Molecular Structure and Conformational Design of Donor‐Acceptor Conjugated Polymers to Enable Predictable Optoelectronic Property

Cao, Zhiqiang; Tolba, Sara A.; Li, Zhaofan; Mason, Gage T.; Wang, Yang; Do, Changwoo; Rondeau‐Gagné, Simon; Xia, Wenjie; Gu, Xiaodan

doi:10.1002/adma.202302178

Title: Molecular Structure and Conformational Design of Donor‐Acceptor Conjugated Polymers to Enable Predictable Optoelectronic Property

Journal Article · Wed Jul 26 00:00:00 EDT 2023 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202302178· OSTI ID:1993899

Cao, Zhiqiang ^[1]; Tolba, Sara A. ^[2];

^[3]; Mason, Gage T. ^[4]; Wang, Yang ^[5]; Do, Changwoo ^[6]; Rondeau‐Gagné, Simon ^[4]; Xia, Wenjie ^[7];

^[1]

School of Polymer Science and Engineering Center for Optoelectronic Materials and Devices The University of Southern Mississippi Hattiesburg MS 39406 USA
Materials and Nanotechnology Program North Dakota State University Fargo ND 58108 USA
Department of Civil, Construction, and Environmental Engineering North Dakota State University Fargo ND 58108 USA
Department of Chemistry and Biochemistry University of Windsor Windsor Ontario N9B3P4 Canada
School of Materials Science and Engineering University of Science and Technology Beijing Beijing 100083 P. R. China
Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA
Department of Civil, Construction, and Environmental Engineering North Dakota State University Fargo ND 58108 USA, Department of Aerospace Engineering Iowa State University Ames IA 50011 USA

Abstract Tuning the optoelectronic properties of donor‐acceptor conjugated polymers (D‐A CPs) is of great importance in designing various organic optoelectronic devices. However, there remains a critical challenge in precise control of bandgap through synthetic approach, since the chain conformation also affects molecular orbital energy levels. Here, D‐A CPs with different acceptor units are explored that show an opposite trend in energy band gaps with the increasing length of oligothiophene donor units. By investigating their chain conformation and molecular orbital energy, it is found that the molecular orbital energy alignment between donor and acceptor units plays a crucial role in dictating the final optical bandgap of D‐A CPs. For polymers with staggered orbital energy alignment, the higher HOMO with increasing oligothiophene length leads to a narrowing of the optical bandgap despite decreased chain rigidity. On the other hand, for polymers with sandwiched orbital energy alignment, the increased band gap with increasing oligothiophene length originates from the reduction of bandwidth due to more localized charge density distribution. Thus, this work provides a molecular understanding of the role of backbone building blocks on the chain conformation and bandgaps of D‐A CPs for organic optoelectronic devices through the conformation design and segment orbital energy alignment.

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Sponsoring Organization:: USDOE

OSTI ID:: 1993899

Alternate ID(s):: OSTI ID: 1992567

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Vol. 35 Journal Issue: 41; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (72)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Annealing-Free High-Mobility Diketopyrrolopyrrole−Quaterthiophene Copolymer for Solution-Processed Organic Thin Film Transistors Li, Yuning; Sonar, Prashant; Singh, Samarendra P. Journal of the American Chemical Society, Vol. 133, Issue 7 https://doi.org/10.1021/ja1085996	journal	February 2011
A high-mobility electron-transporting polymer for printed transistors Yan, He; Chen, Zhihua; Zheng, Yan Nature, Vol. 457, Issue 7230, p. 679-686 https://doi.org/10.1038/nature07727	journal	January 2009
A new class of small band gap organic polymer conductors Havinga, E. E.; ten Hoeve, W.; Wynberg, H. Polymer Bulletin, Vol. 29, Issue 1-2 https://doi.org/10.1007/BF00558045	journal	August 1992
Self-assembly of donor–acceptor conjugated polymers induced by miscible ‘poor’ solvents Xi, Yuyin; Wolf, Caitlyn M.; Pozzo, Lilo D. Soft Matter, Vol. 15, Issue 8 https://doi.org/10.1039/C8SM02517G	journal	January 2019
High-Performance Air-Stable Organic Field-Effect Transistors: Isoindigo-Based Conjugated Polymers Lei, Ting; Cao, Yue; Fan, Yunlong Journal of the American Chemical Society, Vol. 133, Issue 16 https://doi.org/10.1021/ja111066r	journal	April 2011
Diketopyrrolopyrrole-Based π-Conjugated Copolymer Containing β-Unsubstituted Quintetthiophene Unit: A Promising Material Exhibiting High Hole-Mobility for Organic Thin-Film Transistors Yi, Zhengran; Sun, Xiangnan; Zhao, Yan Chemistry of Materials, Vol. 24, Issue 22 https://doi.org/10.1021/cm302341m	journal	November 2012
Synthesis, Electronic Structure, and Charge Transport Characteristics of Naphthalenediimide-Based Co-Polymers with Different Oligothiophene Donor Units Luzio, Alessandro; Fazzi, Daniele; Natali, Dario Advanced Functional Materials, Vol. 24, Issue 8 https://doi.org/10.1002/adfm.201302297	journal	October 2013
Synthesis and Characterization of Thiophene-Containing Naphthalene Diimide n-Type Copolymers for OFET Applications Durban, Matthew M.; Kazarinoff, Peter D.; Luscombe, Christine K. Macromolecules, Vol. 43, Issue 15 https://doi.org/10.1021/ma100997g	journal	August 2010
Recent Advances in the Development of Semiconducting DPP-Containing Polymers for Transistor Applications Nielsen, Christian B.; Turbiez, Mathieu; McCulloch, Iain Advanced Materials, Vol. 25, Issue 13 https://doi.org/10.1002/adma.201201795	journal	September 2012
para -Azaquinodimethane: A Compact Quinodimethane Variant as an Ambient Stable Building Block for High-Performance Low Band Gap Polymers Liu, Xuncheng; He, Bo; Anderson, Christopher L. Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b04031	journal	June 2017
DREIDING: a generic force field for molecular simulations Mayo, Stephen L.; Olafson, Barry D.; Goddard, William A. The Journal of Physical Chemistry, Vol. 94, Issue 26, p. 8897-8909 https://doi.org/10.1021/j100389a010	journal	December 1990
Effect of the Longer β-Unsubstituted Oliogothiophene Unit (6T and 7T) on the Organic Thin-Film Transistor Performances of Diketopyrrolopyrrole-Oliogothiophene Copolymers Yi, Zhengran; Ma, Lanchao; Chen, Bing Chemistry of Materials, Vol. 25, Issue 21 https://doi.org/10.1021/cm402381w	journal	October 2013
Design of High-Mobility Diketopyrrolopyrrole-Based π-Conjugated Copolymers for Organic Thin-Film Transistors Yi, Zhengran; Wang, Shuai; Liu, Yunqi Advanced Materials, Vol. 27, Issue 24 https://doi.org/10.1002/adma.201500401	journal	May 2015
Systematic Investigation of Solution-State Aggregation Effect on Electrical Conductivity in Doped Conjugated Polymers Zhou, Yang-Yang; Wang, Zi-Yuan; Yao, Ze-Fan CCS Chemistry, Vol. 3, Issue 10 https://doi.org/10.31635/ccschem.021.202101411	journal	October 2021
Diketopyrrolopyrrole (DPP)-based materials for organic photovoltaics Qu, Sanyin; Tian, He Chemical Communications, Vol. 48, Issue 25 https://doi.org/10.1039/c2cc17886a	journal	January 2012
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Attaining Melt Processing of Complementary Semiconducting Polymer Blends at 130 °C via Side-Chain Engineering Gumyusenge, Aristide; Zhao, Xikang; Zhao, Yan ACS Applied Materials & Interfaces, Vol. 10, Issue 5 https://doi.org/10.1021/acsami.7b19847	journal	January 2018
Chain conformations and phase behavior of conjugated polymers Kuei, Brooke; Gomez, Enrique D. Soft Matter, Vol. 13, Issue 1 https://doi.org/10.1039/C6SM00979D	journal	January 2017
25th Anniversary Article: Isoindigo-Based Polymers and Small Molecules for Bulk Heterojunction Solar Cells and Field Effect Transistors Wang, Ergang; Mammo, Wendimagegn; Andersson, Mats R. Advanced Materials, Vol. 26, Issue 12 https://doi.org/10.1002/adma.201304945	journal	February 2014
A Thienoisoindigo-Naphthalene Polymer with Ultrahigh Mobility of 14.4 cm ² /V·s That Substantially Exceeds Benchmark Values for Amorphous Silicon Semiconductors Kim, Gyoungsik; Kang, Seok-Ju; Dutta, Gitish K. Journal of the American Chemical Society, Vol. 136, Issue 26 https://doi.org/10.1021/ja504537v	journal	June 2014
Aggregation and Solubility of a Model Conjugated Donor–Acceptor Polymer Reid, Daniel R.; Jackson, Nicholas E.; Bourque, Alexander J. The Journal of Physical Chemistry Letters, Vol. 9, Issue 16 https://doi.org/10.1021/acs.jpclett.8b01738	journal	July 2018
25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research Dou, Letian; You, Jingbi; Hong, Ziruo Advanced Materials, Vol. 25, Issue 46 https://doi.org/10.1002/adma.201302563	journal	September 2013
Synthesis of Conjugated Polymers for Organic Solar Cell Applications Cheng, Yen-Ju; Yang, Sheng-Hsiung; Hsu, Chain-Shu Chemical Reviews, Vol. 109, Issue 11 https://doi.org/10.1021/cr900182s	journal	November 2009
Importance of Nucleation during Morphology Evolution of the Blade-Cast PffBT4T-2OD-Based Organic Solar Cells Bi, Zhaozhao; Naveed, Hafiz Bilal; Mao, Yimin Macromolecules, Vol. 51, Issue 17 https://doi.org/10.1021/acs.macromol.8b01156	journal	August 2018
A new mixing of Hartree–Fock and local density‐functional theories Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 2 https://doi.org/10.1063/1.464304	journal	January 1993
Organic Light‐Emitting Diodes: Pushing Toward the Limits and Beyond Song, Jinouk; Lee, Hyeonwoo; Jeong, Eun Gyo Advanced Materials, Vol. 32, Issue 35 https://doi.org/10.1002/adma.201907539	journal	March 2020
Revealing temperature-dependent polymer aggregation in solution with small-angle X-ray scattering Abdelsamie, Maged; Chaney, Thomas P.; Yan, Hongping Journal of Materials Chemistry A, Vol. 10, Issue 4 https://doi.org/10.1039/D1TA09086K	journal	January 2022
General Force-Field Parametrization Scheme for Molecular Dynamics Simulations of Conjugated Materials in Solution Wildman, Jack; Repiščák, Peter; Paterson, Martin J. Journal of Chemical Theory and Computation, Vol. 12, Issue 8 https://doi.org/10.1021/acs.jctc.5b01195	journal	July 2016
Integrated Optoelectronic Devices Based on Conjugated Polymers Sirringhaus, H. Science, Vol. 280, Issue 5370 https://doi.org/10.1126/science.280.5370.1741	journal	June 1998
The extended Q -range small-angle neutron scattering diffractometer at the SNS Zhao, J. K.; Gao, C. Y.; Liu, D. Journal of Applied Crystallography, Vol. 43, Issue 5 https://doi.org/10.1107/S002188981002217X	journal	July 2010
A quantum-chemical perspective into low optical-gap polymers for highly-efficient organic solar cells Risko, Chad; McGehee, Michael D.; Brédas, Jean-Luc Chem. Sci., Vol. 2, Issue 7 https://doi.org/10.1039/C0SC00642D	journal	January 2011
All-Atom Molecular Dynamics Simulation of Temperature Effects on the Structural, Thermodynamic, and Packing Properties of the Pure Amorphous and Pure Crystalline Phases of Regioregular P3HT Alexiadis, Orestis; Mavrantzas, Vlasis G. Macromolecules, Vol. 46, Issue 6 https://doi.org/10.1021/ma302211g	journal	March 2013
Efficient n‐Doping of Polymeric Semiconductors through Controlling the Dynamics of Solution‐State Polymer Aggregates Xiong, Miao; Yan, Xinwen; Li, Jia‐Tong Angewandte Chemie International Edition, Vol. 60, Issue 15 https://doi.org/10.1002/anie.202015216	journal	March 2021
Organic and Polymeric Semiconductors Enhanced by Noncovalent Conformational Locks Huang, Hui; Yang, Lei; Facchetti, Antonio Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00084	journal	July 2017
Effect of donor length on electronic structures and charge transport polarity for DTDPP-based D–A copolymers: a computational study based on a super-exchange model He, Feifei; Cheng, Changli; Geng, Hua Journal of Materials Chemistry A, Vol. 6, Issue 25 https://doi.org/10.1039/C8TA02175A	journal	January 2018
Chain Stiffness of Donor–Acceptor Conjugated Polymers in Solution Danielsen, Scott P. O.; Bridges, Colin R.; Segalman, Rachel A. Macromolecules, Vol. 55, Issue 2 https://doi.org/10.1021/acs.macromol.1c02229	journal	January 2022
Synthetic Principles Directing Charge Transport in Low-Band-Gap Dithienosilole–Benzothiadiazole Copolymers Beaujuge, Pierre M.; Tsao, Hoi Nok; Hansen, Michael Ryan Journal of the American Chemical Society, Vol. 134, Issue 21 https://doi.org/10.1021/ja301898h	journal	May 2012
Variable-Temperature Scattering and Spectroscopy Characterizations for Temperature-Dependent Solution Assembly of PffBT4T-Based Conjugated Polymers Cao, Zhiqiang; Ma, Guorong; Leng, Mingwan ACS Applied Polymer Materials, Vol. 4, Issue 5 https://doi.org/10.1021/acsapm.1c01511	journal	February 2022
A molecular dynamics method for simulations in the canonical ensemble Nosé, Shūichi Molecular Physics, Vol. 52, Issue 2 https://doi.org/10.1080/00268978400101201	journal	June 1984
Multifluorination toward High-Mobility Ambipolar and Unipolar n-Type Donor-Acceptor Conjugated Polymers Based on Isoindigo Gao, Yao; Deng, Yunfeng; Tian, Hongkun Advanced Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adma.201606217	journal	February 2017
Structure–property relationships of oligothiophene–isoindigo polymers for efficient bulk-heterojunction solar cells Ma, Zaifei; Sun, Wenjun; Himmelberger, Scott Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42989J	journal	January 2014
Non-fullerene acceptors for organic solar cells Yan, Cenqi; Barlow, Stephen; Wang, Zhaohui Nature Reviews Materials, Vol. 3, Issue 3 https://doi.org/10.1038/natrevmats.2018.3	journal	February 2018
Understanding Low Bandgap Polymer PTB7 and Optimizing Polymer Solar Cells Based on It Lu, Luyao; Yu, Luping Advanced Materials, Vol. 26, Issue 26 https://doi.org/10.1002/adma.201400384	journal	March 2014
The suite of small-angle neutron scattering instruments at Oak Ridge National Laboratory Heller, William T.; Cuneo, Matthew; Debeer-Schmitt, Lisa Journal of Applied Crystallography, Vol. 51, Issue 2 https://doi.org/10.1107/S1600576718001231	journal	February 2018
Design, Synthesis, and Structure–Property Relationships of Isoindigo-Based Conjugated Polymers Lei, Ting; Wang, Jie-Yu; Pei, Jian Accounts of Chemical Research, Vol. 47, Issue 4 https://doi.org/10.1021/ar400254j	journal	February 2014
Assessment of molecular dynamics simulations for amorphous poly(3-hexylthiophene) using neutron and X-ray scattering experiments Wolf, Caitlyn M.; Kanekal, Kiran H.; Yimer, Yeneneh Y. Soft Matter, Vol. 15, Issue 25 https://doi.org/10.1039/C9SM00807A	journal	January 2019
Low bandgap semiconducting polymers for polymeric photovoltaics Liu, Chang; Wang, Kai; Gong, Xiong Chemical Society Reviews, Vol. 45, Issue 17 https://doi.org/10.1039/C5CS00650C	journal	January 2016
Remarkable enhancement of charge carrier mobility of conjugated polymer field-effect transistors upon incorporating an ionic additive Luo, Hewei; Yu, Chenmin; Liu, Zitong Science Advances, Vol. 2, Issue 5 https://doi.org/10.1126/sciadv.1600076	journal	May 2016
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Record High Electron Mobility of 6.3 cm ² V ⁻¹ s ⁻¹ Achieved for Polymer Semiconductors Using a New Building Block Sun, Bin; Hong, Wei; Yan, Zhuangqing Advanced Materials, Vol. 26, Issue 17 https://doi.org/10.1002/adma.201305981	journal	March 2014
The donor–acceptor approach allows a black-to-transmissive switching polymeric electrochrome Beaujuge, P. M.; Ellinger, S.; Reynolds, J. R. Nature Materials, Vol. 7, Issue 10 https://doi.org/10.1038/nmat2272	journal	August 2008
Design of Near‐Infrared Nonfullerene Acceptor with Ultralow Nonradiative Voltage Loss for High‐Performance Semitransparent Ternary Organic Solar Cells Liu, Wuyue; Sun, Shaoming; Zhou, Liang Angewandte Chemie International Edition, Vol. 61, Issue 19 https://doi.org/10.1002/anie.202116111	journal	January 2022
Status and prospects for ternary organic photovoltaics Lu, Luyao; Kelly, Mary Allison; You, Wei Nature Photonics, Vol. 9, Issue 8 https://doi.org/10.1038/nphoton.2015.128	journal	July 2015
Significant Improvement of Unipolar n-Type Transistor Performances by Manipulating the Coplanar Backbone Conformation of Electron-Deficient Polymers via Hydrogen Bonding Wang, Yang; Hasegawa, Tsukasa; Matsumoto, Hidetoshi Journal of the American Chemical Society, Vol. 141, Issue 8 https://doi.org/10.1021/jacs.8b12499	journal	January 2019
From Single Chains to Aggregates, How Conjugated Polymers Behave in Dilute Solutions Wang, Dapeng; Yuan, Yuan; Mardiyati, Yati Macromolecules, Vol. 46, Issue 15 https://doi.org/10.1021/ma4011523	journal	July 2013
Defining donor and acceptor strength in conjugated copolymers Hedström, Svante; Wang, Ergang; Persson, Petter Molecular Physics, Vol. 115, Issue 5 https://doi.org/10.1080/00268976.2016.1181804	journal	May 2016
Thermopower, Hall tensor, and relaxation time approximation for elemental zinc Chaput, L.; Pécheur, P.; Scherrer, H. Physical Review B, Vol. 75, Issue 4 https://doi.org/10.1103/PhysRevB.75.045116	journal	January 2007
Diketopyrrolopyrroles: Synthesis, Reactivity, and Optical Properties Grzybowski, Marek; Gryko, Daniel T. Advanced Optical Materials, Vol. 3, Issue 3 https://doi.org/10.1002/adom.201400559	journal	January 2015
Structures and properties of conjugated Donor–Acceptor copolymers for solar cell applications Zhang, Zhi–Guo; Wang, Jizheng Journal of Materials Chemistry, Vol. 22, Issue 10 https://doi.org/10.1039/c2jm14951f	journal	January 2012
Probing single-chain conformation and its impact on the optoelectronic properties of donor–accepter conjugated polymers Cao, Zhiqiang; Li, Zhaofan; Tolba, Sara A. Journal of Materials Chemistry A, Vol. 11, Issue 24 https://doi.org/10.1039/D2TA09389H	journal	January 2023
Polymer solar cells Li, Gang; Zhu, Rui; Yang, Yang Nature Photonics, Vol. 6, Issue 3 https://doi.org/10.1038/nphoton.2012.11	journal	February 2012
A Review on the Origin of Synthetic Metal Radical: Singlet Open-Shell Radical Ground State? Li, Yuda; Li, Ling; Wu, Ying The Journal of Physical Chemistry C, Vol. 121, Issue 15 https://doi.org/10.1021/acs.jpcc.6b12936	journal	April 2017
C RYSTAL14 : A program for the ab initio investigation of crystalline solids Dovesi, Roberto; Orlando, Roberto; Erba, Alessandro International Journal of Quantum Chemistry, Vol. 114, Issue 19 https://doi.org/10.1002/qua.24658	journal	March 2014
Toward the Prediction and Control of Glass Transition Temperature for Donor–Acceptor Polymers Zhang, Song; Alesadi, Amirhadi; Selivanova, Mariia Advanced Functional Materials, Vol. 30, Issue 27 https://doi.org/10.1002/adfm.202002221	journal	May 2020
Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics Wang, Chengliang; Dong, Huanli; Hu, Wenping Chemical Reviews, Vol. 112, Issue 4 https://doi.org/10.1021/cr100380z	journal	November 2011
π-Conjugated Donor Polymers: Structure Formation and Morphology in Solution, Bulk and Photovoltaic Blends Hildner, Richard; Köhler, Anna; Müller-Buschbaum, Peter Advanced Energy Materials, Vol. 7, Issue 16 https://doi.org/10.1002/aenm.201700314	journal	August 2017
Double acceptor donor–acceptor alternating conjugated polymers containing cyclopentadithiophene, benzothiadiazole and thienopyrroledione: toward subtractive color organic photovoltaics Chang, Shu-Wei; Muto, Tsuyoshi; Kondo, Takeshi Polymer Journal, Vol. 49, Issue 1 https://doi.org/10.1038/pj.2016.72	journal	September 2016
Atomistic Band Gap Engineering in Donor–Acceptor Polymers Gibson, Gregory L.; McCormick, Theresa M.; Seferos, Dwight S. Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja208917m	journal	December 2011
The Critical Role of Electron‐Donating Thiophene Groups on the Mechanical and Thermal Properties of Donor–Acceptor Semiconducting Polymers Zhang, Song; Ocheje, Michael U.; Huang, Lifeng Advanced Electronic Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aelm.201800899	journal	March 2019
VMD: Visual molecular dynamics Humphrey, William; Dalke, Andrew; Schulten, Klaus Journal of Molecular Graphics, Vol. 14, Issue 1 https://doi.org/10.1016/0263-7855(96)00018-5	journal	February 1996
Bulk Heterojunction Solar Cells: Morphology and Performance Relationships Huang, Ye; Kramer, Edward J.; Heeger, Alan J. Chemical Reviews, Vol. 114, Issue 14 https://doi.org/10.1021/cr400353v	journal	May 2014

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