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Understanding the Catalytic Active Sites of Crystalline CoSb x O y for Electrochemical Chlorine Evolution

Journal Article · · ACS Applied Materials and Interfaces
 [1];  [2];  [3];  [3];  [4];  [1]
  1. Linde Laboratories, California Institute of Technology, Pasadena, California 91125, United States
  2. Department of Civil and Environmental Engineering, Stanford University, Stanford, California 94305, United States
  3. Department of Civil and Environmental Engineering, University of Massachusetts Amherst, Amherst, Massachusetts 01003, United States
  4. Department of Civil and Environmental Engineering, Stanford University, Stanford, California 94305, United States, Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States

Not Available

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1995833
Alternate ID(s):
OSTI ID: 1998846
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 34 Vol. 15; ISSN 1944-8244
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (63)

Controlling Selectivity in the Chlorine Evolution Reaction over RuO 2 -Based Catalysts journal August 2014
Controlling Stability and Selectivity in the Competing Chlorine and Oxygen Evolution Reaction over Transition Metal Oxide Electrodes journal July 2019
Role of Water in the Chlorine Evolution Reaction at RuO2-Based Electrodes-Understanding Electrocatalysis as a Resonance Phenomenon journal August 2012
Contributions of electrochemical oxidation to waste-water treatment: fundamentals and review of applications journal December 2009
Enhanced NH3-SCR activity of Sb-V/CeO2–TiO2 catalyst at low temperatures by synthesis modification journal November 2015
Evaluation of the technoeconomic feasibility of electrochemical hydrogen peroxide production for decentralized water treatment journal July 2020
Acid-stable antimonate based catalysts for the electrocatalytic oxygen evolution reaction journal November 2022
Microscopic Insights into the Chlorine Evolution Reaction on RuO2(110): a Mechanistic Ab Initio Atomistic Thermodynamics Study journal September 2014
Surface structure of CoO$z.sbnd;MoO3/Al2O3 catalysts studied by X-ray photoelectron spectroscopy journal October 1980
An investigation of the flame retardation mechanism of polypropylene containing a chlorine flame retardant system by XPS(ESCA) journal January 1991
X-ray photoelectron spectra of antimony oxides journal November 1989
The oxygen and chlorine evolution reactions at titanium oxide electrodes modified with platinum journal May 1998
Studies on the SbOx species of SbOx/SiO2 catalysts for methane-selective oxidation to formaldehyde journal May 2006
The enhanced performance of Sb-modified Cu/TiO2 catalyst for selective catalytic reduction of NOx with NH3 journal May 2019
A selective and efficient precious metal-free electrocatalyst for chlorine evolution reaction: An experimental and computational study journal October 2021
Oxygen and chlorine evolution on RuO2+TiO2+CeO2+Nb2O5 mixed oxide electrodes journal April 2006
Parallel oxygen and chlorine evolution on Ru1−xNixO2−y nanostructured electrodes journal September 2008
Novel Sb-doped ruthenium oxide electrode with ordered nanotube structure and its electrocatalytic activity toward chlorine evolution journal February 2013
Ti atoms in Ru0.3Ti0.7O2 mixed oxides form active and selective sites for electrochemical chlorine evolution journal November 2014
Microstructure, morphology and electrochemical property of RuO270SnO230mol% and RuO230SnO270mol% coatings journal March 2007
Ultrathin multilayer Sb-SnO2/IrTaOx/TiO2 nanotube arrays as anodes for the selective oxidation of chloride ions journal November 2020
Decoupling structure-sensitive deactivation mechanisms of Ir/IrOx electrocatalysts toward oxygen evolution reaction journal March 2019
Anomalous potential dependence of conducting property in black titania nanotube arrays for electrocatalytic chlorine evolution journal January 2020
On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure journal May 2005
Measurement of competition between oxygen evolution and chlorine evolution using rotating ring-disk electrode voltammetry journal June 2018
Utilization of the catalyst layer of dimensionally stable anodes. Part 2: Impact of spatial current distribution on electrocatalytic performance journal November 2018
Decentralized approaches to wastewater treatment and management: Applicability in developing countries journal January 2009
Sb incorporated into oxides enhances stability in acid during the oxygen evolution reaction by inhibiting structural distortion journal June 2023
Field testing of a household-scale onsite blackwater treatment system in South Africa journal February 2020
Electrochemical disinfection of toilet wastewater using wastewater electrolysis cell journal April 2016
Visualization of Chlorine Evolution at Dimensionally Stable Anodes by Means of Scanning Electrochemical Microscopy journal September 2011
Selectivity between Oxygen and Chlorine Evolution in the Chlor-Alkali and Chlorate Processes journal February 2016
Multilayer Heterojunction Anodes for Saline Wastewater Treatment: Design Strategies and Reactive Species Generation Mechanisms journal July 2016
Mixed Metal Oxide Electrodes and the Chlorine Evolution Reaction journal September 2021
Electrochemical Synthesis and Investigation of Stoichiometric, Phase - Pure CoSb 2 O 6 and MnSb 2 O 6 Electrodes for the Oxygen Evolution Reaction in Acidic Media journal June 2020
Descriptive Role of Pt/PtOx Ratio on the Selective Chlorine Evolution Reaction under Polarity Reversal as Studied by Scanning Electrochemical Microscopy journal July 2021
Quantifying Confidence in DFT Predicted Surface Pourbaix Diagrams and Associated Reaction Pathways for Chlorine Evolution journal August 2018
Selectivity Trends Between Oxygen Evolution and Chlorine Evolution on Iridium-Based Double Perovskites in Acidic Media journal July 2019
Extensive Active-Site Formation in Trirutile CoSb 2 O 6 by Oxygen Vacancy for Oxygen Evolution Reaction in Anion Exchange Membrane Water Splitting journal January 2021
Stability and Activity of Cobalt Antimonate for Oxygen Reduction in Strong Acid journal February 2022
Dimensionally Stable Ru/Ir/TiO 2 -Anodes with Tailored Mesoporosity for Efficient Electrochemical Chlorine Evolution journal April 2013
The Release of Lead from the Reduction of Lead Oxide (PbO 2 ) by Natural Organic Matter journal January 2008
Kinetics of the Reductive Dissolution of Lead(IV) Oxide by Iodide journal May 2012
Role of Pb(II) Defects in the Mechanism of Dissolution of Plattnerite (β-PbO 2 ) in Water under Depleting Chlorine Conditions journal October 2014
XPS studies of solvated metal atom dispersed (SMAD) catalysts. Evidence for layered cobalt-manganese particles on alumina and silica journal January 1991
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction journal October 2013
Electrochemical Dissolution of Iridium and Iridium Oxide Particles in Acidic Media: Transmission Electron Microscopy, Electrochemical Flow Cell Coupled to Inductively Coupled Plasma Mass Spectrometry, and X-ray Absorption Spectroscopy Study journal August 2017
Hierarchically Structured Cobalt Oxide (Co 3 O 4 ):  The Morphology Control and Its Potential in Sensors journal August 2006
The Role of TiO 2 Doping on RuO 2 -Coated Electrodes for the Water Oxidation Reaction journal February 2013
Electrochemical chlorine evolution at rutile oxide (110) surfaces journal January 2010
On the faradaic selectivity and the role of surface inhomogeneity during the chlorine evolution reaction on ternary Ti–Ru–Ir mixed metal oxide electrocatalysts journal January 2014
Crystalline nickel manganese antimonate as a stable water-oxidation catalyst in aqueous 1.0 M H 2 SO 4 journal January 2017
Enhancing the activity of oxygen-evolution and chlorine-evolution electrocatalysts by atomic layer deposition of TiO 2 journal January 2019
Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction journal January 2019
Design and preliminary implementation of onsite electrochemical wastewater treatment and recycling toilets for the developing world journal January 2018
Co 3 O 4 nanobelt arrays assembled with ultrathin nanosheets as highly efficient and stable electrocatalysts for the chlorine evolution reaction journal January 2018
In situ incorporation of cobalt nanoclusters and nitrogen into the carbon matrix: a bifunctional catalyst for the oxygen depolarized cathode and chlorine evolution in HCl electrolysis journal January 2019
Microstructural impact of anodic coatings on the electrochemical chlorine evolution reaction journal January 2012
Rational design of the electrode morphology for oxygen evolution – enhancing the performance for catalytic water oxidation journal January 2014
Emerging solutions to the water challenges of an urbanizing world journal May 2016
Electrochemical dissolution of Co3O4 in acidic solutions journal October 2009
Anodic Electrocatalytic Coatings for Electrolytic Chlorine Production: A Review journal December 2012
Sb-Containing Metal Oxide Catalysts for the Selective Catalytic Reduction of NOx with NH3 journal October 2020

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