skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Optically induced changes in the band structure of the Weyl charge-density-wave compound (TaSe4)2I

Journal Article · · JPhys Materials
ORCiD logo [1]; ORCiD logo [2];  [2]; ORCiD logo [3];  [4];  [2]; ORCiD logo [2];  [2];  [2]
  1. Politecnico di Milano, Milan (Italy); Ecole Polytechnique Federale Lausanne (EPFL) (Switzerland)
  2. Ecole Polytechnique Federale Lausanne (EPFL) (Switzerland)
  3. Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Materials Sciences Division; University of California, Berkeley, CA (United States)
  4. Elettra—Sincrotrone Trieste S.C.p.A., Trieste (Italy

Collective modes are responsible for the emergence of novel quantum phases in topological materials. In the quasi-one dimensional (1D) Weyl semimetal (TaSe4)2I, a charge density wave (CDW) opens band gaps at the Weyl points, thus turning the system into an axionic insulator. Melting the CDW would restore the Weyl phase, but 1D fluctuations extend the gapped regime far above the 3D transition temperature (TCDW = 263 K), thus preventing the investigation of this topological phase transition with conventional spectroscopic methods. Here we use a non-equilibrium approach: we perturb the CDW phase by photoexcitation, and we monitor the dynamical evolution of the band structure by time- and angle-resolved photoelectron spectroscopy. We find that, upon optical excitation, electrons populate the linearly dispersing states at the Fermi level (EF), and fill the CDW gap. The dynamics of both the charge carrier population and the band gap renormalization (BGR) show a fast component with a characteristic time scale of a few hundreds femtoseconds. However, the BGR also exhibits a second slow component on the µs time scale. The combination of an ultrafast response and of persistent changes in the spectral weight at E$$_\mathrm{F}$$, and the resulting sensitivity of the linearly dispersing states to optical excitations, may explain the high performances of (TaSe4)2I as a material for broadband infrared photodetectors.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); Swiss National Science Foundation (SNSF); European Research Council (ERC)
Grant/Contract Number:
AC02-05CH11231; 206021-157773; 407040-154056; H2020 ERCEA 695197 DYNAMOX; 182892
OSTI ID:
1994358
Journal Information:
JPhys Materials, Vol. 5, Issue 4; ISSN 2515-7639
Publisher:
IOP PublishingCopyright Statement
Country of Publication:
United States
Language:
English

References (56)

Spectroscopic Indications of Polaronic Carriers in the Quasi-One-Dimensional Conductor ( TaSe 4 ) 2 I journal November 2001
Generalized Gradient Approximation Made Simple journal October 1996
Ultrafast Optical Control of the Electronic Properties of Zr Te 5 journal November 2015
Ultrafast Sub‐100 fs All‐Optical Modulation and Efficient Third‐Harmonic Generation in Weyl Semimetal Niobium Phosphide Thin Films journal March 2022
Axionic charge-density wave in the Weyl semimetal (TaSe4)2I journal October 2019
Cosmology of the invisible axion journal January 1983
Weyl Metals journal March 2018
Photoinduced renormalization and electronic screening of quasi-two-dimensional Dirac states in BaNiS2 journal December 2020
A neutron scattering study of the quasi-one-dimensional conductor journal June 1998
A charge-density-wave topological semimetal journal January 2021
Ramifications of optical pumping on the interpretation of time-resolved photoemission experiments on graphene journal April 2015
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials journal September 2009
Recent ARPES experiments on quasi-1D bulk materials and artificial structures journal December 2008
Electronic Structure of Solids with Competing Periodic Potentials journal October 2000
Does (TaSe4)2I really harbor an axionic charge density wave? journal February 2022
Clocking the Melting Transition of Charge and Lattice Order in 1 T TaS 2 with Ultrafast Extreme-Ultraviolet Angle-Resolved Photoemission Spectroscopy journal October 2011
Electronic Instability in a Zero-Gap Semiconductor: The Charge-Density Wave in ( TaSe 4 ) 2 I journal June 2013
First-principles study of the low-temperature charge density wave phase in the quasi-one-dimensional Weyl chiral compound ( TaSe 4 ) 2 I journal May 2020
Realization of Epitaxial NbP and TaP Weyl Semimetal Thin Films journal February 2020
Fluctuation effects on the electrodynamics of quasi-one-dimensional conductors above the charge-density-wave transition journal August 1995
Electronic crystals: an experimental overview journal August 2012
Topological field theory of time-reversal invariant insulators journal November 2008
Pseudopotentials periodic table: From H to Pu journal December 2014
Surface charge induced Dirac band splitting in a charge density wave material (TaSe4)2I journal March 2021
Thermal conductivity of the charge-density-wave systems K 0.3 MoO 3 and ( TaSe 4 ) 2 I near the Peierls transition journal August 1989
Excitonic and lattice contributions to the charge density wave in 1 T TiS e 2 revealed by a phonon bottleneck journal September 2019
CP Conservation in the Presence of Pseudoparticles journal June 1977
Axion physics in condensed-matter systems journal September 2020
Absence of in-gap modes in charge density wave edge dislocations of the Weyl semimetal (TaSe4)2I journal November 2021
Fluctuation Effects at a Peierls Transition journal August 1973
High-performance near-infrared photodetector based on quasi one-dimensional layered (TaSe4)2I journal November 2021
Light-Induced Renormalization of the Dirac Quasiparticles in the Nodal-Line Semimetal ZrSiSe journal August 2020
Weyl and Dirac semimetals in three-dimensional solids journal January 2018
Topological quantum properties of chiral crystals journal October 2018
Chiral anomaly and transport in Weyl metals journal February 2015
Incommensurate superlattice reflections in quasi one dimensional conductors, (MSe4)2I (M=Ta and Nb) journal January 1984
Phonon Scattering in Semiconductors From Thermal Conductivity Studies journal April 1964
Preparation and structure of ditantalum iodide octaselenide, Ta 2 ISe 8 journal November 1982
Pump laser-induced space-charge effects in HHG-driven time- and angle-resolved photoelectron spectroscopy journal June 2016
Electronic structures of transition-metal tetrachalcogenides (MSe4)nI (M = Nb, Ta) journal April 1984
Time-resolved ARPES at LACUS: Band Structure and Ultrafast Electron Dynamics of Solids journal May 2017
Discovery of a Weyl fermion semimetal and topological Fermi arcs journal July 2015
Photocarrier-induced band-gap renormalization and ultrafast charge dynamics in black phosphorus journal April 2019
Electron propagation from a photo-excited surface: implications for time-resolved photoemission journal November 2013
Ultrafast Band Structure Control of a Two-Dimensional Heterostructure journal May 2016
Transient Electronic Structure and Melting of a Charge Density Wave in TbTe3 journal September 2008
Two applications of axion electrodynamics journal May 1987
Chiral anomaly, charge density waves, and axion strings from Weyl semimetals journal April 2013
Radial Spin Texture of the Weyl Fermions in Chiral Tellurium journal November 2020
Charge density wave transport in (TaSe4)2I journal April 1983
Large Fermi‐Energy Shift and Suppression of Trivial Surface States in NbP Weyl Semimetal Thin Films journal May 2021
Dynamics of charge density wave order in the quasi one dimensional conductor (TaSe4)2I probed by femtosecond optical spectroscopy journal July 2013
Time-domain classification of charge-density-wave insulators journal January 2012
Structural Evidence for Ta-Tetramerization Displacements in the Charge-Density-Wave Compound ( TaSe 4 ) 2 I from X-Ray Anomalous Diffraction journal June 2001
Advanced capabilities for materials modelling with Quantum ESPRESSO journal October 2017
Topological semimetal and Fermi-arc surface states in the electronic structure of pyrochlore iridates journal May 2011

Similar Records

First-principles study of the low-temperature charge density wave phase in the quasi-one-dimensional Weyl chiral compound (TaSe4)2I
Journal Article · Wed May 13 00:00:00 EDT 2020 · Physical Review B · OSTI ID:1994358

Chirality manipulation of ultrafast phase switches in a correlated CDW-Weyl semimetal
Journal Article · Fri Jan 26 00:00:00 EST 2024 · Nature Communications · OSTI ID:1994358

Surface charge induced Dirac band splitting in a charge density wave material ( Ta Se 4 ) 2 I
Journal Article · Tue Mar 23 00:00:00 EDT 2021 · Physical Review Research · OSTI ID:1994358