A Porous Crystalline Nitrone‐Linked Covalent Organic Framework**

Kurandina, Daria; Huang, Banruo; Xu, Wentao; Hanikel, Nikita; Darù, Andrea; Stroscio, Gautam D.; Wang, Kaiyu; Gagliardi, Laura; Toste, F. Dean; Yaghi, Omar M.

doi:10.1002/ange.202307674

A Porous Crystalline Nitrone‐Linked Covalent Organic Framework**

Journal Article · Mon Jul 24 00:00:00 EDT 2023 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.202307674· OSTI ID:1995556

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Department of Chemistry and Kavli Energy Nanoscience Institute University of California, Berkeley Berkeley CA 94720 USA
Department of Chemistry University of California, Berkley Berkeley CA 94720 USA
Department of Chemistry Pritzker School of Molecular Engineering Chicago Center for Theoretical Chemistry University of Chicago Chicago IL 60637 USA
Department of Chemistry Kavli Energy Nanoscience Institute and Bakar Institute of Digital Materials for the Planet Division of Computing, Data Science, and Society University of California Berkeley CA 94720 USA
Department of Chemistry Kavli Energy Nanoscience Institute and Bakar Institute of Digital Materials for the Planet Division of Computing, Data Science, and Society University of California Berkeley CA 94720 USA, UC Berkeley—KACST Joint Center of Excellence for Nanomaterials for Clean Energy Applications King Abdulaziz City for Science and Technology Riyadh 11442 Saudi Arabia

Abstract

Herein, we report the synthesis of a nitrone‐linked covalent organic framework, COF‐115, by combining N , N′ , N′ , N ′′′‐(ethene‐1, 1, 2, 2‐tetrayltetrakis(benzene‐4, 1‐diyl))tetrakis(hydroxylamine) and terephthaladehyde via a polycondensation reaction. The formation of the nitrone functionality was confirmed by solid‐state ¹³ C multi cross‐polarization magic angle spinning NMR spectroscopy of the ¹³ C‐isotope‐labeled COF‐115 and Fourier‐transform infrared spectroscopy. The permanent porosity of COF‐115 was evaluated through low‐pressure N ₂ , CO ₂ , and H ₂ sorption experiments. Water vapor and carbon dioxide sorption analysis of COF‐115 and the isoreticular imine‐linked COF indicated a superior potential of N ‐oxide‐based porous materials for atmospheric water harvesting and CO ₂ capture applications. Density functional theory calculations provided valuable insights into the difference between the adsorption properties of these COFs. Lastly, photoinduced rearrangement of COF‐115 to the associated amide‐linked material was successfully demonstrated.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1995556

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 36 Vol. 135; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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