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Title: Reduction of Iron‐Ore Pellets Using Different Gas Mixtures and Temperatures

Journal Article · · Steel Research International

Direct reduction of iron ore (DRI) is gaining an increased attention due to the growing need to decarbonize industrial processes. The current industrial DRI processes are performed using reformed natural gas, which results in CO 2 emission, although it is less than carbothermic reduction in the blast furnace. Carbon‐free reduction may be realized through the utilization of green H 2 as a reducing agent, in place of natural gas. Herein, the effects of various gas mixtures and temperature on the reduction kinetics of the hematite iron‐ore pellets are focused on in this work. Pellets are reduced at 700, 800, 850, and 900 °C in hydrogen and using various gas mixes at 850 °C. Morphology of the pellets is investigated with the help of scanning electron microscopy and mercury intrusion porosimetry. The effects of temperature and gas composition on the reduction kinetics and porosity of the pellets are discussed. A notable effect of reduction rate on the internal structure of the pellets is detected, slower reduction rate yielded bigger pores offsetting the gas composition. Higher temperature results in coarser pores and higher porosity. Increase of CO content in the gas mix also leads to bigger pore size.

Sponsoring Organization:
USDOE
OSTI ID:
1995324
Journal Information:
Steel Research International, Journal Name: Steel Research International; ISSN 1611-3683
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (35)

Modeling of Isothermal Reduction of Hematite Pellets Using Hydrogen conference January 2022
70 Years of LD-Steelmaking—Quo Vadis? journal May 2022
The modeling of hematite reduction with hydrogen plus carbon monoxide mixtures: Part I. The behavior of single pellets journal November 1976
The origin and status of the Arrhenius equation journal April 1982
Toward a Fossil Free Future with HYBRIT: Development of Iron and Steelmaking Technology in Sweden and Finland journal July 2020
Influence of hydrogen and carbon monoxide on reduction behavior of iron oxide at high temperature: Effect on reduction gas concentrations journal July 2021
The kinetics of reduction of iron oxides at moderate temperatures journal June 1979
Solid state reaction kinetics of iron oxide reduction using hydrogen as a reducing agent journal June 2016
Reduction Behavior of Iron Ore Pellets with Simulated Coke Oven Gas and Natural Gas journal April 2013
DRI Apparent Density and Its Strength journal January 2005
Action rules of H2 and CO in gas-based direct reduction of iron ore pellets journal August 2012
CFD Study of an Energiron Reactor Fed With Different Concentrations of Hydrogen conference January 2020
Modeling Isothermal Reduction of Iron Ore Pellet Using Finite Element Analysis Method: Experiments & Validation journal November 2022
Hydrogen-based direct reduction of iron oxide at 700°C: Heterogeneity at pellet and microstructure scales journal August 2022
Reduction Behavior and Kinetics of Iron Ore Pellets under H2–N2 Atmosphere journal June 2018
Reduction of Iron Oxides with Hydrogen—A Review journal August 2019
Reduction kinetics of iron oxide pellets with H2 and CO mixtures journal July 2015
Hydrogen‐Based Direct Reduction of Iron Oxides Pellets Modeling journal March 2023
Hydrogen Ironmaking: How It Works journal July 2020
Gaseous reduction of iron oxides: Part III. Reduction-oxidation of porous and dense iron oxides and iron journal June 1972
Reduction kinetics, magnetic behavior and morphological changes during reduction of magnetite single crystal journal April 2007
Reduction of hematite (Fe 2 O 3 ) to metallic iron (Fe) by CO in a micro fluidized bed reaction analyzer: A multistep kinetics study journal July 2017
Metals Production and Metal Oxides Reduction Using Hydrogen: A Review journal January 2022
A Review on the Modeling of Gaseous Reduction of Iron Oxide Pellets journal October 2019
Direct reduction of iron ore pellets by H2 and CO: In-situ investigation of the structural transformation and reduction progression caused by atmosphere and temperature journal April 2022
Transactions and Communications journal May 1944
Kinetics of Reduction in Stages of Pellets Prepared from the Bayan Obo Iron Ore Concentrate journal February 2022
Experimental and Modeling Study on Reduction of Hematite Pellets by Hydrogen Gas journal January 2017
Kinetic Analysis of the Iron Oxide Reduction Using Hydrogen-Carbon Monoxide Mixtures as Reducing Agent journal January 2005
Influence of H2–H2O Content on the Reduction of Acid Iron Ore Pellets in a CO–CO2–N2 Reducing Atmosphere journal October 2020
Influence of the original structure on the kinetics of hydrogen reduction of hematite compacts. journal January 1988
Influence of particle size on the gaseous reduction of wustite at 900-1100.DEG.C. journal January 1985
Gaseous reduction of iron oxides: Part II. Pore characteristics of iron reduced from hematite in hydrogen journal November 1971
Kinetics of the low-temperature hydrogen reduction of magnetite concentrates journal January 2012
A Review on the Kinetics of Iron Ore Reduction by Hydrogen journal December 2021

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