Synergistic Co─Ir/Ru Composite Electrocatalysts Impart Efficient and Durable Oxygen Evolution Catalysis in Acid

Chong, Lina; Wen, Jianguo; Song, Erhong; Yang, Zhenzhen; Bloom, Ira D.; Ding, Wenjiang

doi:10.1002/aenm.202302306

Title: Synergistic Co─Ir/Ru Composite Electrocatalysts Impart Efficient and Durable Oxygen Evolution Catalysis in Acid

Journal Article · Fri Aug 11 00:00:00 EDT 2023 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202302306· OSTI ID:1995874

^[1]; Wen, Jianguo ^[2]; Song, Erhong ^[3]; Yang, Zhenzhen ^[4]; Bloom, Ira D. ^[4]; Ding, Wenjiang ^[5]

Chemical Science and Engineering Division Argonne National Laboratory 9700 S Cass Ave Lemont IL 60439 USA, Hydrogen Energy Center State Key Laboratory of Shanghai School of Chemical Science and Engineering Shanghai Jiao Tong University 800 Dongchuan Road, Minhang Shanghai 200240 China
Center for Nanoscale Materials Argonne National Laboratory 9700 S Cass Ave Lemont IL 60439 USA
State Key Lab of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai 200050 China
Chemical Science and Engineering Division Argonne National Laboratory 9700 S Cass Ave Lemont IL 60439 USA
Hydrogen Energy Center State Key Laboratory of Shanghai School of Chemical Science and Engineering Shanghai Jiao Tong University 800 Dongchuan Road, Minhang Shanghai 200240 China

Abstract Exploring highly active and robust catalysts, which have low precious metal content, to boost the kinetically sluggish oxygen evolution reaction (OER) is a key concern for hydrogen production via proton exchange membrane water electrolysis (PEMWE). Here, rational engineering of the morphology and the local geometric ligand environment of Ir and Ru catalysts are presented by using defect‐rich, lanthanum‐ and lithium‐doped Co ₃ O ₄ nanofiber (LLCF) as substrate that promotes the electrocatalytic OER. Two catalysts, IrCoOx@LLCF and RuCoOx@LLCF, achieve mass activities of 1013.5 A g _Ir ⁻¹ and 1911.4 A g _Ru ⁻¹ in 0.1 m HClO ₄ at 300 mV overpotential, respectively, which are 26 and 50 times higher than that of commercial IrO ₂ and RuO ₂ . Operando X‐ray absorption spectroscopy unveils the reversible structure of IrCoOx during the OER and the suppression of over‐oxidation of Co and Ir, giving rise to high stability. Density functional theory calculations reveal that the local geometric ligand engineering optimizes the binding of oxygenated species to the active sites, resulting in strongly enhanced catalytic activity.

View Accepted Manuscript (Publisher)

This content will become publicly available on Sun Aug 11 00:00:00 EDT 2024

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1995874

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Vol. 13 Journal Issue: 37; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (66)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Unification of Catalytic Water Oxidation and Oxygen Reduction Reactions: Amorphous Beat Crystalline Cobalt Iron Oxides Indra, Arindam; Menezes, Prashanth W.; Sahraie, Nastaran Ranjbar Journal of the American Chemical Society, Vol. 136, Issue 50 https://doi.org/10.1021/ja509348t	journal	December 2014
Defective ZnFe ₂ O ₄ nanorods with oxygen vacancy for photoelectrochemical water splitting Kim, Ju Hun; Jang, Youn Jeong; Kim, Jin Hyun Nanoscale, Vol. 7, Issue 45 https://doi.org/10.1039/C5NR05812K	journal	January 2015
Plasma-Engraved Co ₃ O ₄ Nanosheets with Oxygen Vacancies and High Surface Area for the Oxygen Evolution Reaction Xu, Lei; Jiang, Qianqian; Xiao, Zhaohui Angewandte Chemie International Edition, Vol. 55, Issue 17 https://doi.org/10.1002/anie.201600687	journal	March 2016
Using Surface Segregation To Design Stable Ru-Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments Danilovic, Nemanja; Subbaraman, Ramachandran; Chang, Kee Chul Angewandte Chemie International Edition, Vol. 53, Issue 51 https://doi.org/10.1002/anie.201406455	journal	October 2014
Synthesis and catalysis of chemically reduced metal–metalloid amorphous alloys Pei, Yan; Zhou, Gongbing; Luan, Nguyen Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35182j	journal	January 2012
RuO2 electronic structure and lattice strain dual engineering for enhanced acidic oxygen evolution reaction performance Qin, Yin; Yu, Tingting; Deng, Sihao Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-31468-0	journal	July 2022
In-situ reconstructed Ru atom array on α-MnO2 with enhanced performance for acidic water oxidation Lin, Chao; Li, Ji-Li; Li, Xiaopeng Nature Catalysis, Vol. 4, Issue 12 https://doi.org/10.1038/s41929-021-00703-0	journal	December 2021
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation Bao, Jian; Zhang, Xiaodong; Fan, Bo Angewandte Chemie International Edition, Vol. 54, Issue 25 https://doi.org/10.1002/anie.201502226	journal	May 2015
In situ X-ray absorption spectroscopy of transition metal based water oxidation catalysts van Oversteeg, Christina H. M.; Doan, Hoang Q.; de Groot, Frank M. F. Chemical Society Reviews, Vol. 46, Issue 1 https://doi.org/10.1039/C6CS00230G	journal	January 2017
Electrochemical Dissolution of Iridium and Iridium Oxide Particles in Acidic Media: Transmission Electron Microscopy, Electrochemical Flow Cell Coupled to Inductively Coupled Plasma Mass Spectrometry, and X-ray Absorption Spectroscopy Study Jovanovič, Primož; Hodnik, Nejc; Ruiz-Zepeda, Francisco Journal of the American Chemical Society, Vol. 139, Issue 36 https://doi.org/10.1021/jacs.7b08071	journal	August 2017
Strain Regulation to Optimize the Acidic Water Oxidation Performance of Atomic‐Layer IrO _x Meng, Ge; Sun, Wenming; Mon, Aye Aye Advanced Materials, Vol. 31, Issue 37 https://doi.org/10.1002/adma.201903616	journal	July 2019
Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide Cabán-Acevedo, Miguel; Stone, Michael L.; Schmidt, J. R. Nature Materials, Vol. 14, Issue 12 https://doi.org/10.1038/nmat4410	journal	September 2015
Free Electrons to Molecular Bonds and Back: Closing the Energetic Oxygen Reduction (ORR)–Oxygen Evolution (OER) Cycle Using Core–Shell Nanoelectrocatalysts Strasser, Peter Accounts of Chemical Research, Vol. 49, Issue 11 https://doi.org/10.1021/acs.accounts.6b00346	journal	October 2016
Iridium Oxide for the Oxygen Evolution Reaction: Correlation between Particle Size, Morphology, and the Surface Hydroxo Layer from Operando XAS Abbott, Daniel F.; Lebedev, Dmitry; Waltar, Kay Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b02625	journal	September 2016
Crystalline nickel manganese antimonate as a stable water-oxidation catalyst in aqueous 1.0 M H ₂ SO ₄ Moreno-Hernandez, Ivan A.; MacFarland, Clara A.; Read, Carlos G. Energy & Environmental Science, Vol. 10, Issue 10 https://doi.org/10.1039/C7EE01486D	journal	January 2017
A highly active and stable IrO _x /SrIrO ₃ catalyst for the oxygen evolution reaction Seitz, Linsey C.; Dickens, Colin F.; Nishio, Kazunori Science, Vol. 353, Issue 6303 https://doi.org/10.1126/science.aaf5050	journal	September 2016
Reduced Mesoporous Co ₃ O ₄ Nanowires as Efficient Water Oxidation Electrocatalysts and Supercapacitor Electrodes Wang, Yongcheng; Zhou, Tong; Jiang, Kun Advanced Energy Materials, Vol. 4, Issue 16 https://doi.org/10.1002/aenm.201400696	journal	July 2014
Alternative energy technologies Dresselhaus, M. S.; Thomas, I. L. Nature, Vol. 414, Issue 6861 https://doi.org/10.1038/35104599	journal	November 2001
Intercalated Iridium Diselenide Electrocatalysts for Efficient pH‐Universal Water Splitting Zheng, Tingting; Shang, Chunyan; He, Zhihai Angewandte Chemie International Edition, Vol. 58, Issue 41 https://doi.org/10.1002/anie.201909369	journal	October 2019
X-Ray spectroscopy of electrochemically deposited iridium oxide films: detection of multiple sites through structural disorder Hillman, A. Robert; Skopek, Magdalena A.; Gurman, Stephen J. Phys. Chem. Chem. Phys., Vol. 13, Issue 12 https://doi.org/10.1039/C0CP01472A	journal	January 2011
Water-Splitting Electrocatalysis in Acid Conditions Using Ruthenate-Iridate Pyrochlores Sardar, Kripasindhu; Petrucco, Enrico; Hiley, Craig I. Angewandte Chemie International Edition, Vol. 53, Issue 41 https://doi.org/10.1002/anie.201406668	journal	September 2014
In-situ identification of RuO4 as the corrosion product during oxygen evolution on ruthenium in acid media Kötz, R.; Stucki, S.; Scherson, D. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 172, Issue 1-2 https://doi.org/10.1016/0022-0728(84)80187-4	journal	August 1984
Perspectives on Low-Temperature Electrolysis and Potential for Renewable Hydrogen at Scale Ayers, Katherine; Danilovic, Nemanja; Ouimet, Ryan Annual Review of Chemical and Biomolecular Engineering, Vol. 10, Issue 1 https://doi.org/10.1146/annurev-chembioeng-060718-030241	journal	June 2019
Powering the planet with solar fuel Gray, Harry B. Nature Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/nchem.141	journal	April 2009
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong Nature Chemistry, Vol. 9, Issue 5 https://doi.org/10.1038/nchem.2695	journal	January 2017
Cobalt Assisted Synthesis of IrCu Hollow Octahedral Nanocages as Highly Active Electrocatalysts toward Oxygen Evolution Reaction Kwon, Taehyun; Hwang, Hyeyoun; Sa, Young Jin Advanced Functional Materials, Vol. 27, Issue 7, Article No. 1604688 https://doi.org/10.1002/adfm.201604688	journal	January 2017
Oxide-supported Ir nanodendrites with high activity and durability for the oxygen evolution reaction in acid PEM water electrolyzers Oh, Hyung-Suk; Nong, Hong Nhan; Reier, Tobias Chemical Science, Vol. 6, Issue 6 https://doi.org/10.1039/C5SC00518C	journal	January 2015
A pentanuclear iron catalyst designed for water oxidation Okamura, Masaya; Kondo, Mio; Kuga, Reiko Nature, Vol. 530, Issue 7591 https://doi.org/10.1038/nature16529	journal	February 2016
A general synthesis approach for amorphous noble metal nanosheets Wu, Geng; Zheng, Xusheng; Cui, Peixin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12859-2	journal	October 2019
A review on fundamentals for designing oxygen evolution electrocatalysts Song, Jiajia; Wei, Chao; Huang, Zhen-Feng Chemical Society Reviews, Vol. 49, Issue 7 https://doi.org/10.1039/C9CS00607A	journal	January 2020
The stability number as a metric for electrocatalyst stability benchmarking Geiger, Simon; Kasian, Olga; Ledendecker, Marc Nature Catalysis, Vol. 1, Issue 7 https://doi.org/10.1038/s41929-018-0085-6	journal	June 2018
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P. Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730 https://doi.org/10.1016/j.apsusc.2010.10.051	journal	January 2011
Engineering Metallic Heterostructure Based on Ni₃N and 2M‐MoS₂ for Alkaline Water Electrolysis with Industry‐Compatible Current Density and Stability Wu, Tong; Song, Erhong; Zhang, Shaoning Advanced Materials, Vol. 34, Issue 9 https://doi.org/10.1002/adma.202108505	journal	January 2022
Intrinsically stable in situ generated electrocatalyst for long-term oxidation of acidic water at up to 80 °C Chatti, Manjunath; Gardiner, James L.; Fournier, Maxime Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0277-8	journal	May 2019
A universal principle for a rational design of single-atom electrocatalysts Xu, Haoxiang; Cheng, Daojian; Cao, Dapeng Nature Catalysis, Vol. 1, Issue 5 https://doi.org/10.1038/s41929-018-0063-z	journal	April 2018
Control of p- and n-type conductivities in Li-doped ZnO thin films Lu, J. G.; Zhang, Y. Z.; Ye, Z. Z. Applied Physics Letters, Vol. 89, Issue 11 https://doi.org/10.1063/1.2354034	journal	September 2006
Oxygen evolution at RuO2(x)+Co3O4(1−x) electrodes from acid solution Da Silva, L. M.; Boodts, J. F. C.; De Faria, L. A. Electrochimica Acta, Vol. 46, Issue 9 https://doi.org/10.1016/S0013-4686(00)00716-7	journal	February 2001
Resolving ruthenium: XPS studies of common ruthenium materials Morgan, David J. Surface and Interface Analysis, Vol. 47, Issue 11 https://doi.org/10.1002/sia.5852	journal	September 2015
Crystalline Cobalt Oxide Films for Sustained Electrocatalytic Oxygen Evolution under Strongly Acidic Conditions Mondschein, Jared S.; Callejas, Juan F.; Read, Carlos G. Chemistry of Materials, Vol. 29, Issue 3 https://doi.org/10.1021/acs.chemmater.6b02879	journal	January 2017
Oxygen Electrochemistry as a Cornerstone for Sustainable Energy Conversion Katsounaros, Ioannis; Cherevko, Serhiy; Zeradjanin, Aleksandar R. Angewandte Chemie International Edition, Vol. 53, Issue 1 https://doi.org/10.1002/anie.201306588	journal	December 2013
The electronic structure of iridium oxide electrodes active in water splitting Pfeifer, V.; Jones, T. E.; Velasco Vélez, J. J. Physical Chemistry Chemical Physics, Vol. 18, Issue 4 https://doi.org/10.1039/C5CP06997A	journal	January 2016
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico ChemCatChem, Vol. 3, Issue 7 https://doi.org/10.1002/cctc.201000397	journal	March 2011
A unique oxygen ligand environment facilitates water oxidation in hole-doped IrNiOx core–shell electrocatalysts Nong, Hong Nhan; Reier, Tobias; Oh, Hyung-Suk Nature Catalysis, Vol. 1, Issue 11 https://doi.org/10.1038/s41929-018-0153-y	journal	October 2018
Ferromagnetism in Li doped ZnO nanoparticles: The role of interstitial Li Ullah Awan, Saif; Hasanain, S. K.; Bertino, Massimo F. Journal of Applied Physics, Vol. 112, Issue 10 https://doi.org/10.1063/1.4767364	journal	November 2012
Amorphous Metallic NiFeP: A Conductive Bulk Material Achieving High Activity for Oxygen Evolution Reaction in Both Alkaline and Acidic Media Hu, Fei; Zhu, Shengli; Chen, Shuangming Advanced Materials, Vol. 29, Issue 32 https://doi.org/10.1002/adma.201606570	journal	June 2017
IrO2/Nb–TiO2 electrocatalyst for oxygen evolution reaction in acidic medium Hu, Wei; Chen, Shengli; Xia, Qinghua International Journal of Hydrogen Energy, Vol. 39, Issue 13 https://doi.org/10.1016/j.ijhydene.2014.02.114	journal	April 2014
Bimetallic Ru–Co Clusters Derived from a Confined Alloying Process within Zeolite–Imidazolate Frameworks for Efficient NH ₃ Decomposition and Synthesis Yang, Jian; He, Dongsheng; Chen, Wenxing ACS Applied Materials & Interfaces, Vol. 9, Issue 45 https://doi.org/10.1021/acsami.7b14134	journal	November 2017
Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction Grimaud, Alexis; Demortière, Arnaud; Saubanère, Matthieu Nature Energy, Vol. 2, Issue 1 https://doi.org/10.1038/nenergy.2016.189	journal	December 2016
Electrochemical Catalyst–Support Effects and Their Stabilizing Role for IrO _x Nanoparticle Catalysts during the Oxygen Evolution Reaction Oh, Hyung-Suk; Nong, Hong Nhan; Reier, Tobias Journal of the American Chemical Society, Vol. 138, Issue 38 https://doi.org/10.1021/jacs.6b07199	journal	September 2016
La- and Mn-doped cobalt spinel oxygen evolution catalyst for proton exchange membrane electrolysis Chong, Lina; Gao, Guoping; Wen, Jianguo Science, Vol. 380, Issue 6645 https://doi.org/10.1126/science.ade1499	journal	May 2023
Atomic Iridium Incorporated in Cobalt Hydroxide for Efficient Oxygen Evolution Catalysis in Neutral Electrolyte Zhang, Youkui; Wu, Chuanqiang; Jiang, Hongliang Advanced Materials, Vol. 30, Issue 18 https://doi.org/10.1002/adma.201707522	journal	March 2018
Chemistry of active oxygen in RuO _x and its influence on the atomic layer deposition of TiO ₂ films Jeon, Woojin; Lee, Woongkyu; Yoo, Yeon Woo J. Mater. Chem. C, Vol. 2, Issue 46 https://doi.org/10.1039/C4TC01381F	journal	January 2014
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Electrocatalytic Oxygen Evolution Reaction in Acidic Environments - Reaction Mechanisms and Catalysts Reier, Tobias; Nong, Hong Nhan; Teschner, Detre Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601275	journal	October 2016
Ni–Co Codoping Breaks the Limitation of Single-Metal-Doped IrO₂ with Higher Oxygen Evolution Reaction Performance and Less Iridium Zaman, Waqas Qamar; Wang, Zhiqiang; Sun, Wei ACS Energy Letters, Vol. 2, Issue 12 https://doi.org/10.1021/acsenergylett.7b01032	journal	November 2017
Charge-Redistribution-Enhanced Nanocrystalline Ru@IrOx Electrocatalysts for Oxygen Evolution in Acidic Media Shan, Jieqiong; Guo, Chunxian; Zhu, Yihan Chem, Vol. 5, Issue 2 https://doi.org/10.1016/j.chempr.2018.11.010	journal	February 2019
Catalyst Stability Benchmarking for the Oxygen Evolution Reaction: The Importance of Backing Electrode Material and Dissolution in Accelerated Aging Studies Geiger, Simon; Kasian, Olga; Mingers, Andrea M. ChemSusChem, Vol. 10, Issue 21 https://doi.org/10.1002/cssc.201701523	journal	October 2017
Iridium-Based Multimetallic Nanoframe@Nanoframe Structure: An Efficient and Robust Electrocatalyst toward Oxygen Evolution Reaction Park, Jongsik; Sa, Young Jin; Baik, Hionsuck ACS Nano, Vol. 11, Issue 6 https://doi.org/10.1021/acsnano.7b00233	journal	May 2017
The role of van der Waals forces in water adsorption on metals Carrasco, Javier; Klimeš, Jiří; Michaelides, Angelos The Journal of Chemical Physics, Vol. 138, Issue 2 https://doi.org/10.1063/1.4773901	journal	January 2013
Oxygen evolution on Ru and RuO2 electrodes studied using isotope labelling and on-line mass spectrometry Wohlfahrt-Mehrens, M.; Heitbaum, J. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 237, Issue 2 https://doi.org/10.1016/0022-0728(87)85237-3	journal	November 1987
Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis Smith, Rodney D. L.; Prévot, Mathieu S.; Fagan, Randal D. Science, Vol. 340, Issue 6128 https://doi.org/10.1126/science.1233638	journal	March 2013
A comprehensive review on PEM water electrolysis Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934 https://doi.org/10.1016/j.ijhydene.2013.01.151	journal	April 2013
A Fundamental Relationship between Reaction Mechanism and Stability in Metal Oxide Catalysts for Oxygen Evolution Rong, Xi; Parolin, Jules; Kolpak, Alexie M. ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02432	journal	January 2016
Low Overpotential in Vacancy-Rich Ultrathin CoSe ₂ Nanosheets for Water Oxidation Liu, Youwen; Cheng, Hao; Lyu, Mengjie Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja5085157	journal	October 2014

Similar Records

Directed surfaces structures and interfaces for enhanced electrocatalyst activity, selectivity, and stability for energy conversion reactions

Technical Report · Wed Apr 20 00:00:00 EDT 2016 · OSTI ID:1995874

Jaramillo, Thomas F.

Mesoporous Ruthenium/Ruthenium Oxide Thin Films: Active Electrocatalysts for the Oxygen Evolution Reaction

Journal Article · Tue Jul 25 00:00:00 EDT 2017 · ChemElectroChem · OSTI ID:1995874

Kibsgaard, Jakob; Hellstern, Thomas R.; Choi, Shin‐Jung; +2 more

Highly Active, Durable Dispersed Iridium Nanocatalysts for PEM Water Electrolyzers

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Journal of the Electrochemical Society · OSTI ID:1995874

Zhao, Shuai; Stocks, Allison; Rasimick, Brian; +2 more

Title: Synergistic Co─Ir/Ru Composite Electrocatalysts Impart Efficient and Durable Oxygen Evolution Catalysis in Acid

Citation Formats

References (66)

Similar Records

Related Subjects