· OSTI ID:1997366

^[1]; Kamysbayev, Vladislav ^[2]; Wang, Di ^[2]; Hu, Huicheng ^[2]; Li, Ruiyu ^[2]; ^[2]; ^[3]; ^[3]; Wang, Xijie ^[3]; Walko, Donald A. ^[4]; ^[4]; ^[5]; ^[6]

Argonne National Laboratory (ANL), Argonne, IL (United States); SLAC
University of Chicago, IL (United States)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Stanford University, CA (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
University of Chicago, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)

MXenes have the potential for efficient light-to-heat conversion in photothermal applications. To effectively utilize MXenes in such applications, it is important to understand the underlying nonequilibrium processes, including electron–phonon and phonon–phonon couplings. Here, we use transient electron and X-ray diffraction to investigate the heating and cooling of photoexcited MXenes at femtosecond to nanosecond time scales. Our results show extremely strong electron–phonon coupling in Ti₃C₂-based MXenes, resulting in lattice heating within a few hundred femtoseconds. We also systematically study heat dissipation in MXenes with varying film thicknesses, chemical surface terminations, flake sizes, and annealing conditions. We find that the thermal boundary conductance (TBC) governs the thermal relaxation in films thinner than the optical penetration depth. In conclusion, we achieve a 2-fold enhancement of the TBC, reaching 20 MW m^–2 K^–1, by controlling the flake size or chemical surface termination, which is promising for engineering heat dissipation in photothermal and thermoelectric applications of the MXenes.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Science Foundation (NSF); US Air Force Office of Scientific Research (AFOSR); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-76SF00515; AC02-06CH11357

OSTI ID:: 1997366

Alternate ID(s):: OSTI ID: 2404500

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 7 Vol. 23; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (65)

Tuning Thermal Transport Through Atomically Thin Ti ₃ C ₂ T _z MXene by Current Annealing in Vacuum Hemmat, Zahra; Yasaei, Poya; Schultz, Jeremy F. Advanced Functional Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adfm.201805693	journal	March 2019
A Review of Experimental and Computational Advances in Thermal Boundary Conductance and Nanoscale Thermal Transport across Solid Interfaces Giri, Ashutosh; Hopkins, Patrick E. Advanced Functional Materials https://doi.org/10.1002/adfm.201903857	journal	August 2019
Insights into the Photothermal Conversion of 2D MXene Nanomaterials: Synthesis, Mechanism, and Applications Xu, Dingxin; Li, Zhidong; Li, Laisheng Advanced Functional Materials, Vol. 30, Issue 47 https://doi.org/10.1002/adfm.202000712	journal	April 2020
Visualizing Energy Transfer at Buried Interfaces in Layered Materials Using Picosecond X‐Rays Nyby, Clara; Sood, Aditya; Zalden, Peter Advanced Functional Materials, Vol. 30, Issue 34 https://doi.org/10.1002/adfm.202002282	journal	June 2020
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7, p. 992-1005 https://doi.org/10.1002/adma.201304138	journal	December 2013
Nanometals for Solar-to-Chemical Energy Conversion: From Semiconductor-Based Photocatalysis to Plasmon-Mediated Photocatalysis and Photo-Thermocatalysis Meng, Xianguang; Liu, Lequan; Ouyang, Shuxin Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201600305	journal	May 2016
Metallic MXene Saturable Absorber for Femtosecond Mode-Locked Lasers Jhon, Young In; Koo, Joonhoi; Anasori, Babak Advanced Materials, Vol. 29, Issue 40 https://doi.org/10.1002/adma.201702496	journal	July 2017
Theranostic 2D Tantalum Carbide (MXene) Lin, Han; Wang, Youwei; Gao, Shanshan Advanced Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adma.201703284	journal	December 2017
Saturable Absorption in 2D Ti ₃ C ₂ MXene Thin Films for Passive Photonic Diodes Dong, Yongchang; Chertopalov, Sergii; Maleski, Kathleen Advanced Materials, Vol. 30, Issue 10 https://doi.org/10.1002/adma.201705714	journal	January 2018
Enhanced Thermal Boundary Conductance in Few-Layer Ti ₃ C ₂ MXene with Encapsulation Yasaei, Poya; Hemmat, Zahra; Foss, Cameron J. Advanced Materials, Vol. 30, Issue 43 https://doi.org/10.1002/adma.201801629	journal	September 2018
Ultrafast Spectroscopy of Plasmons and Free Carriers in 2D MXenes Colin‐Ulloa, Erika; Fitzgerald, Andrew; Montazeri, Kiana Advanced Materials, Vol. 35, Issue 8 https://doi.org/10.1002/adma.202208659	journal	December 2022
Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti ₃ C ₂ MXene Flakes Lipatov, Alexey; Alhabeb, Mohamed; Lukatskaya, Maria R. Advanced Electronic Materials, Vol. 2, Issue 12 https://doi.org/10.1002/aelm.201600255	journal	November 2016
High‐Efficiency Thermoelectric Power Generation Enabled by Homogeneous Incorporation of MXene in (Bi,Sb) ₂ Te ₃ Matrix Lu, Xiaofang; Zhang, Qihao; Liao, Jincheng Advanced Energy Materials, Vol. 10, Issue 2 https://doi.org/10.1002/aenm.201902986	journal	November 2019
Thermal Properties of MXenes and Relevant Applications Yu, LePing; Xu, Lyu; Lu, Lu ChemPhysChem, Vol. 23, Issue 17 https://doi.org/10.1002/cphc.202200203	journal	July 2022
Thermoelectric Properties of Two-Dimensional Molybdenum-Based MXenes Kim, Hyunho; Anasori, Babak; Gogotsi, Yury Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b02056	journal	July 2017
Rational Design of Flexible Two-Dimensional MXenes with Multiple Functionalities Fu, Zhongheng; Wang, Ning; Legut, Dominik Chemical Reviews, Vol. 119, Issue 23 https://doi.org/10.1021/acs.chemrev.9b00348	journal	November 2019
Hydrogen Bond Interaction Promotes Flash Energy Transport at MXene-Solvent Interface Li, Jiebo; Chi, Zhen; Qin, Ruzhan The Journal of Physical Chemistry C, Vol. 124, Issue 19 https://doi.org/10.1021/acs.jpcc.0c01039	journal	April 2020
Intrinsic Structural, Electrical, Thermal, and Mechanical Properties of the Promising Conductor Mo ₂ C MXene Zha, Xian-Hu; Yin, Jingshuo; Zhou, Yuhong The Journal of Physical Chemistry C, Vol. 120, Issue 28 https://doi.org/10.1021/acs.jpcc.6b04192	journal	July 2016
Ultrafast Transient Spectra and Dynamics of MXene (Ti₃C₂T_x) in Response to Light Excitations of Various Wavelengths Zhang, Qi; Yan, Li; Yang, Mingsheng The Journal of Physical Chemistry C, Vol. 124, Issue 11 https://doi.org/10.1021/acs.jpcc.9b11652	journal	February 2020
Dynamic Structural Response and Deformations of Monolayer MoS ₂ Visualized by Femtosecond Electron Diffraction Mannebach, Ehren M.; Li, Renkai; Duerloo, Karel-Alexander Nano Letters, Vol. 15, Issue 10 https://doi.org/10.1021/acs.nanolett.5b02805	journal	September 2015
Dynamical Control over Terahertz Electromagnetic Interference Shielding with 2D Ti ₃ C ₂ T _y MXene by Ultrafast Optical Pulses Li, Guangjiang; Amer, Naaman; Hafez, Hassan A. Nano Letters, Vol. 20, Issue 1 https://doi.org/10.1021/acs.nanolett.9b04404	journal	December 2019
Temperature-Dependent Thermal Boundary Conductance of Monolayer MoS ₂ by Raman Thermometry Yalon, Eilam; Aslan, Özgür Burak; Smithe, Kirby K. H. ACS Applied Materials & Interfaces, Vol. 9, Issue 49 https://doi.org/10.1021/acsami.7b11641	journal	November 2017
Nonequilibrium Thermodynamics of Colloidal Gold Nanocrystals Monitored by Ultrafast Electron Diffraction and Optical Scattering Microscopy Guzelturk, Burak; Utterback, James K.; Coropceanu, Igor ACS Nano, Vol. 14, Issue 4 https://doi.org/10.1021/acsnano.0c00673	journal	March 2020
Theory of “Hot” Photoluminescence from Drude Metals Sivan, Yonatan; Dubi, Yonatan ACS Nano, Vol. 15, Issue 5 https://doi.org/10.1021/acsnano.1c00835	journal	April 2021
Photo-Switchable Nanoripples in Ti₃C₂T_x MXene Volkov, Mikhail; Willinger, Elena; Kuznetsov, Denis A. ACS Nano, Vol. 15, Issue 9 https://doi.org/10.1021/acsnano.1c03635	journal	August 2021
Ultralarge Flakes of Ti₃C₂T_x MXene via Soft Delamination Shekhirev, Mikhail; Busa, Jeffrey; Shuck, Christopher E. ACS Nano, Vol. 16, Issue 9 https://doi.org/10.1021/acsnano.2c04506	journal	July 2022
MXene Ti ₃ C ₂ : An Effective 2D Light-to-Heat Conversion Material Li, Renyuan; Zhang, Lianbin; Shi, Le ACS Nano, Vol. 11, Issue 4 https://doi.org/10.1021/acsnano.6b08415	journal	March 2017
Mapping Hot Spots at Heterogeneities of Few-Layer Ti₃C₂ MXene Sheets Yasaei, Poya; Tu, Qing; Xu, Yaobin ACS Nano, Vol. 13, Issue 3 https://doi.org/10.1021/acsnano.8b09103	journal	February 2019
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M. Chemistry of Materials, Vol. 26, Issue 7 https://doi.org/10.1021/cm500641a	journal	March 2014
A Two-Dimensional Biodegradable Niobium Carbide (MXene) for Photothermal Tumor Eradication in NIR-I and NIR-II Biowindows Lin, Han; Gao, Shanshan; Dai, Chen Journal of the American Chemical Society, Vol. 139, Issue 45 https://doi.org/10.1021/jacs.7b07818	journal	November 2017
Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize Nanolaminated MAX Phases and MXenes Li, Mian; Lu, Jun; Luo, Kan Journal of the American Chemical Society, Vol. 141, Issue 11 https://doi.org/10.1021/jacs.9b00574	journal	March 2019
Abnormally Strong Electron–Phonon Scattering Induced Unprecedented Reduction in Lattice Thermal Conductivity of Two-Dimensional Nb₂C Huang, Yongda; Zhou, Jian; Wang, Guanjie Journal of the American Chemical Society, Vol. 141, Issue 21 https://doi.org/10.1021/jacs.9b01742	journal	May 2019
Tailoring the thermal and electrical transport properties of graphene films by grain size engineering Ma, Teng; Liu, Zhibo; Wen, Jinxiu Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14486	journal	February 2017
Ultrafast non-radiative dynamics of atomically thin MoSe2 Lin, Ming-Fu; Kochat, Vidya; Krishnamoorthy, Aravind Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01844-2	journal	November 2017
Control of MXenes’ electronic properties through termination and intercalation Hart, James L.; Hantanasirisakul, Kanit; Lang, Andrew C. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-08169-8	journal	January 2019
Dynamic lattice distortions driven by surface trapping in semiconductor nanocrystals Guzelturk, Burak; Cotts, Benjamin L.; Jasrasaria, Dipti Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-22116-0	journal	March 2021
Room-temperature high-precision printing of flexible wireless electronics based on MXene inks Shao, Yuzhou; Wei, Lusong; Wu, Xinyue Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-30648-2	journal	June 2022
Simultaneous capturing phonon and electron dynamics in MXenes Zhang, Qi; Li, Jiebo; Wen, Jiao Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-35605-7	journal	December 2022
Flexural phonons in supported graphene: from pinning to localization Zhao, Wei L. Z.; Tikhonov, Konstantin S.; Finkel’stein, Alexander M. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-34426-3	journal	November 2018
Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction Zhang, Jinqiang; Zhao, Yufei; Guo, Xin Nature Catalysis, Vol. 1, Issue 12 https://doi.org/10.1038/s41929-018-0195-1	journal	December 2018
Fundamentals of MXene synthesis Lim, Kang Rui Garrick; Shekhirev, Mikhail; Wyatt, Brian C. Nature Synthesis, Vol. 1, Issue 8 https://doi.org/10.1038/s44160-022-00104-6	journal	August 2022
Electronic properties and applications of MXenes: a theoretical review Khazaei, Mohammad; Ranjbar, Ahmad; Arai, Masao Journal of Materials Chemistry C, Vol. 5, Issue 10 https://doi.org/10.1039/C7TC00140A	journal	January 2017
Coincident modulation of lattice and electron thermal transport performance in MXenes via surface functionalization Guo, Zhonglu; Miao, Naihua; Zhou, Jian Physical Chemistry Chemical Physics, Vol. 20, Issue 29 https://doi.org/10.1039/C8CP02564A	journal	January 2018
Applications of 2D MXenes in energy conversion and storage systems Pang, Jinbo; Mendes, Rafael G.; Bachmatiuk, Alicja Chemical Society Reviews, Vol. 48, Issue 1 https://doi.org/10.1039/C8CS00324F	journal	January 2019
Solar absorber material and system designs for photothermal water vaporization towards clean water and energy production Gao, Minmin; Zhu, Liangliang; Peh, Connor Kangnuo Energy & Environmental Science, Vol. 12, Issue 3 https://doi.org/10.1039/C8EE01146J	journal	January 2019
Two-dimensional MXene-reinforced robust surface superhydrophobicity with self-cleaning and photothermal-actuating binary effects Cao, Wen-Tao; Feng, Wei; Jiang, Ying-Ying Materials Horizons, Vol. 6, Issue 5 https://doi.org/10.1039/C8MH01566J	journal	January 2019
Thermal effects – an alternative mechanism for plasmon-assisted photocatalysis Dubi, Yonatan; Un, Ieng Wai; Sivan, Yonatan Chemical Science, Vol. 11, Issue 19 https://doi.org/10.1039/C9SC06480J	journal	January 2020
First-principles exploration of superconductivity in MXenes Bekaert, Jonas; Sevik, Cem; Milošević, Milorad V. Nanoscale, Vol. 12, Issue 33 https://doi.org/10.1039/D0NR03875J	journal	January 2020
Surface modification of titanium carbide MXene monolayers (Ti₂C and Ti₃C₂) via chalcogenide and halogenide atoms Faraji, M.; Bafekry, A.; Fadlallah, M. M. Physical Chemistry Chemical Physics, Vol. 23, Issue 28 https://doi.org/10.1039/D1CP01788H	journal	January 2021
Measurement of transient atomic displacements in thin films with picosecond and femtometer resolution Kozina, M.; Hu, T.; Wittenberg, J. S. Structural Dynamics, Vol. 1, Issue 3 https://doi.org/10.1063/1.4875347	journal	May 2014
Mega-electron-volt ultrafast electron diffraction at SLAC National Accelerator Laboratory Weathersby, S. P.; Brown, G.; Centurion, M. Review of Scientific Instruments, Vol. 86, Issue 7 https://doi.org/10.1063/1.4926994	journal	July 2015
Effect of surface termination on the lattice thermal conductivity of monolayer Ti ₃ C ₂ T _z MXenes Gholivand, Hamed; Fuladi, Shadi; Hemmat, Zahra Journal of Applied Physics, Vol. 126, Issue 6 https://doi.org/10.1063/1.5094294	journal	August 2019
Quantifying the limits of through-plane thermal dissipation in 2D-material-based systems Yasaei, Poya; Behranginia, Amirhossein; Hemmat, Zahra 2D Materials, Vol. 4, Issue 3 https://doi.org/10.1088/2053-1583/aa81bd	journal	August 2017
Comprehensive first-principles analysis of phonon thermal conductivity and electron-phonon coupling in different metals Tong, Zhen; Li, Shouhang; Ruan, Xiulin Physical Review B, Vol. 100, Issue 14 https://doi.org/10.1103/PhysRevB.100.144306	journal	October 2019
Electron-phonon coupling in metals at high electronic temperatures Medvedev, N.; Milov, I. Physical Review B, Vol. 102, Issue 6 https://doi.org/10.1103/PhysRevB.102.064302	journal	August 2020
Phonon thermal conduction in graphene: Role of Umklapp and edge roughness scattering Nika, D. L.; Pokatilov, E. P.; Askerov, A. S. Physical Review B, Vol. 79, Issue 15 https://doi.org/10.1103/PhysRevB.79.155413	journal	April 2009
Spectral analysis of nonequilibrium molecular dynamics: Spectral phonon temperature and local nonequilibrium in thin films and across interfaces Feng, Tianli; Yao, Wenjun; Wang, Zuyuan Physical Review B, Vol. 95, Issue 19 https://doi.org/10.1103/PhysRevB.95.195202	journal	May 2017
Electron-phonon coupling and hot electron thermalization in titanium nitride Dal Forno, Stefano; Lischner, Johannes Physical Review Materials, Vol. 3, Issue 11 https://doi.org/10.1103/PhysRevMaterials.3.115203	journal	November 2019
Kapitza Resistance Pollack, Gerald L. Reviews of Modern Physics, Vol. 41, Issue 1 https://doi.org/10.1103/RevModPhys.41.48	journal	January 1969
The {110} reflection in X-ray diffraction of MXene films: Misinterpretation and measurement via non-standard orientation Ghidiu, Michael; Barsoum, Michel W. Journal of the American Ceramic Society, Vol. 100, Issue 12 https://doi.org/10.1111/jace.15124	journal	August 2017
Light-induced picosecond rotational disordering of the inorganic sublattice in hybrid perovskites Wu, Xiaoxi; Tan, Liang Z.; Shen, Xiaozhe Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1602388	journal	July 2017
Electromagnetic interference shielding with 2D transition metal carbides (MXenes) Shahzad, F.; Alhabeb, M.; Hatter, C. B. Science, Vol. 353, Issue 6304 https://doi.org/10.1126/science.aag2421	journal	September 2016
Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes Kamysbayev, Vladislav; Filatov, Alexander S.; Hu, Huicheng Science, Vol. 369, Issue 6506 https://doi.org/10.1126/science.aba8311	journal	July 2020
Measurement and Analysis of Thermal Conductivity of Ti3C2Tx MXene Films Chen, Lin; Shi, Xuguo; Yu, Nanjie Materials, Vol. 11, Issue 9 https://doi.org/10.3390/ma11091701	journal	September 2018

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77 NANOSCIENCE AND NANOTECHNOLOGY
MXenes
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Understanding and Controlling Photothermal Responses in MXenes

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