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Inorganic Hydrogeochemistry in the 21st Century

Journal Article · · Ground Water
DOI:https://doi.org/10.1111/gwat.13342· OSTI ID:1995335
;  [1];  [2]
  1. Department of Earth and Environmental Sciences University of Kentucky 101 Slone Bldg. Lexington KY 40506‐0053 USA
  2. Earth and Environmental Sciences Area Lawrence Berkeley National Laboratory Berkeley CA 94705 USA
Abstract

Chemical and isotopic processes occur in every segment of the hydrological cycle. Hydrogeochemistry—the subdiscipline that studies these processes—has seen a transformation from “witch's brew” to credible science since 2000. Going forward, hydrogeochemical research and applications are critical to meeting urgent societal needs of climate change mitigation and clean energy, such as (1) removing CO 2 from the atmosphere and storing gigatons of CO 2 in soils and aquifers to achieve net‐zero emissions, (2) securing critical minerals in support of the transition from fossil fuels to renewable energies, and (3) protecting water resources by adapting to a warming climate. In the last two decades, we have seen extensive activity and progress in four research areas of hydrogeochemistry related to water‐rock interactions: arsenic contamination of groundwater; the use of isotopic and chemical tracers to quantify groundwater recharge and submarine groundwater discharge; the kinetics of chemical reactions and the mineral‐water interface's control of contaminant fate and transport; and the transformation of geochemical modeling from an expert‐only exercise to a widely accessible tool. In the future, embracing technological advances in machine learning, cyberinfrastructure, and isotope analytical tools will allow breakthrough research and expand the role of hydrogeochemistry in meeting society's needs for climate change mitigation and the transition from fossil fuels to renewable energies.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0022269
OSTI ID:
1995335
Journal Information:
Ground Water, Journal Name: Ground Water; ISSN 0017-467X
Publisher:
Wiley-BlackwellCopyright Statement
Country of Publication:
United States
Language:
English

References (74)

Processes governing arsenic retardation on Pleistocene sediments: Adsorption experiments and model-based analysis journal May 2017
Enhanced chemical weathering as a geoengineering strategy to reduce atmospheric carbon dioxide, supply nutrients, and mitigate ocean acidification: ENHANCED WEATHERING journal April 2013
Characterizing particle-scale equilibrium adsorption and kinetics of uranium(VI) desorption from U-contaminated sediments: RELATING URANIUM MASS-TRANSFER RATES TO MICROPOROSITY journal February 2013
Environmental Tracers in Subsurface Hydrology book January 2000
Water and Earthquakes book January 2021
Choosing appropriate techniques for quantifying groundwater recharge journal January 2002
Hydrochemical tracers in the middle Rio Grande Basin, USA: 2. Calibration of a groundwater-flow model journal April 2004
Geochemistry and the understanding of ground-water systems journal February 2005
Calibration of models using groundwater age journal September 2010
A comparison of recharge rates in aquifers of the United States based on groundwater-age data journal April 2011
Stable and radio-isotope analysis to determine recharge timing and paleoclimate of sandstone aquifers in central and southeast Libya journal February 2015
Reactive transport codes for subsurface environmental simulation journal September 2014
Evaluation of Potential Changes in Groundwater Quality in Response to CO2 Leakage from Deep Geologic Storage journal January 2010
Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar journal December 1984
Ground-water models cannot be validated journal January 1992
RES3T-Rossendorf expert system for surface and sorption thermodynamics journal March 2003
A review of the source, behaviour and distribution of arsenic in natural waters journal May 2002
Mechanism of arsenic release to groundwater, Bangladesh and West Bengal journal May 2000
Conceptual model of recharge to southeastern Badain Jaran Desert groundwater and lakes from environmental tracers journal December 2008
Geochemistry’s vital contribution to solving water resource problems journal June 2009
A database of dissolution and precipitation rates for clay-rocks minerals journal April 2015
SUPCRTBL: A revised and extended thermodynamic dataset and software package of SUPCRT92 journal May 2016
The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field? journal December 2003
A comprehensive and internally consistent mineral dissolution rate database: Part I: Primary silicate minerals and glasses journal May 2022
The role of electron donors in arsenic-release by redox-transformation of iron oxide minerals – A review journal March 2023
Societal use of fresh submarine groundwater discharge: An overlooked water resource journal August 2017
Sedimentogenesis and hydrobiogeochemistry of high arsenic Late Pleistocene-Holocene aquifer systems journal February 2019
Reactive chemical transport simulations of geologic carbon sequestration: Methods and applications journal September 2020
A new approach for measuring dissolution rates of silicate minerals by using silicon isotopes journal March 2013
Testing hypotheses of albite dissolution mechanisms at near-equilibrium using Si isotope tracers journal June 2021
On the potential of CO2–water–rock interactions for CO2 storage using a modified kinetic model journal July 2011
Rare earth minerals and resources in the world journal February 2006
Mixing, spreading and reaction in heterogeneous media: A brief review journal March 2011
Temporal and spatial variability of groundwater–surface water fluxes: Development and application of an analytical method using temperature time series journal March 2007
A review of methods for modelling environmental tracers in groundwater: Advantages of tracer concentration simulation journal November 2014
Ra and Rn isotopes as natural tracers of submarine groundwater discharge in Tampa Bay, Florida journal February 2007
A review of hydrogeochemical mineral exploration in the Atacama Desert, Chile journal September 2020
Elevated arsenic and manganese in groundwaters of Murshidabad, West Bengal, India journal August 2014
Occurrence, predictors and hazards of elevated groundwater arsenic across India through field observations and regional-scale AI-based modeling journal March 2021
Adsorption of As(V) and As(III) by nanocrystalline titanium dioxide journal June 2005
Machine-Learning Predictions of High Arsenic and High Manganese at Drinking Water Depths of the Glacial Aquifer System, Northern Continental United States journal April 2021
Estimating the High-Arsenic Domestic-Well Population in the Conterminous United States journal October 2017
Quality of Groundwater Used for Public Supply in the Continental United States: A Comprehensive Assessment journal October 2022
Comparison of Arsenic(V) and Arsenic(III) Sorption onto Iron Oxide Minerals:  Implications for Arsenic Mobility journal September 2003
Process-Based Reactive Transport Model To Quantify Arsenic Mobility during Aquifer Storage and Recovery of Potable Water journal August 2011
pH Dependence of Fenton Reagent Generation and As(III) Oxidation and Removal by Corrosion of Zero Valent Iron in Aerated Water journal October 2008
Application of the Surface Complexation Concept to Complex Mineral Assemblages journal October 1998
Estimate of recharge from radiocarbon dating of groundwater and numerical flow and transport modeling journal September 2000
Calibration of regional groundwater flow models: Working toward a better understanding of site-specific systems journal June 2003
Simulation of reactive transport of uranium(VI) in groundwater with variable chemical conditions: SIMULATION OF REACTIVE TRANSPORT OF URANIUM(VI) journal April 2006
A field-scale reactive transport model for U(VI) migration influenced by coupled multirate mass transfer and surface complexation reactions: A FIELD-SCALE REACTIVE TRANSPORT MODEL journal May 2010
Understanding the Hydrogeochemical Response of a Mountainous Watershed Using Integrated Surface‐Subsurface Flow and Reactive Transport Modeling journal August 2022
The use of simulation and multiple environmental tracers to quantify groundwater flow in a shallow aquifer journal February 1994
Large groundwater inputs to coastal waters revealed by 226Ra enrichments journal April 1996
Fresh groundwater discharge insignificant for the world’s oceans but important for coastal ecosystems journal March 2020
Stable isotopes show that earthquakes enhance permeability and release water from mountains journal June 2020
Renewable energy production will exacerbate mining threats to biodiversity journal September 2020
Groundwater discharge impacts marine isotope budgets of Li, Mg, Ca, Sr, and Ba journal January 2021
Global analysis and prediction of fluoride in groundwater journal August 2022
TeraGrid Science Gateways and Their Impact on Science journal November 2008
Limitations of the Use of Environmental Tracers to Infer Groundwater Age journal July 2014
Machine Learning Predictions of pH in the Glacial Aquifer System, Northern USA journal December 2020
Global Groundwater Solute Composition and Concentrations journal May 2022
SURFACE SCIENCE: How Minerals React with Water journal October 2001
Spatial and Temporal Variations of Groundwater Arsenic in South and Southeast Asia journal May 2010
Groundwater Arsenic Contamination Throughout China journal August 2013
Global threat of arsenic in groundwater journal May 2020
FutureWater Indiana: A science gateway for spatio-temporal modeling of water in Wabash basin with a focus on climate change conference July 2020
Forensic Stable Isotope Biogeochemistry journal June 2016
Groundwater Age and Groundwater Age Dating journal May 2008
Mineral Precipitation Kinetics book January 2009
Hydrogeochemistry in landslide research: a review journal March 2007
A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling report January 2004
Submarine Groundwater Discharge: Updates on Its Measurement Techniques, Geophysical Drivers, Magnitudes, and Effects journal October 2019

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