Nonclassical Strong Metal–Support Interactions for Enhanced Catalysis

Sun, Yifan; Yang, Zhenzhen; Dai, Sheng

doi:10.1021/acs.jpclett.2c03915

Nonclassical Strong Metal–Support Interactions for Enhanced Catalysis

Journal Article · Sun Feb 26 23:00:00 EST 2023 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.2c03915· OSTI ID:1993674

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Shanghai Jiao Tong Univ. (China)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States)

Strong metal–support interaction (SMSI), which encompasses reversible encapsulation and de-encapsulation and modulation of surface adsorption properties, imposes great impacts on the performance of heterogeneous catalysts. Recent development of SMSI has surpassed the prototypical encapsulated Pt-TiO₂ catalyst, affording a series of conceptually novel and practically advantageous catalytic systems. Here, in this work, we provide our perspective on recent progress in nonclassical SMSIs for enhanced catalysis. Unravelling the structural complexity of SMSI necessitates the combination of multiple characterization techniques at different scales. Synthesis strategies leveraging chemical, photonic, and mechanochemical driving forces further expand the definition and application scope of SMSI. Exquisite structure engineering permits elucidation of the interface, entropy, and size effect on the geometric and electronic characteristics. Materials innovation places the atomically thin two-dimensional materials at the forefront of interfacial active site control. A broader space is awaiting exploration, where exploitation of metal–support interactions brings compelling catalytic activity, selectivity, and stability.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1993674

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 9 Vol. 14; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (98)

Preparation of Inorganic Materials Using Ionic Liquids Ma, Zhen; Yu, Jihong; Dai, Sheng Advanced Materials, Vol. 22, Issue 2 https://doi.org/10.1002/adma.200900603	journal	January 2010
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7, p. 992-1005 https://doi.org/10.1002/adma.201304138	journal	December 2013
Strong Metal–Support Interaction for 2D Materials: Application in Noble Metal/TiB₂Heterointerfaces and their Enhanced Catalytic Performance for Formic Acid Dehydrogenation Li, Renhong; Liu, Zhiqi; Trinh, Quang Thang Advanced Materials, Vol. 33, Issue 32 https://doi.org/10.1002/adma.202101536	journal	July 2021
Structure, Properties and Applications of Two‐Dimensional Hexagonal Boron Nitride Roy, Soumyabrata; Zhang, Xiang; Puthirath, Anand B. Advanced Materials, Vol. 33, Issue 44 https://doi.org/10.1002/adma.202101589	journal	September 2021
Monolayer Support Control and Precise Colloidal Nanocrystals Demonstrate Metal–Support Interactions in Heterogeneous Catalysts Goodman, Emmett D.; Asundi, Arun S.; Hoffman, Adam S. Advanced Materials, Vol. 33, Issue 44 https://doi.org/10.1002/adma.202104533	journal	September 2021
Strong Metal Phosphide–Phosphate Support Interaction for Enhanced Non‐Noble Metal Catalysis Chen, Zemin; Zeng, Xiang; Li, Xinyu Advanced Materials, Vol. 34, Issue 5 https://doi.org/10.1002/adma.202106724	journal	December 2021
Manipulating Copper Dispersion on Ceria for Enhanced Catalysis: A Nanocrystal‐Based Atom‐Trapping Strategy Sun, Yifan; Polo‐Garzon, Felipe; Bao, Zhenghong Advanced Science, Vol. 9, Issue 8 https://doi.org/10.1002/advs.202104749	journal	January 2022
Ultrastable Hydroxyapatite/Titanium-Dioxide-Supported Gold Nanocatalyst with Strong Metal-Support Interaction for Carbon Monoxide Oxidation Tang, Hailian; Liu, Fei; Wei, Jiake Angewandte Chemie, Vol. 128, Issue 36 https://doi.org/10.1002/ange.201601823	journal	July 2016
Strong Metal–Support Interactions between Pt Single Atoms and TiO ₂ Han, Bing; Guo, Yalin; Huang, Yike Angewandte Chemie, Vol. 132, Issue 29 https://doi.org/10.1002/ange.202003208	journal	May 2020
Facet‐Dependent Oxidative Strong Metal‐Support Interactions of Palladium–TiO ₂ Determined by In Situ Transmission Electron Microscopy Tang, Min; Li, Songda; Chen, Shiyuan Angewandte Chemie, Vol. 133, Issue 41 https://doi.org/10.1002/ange.202106805	journal	September 2021
A Case of Strong Metal-Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces Willinger, Marc G.; Zhang, Wei; Bondarchuk, Oleksandr Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201400290	journal	May 2014
Surfactant-Assisted Stabilization of Au Colloids on Solids for Heterogeneous Catalysis Zhan, Wangcheng; Shu, Yuan; Sheng, Yujie Angewandte Chemie International Edition, Vol. 56, Issue 16 https://doi.org/10.1002/anie.201701191	journal	March 2017
Outstanding Methane Oxidation Performance of Palladium-Embedded Ceria Catalysts Prepared by a One-Step Dry Ball-Milling Method Danielis, Maila; Colussi, Sara; de Leitenburg, Carla Angewandte Chemie International Edition, Vol. 57, Issue 32 https://doi.org/10.1002/anie.201805929	journal	July 2018
Strong Metal–Support Interactions between Copper and Iron Oxide during the High‐Temperature Water‐Gas Shift Reaction Zhu, Minghui; Tian, Pengfei; Kurtz, Ravi Angewandte Chemie International Edition, Vol. 58, Issue 27 https://doi.org/10.1002/anie.201903298	journal	May 2019
Structure Sensitivity of Au‐TiO ₂ Strong Metal–Support Interactions Zhang, Yunshang; Liu, Jin‐Xun; Qian, Kun Angewandte Chemie International Edition, Vol. 60, Issue 21 https://doi.org/10.1002/anie.202101928	journal	April 2021
Engineering Heterogeneous Catalysis with Strong Metal–Support Interactions: Characterization, Theory and Manipulation Pu, Tiancheng; Zhang, Wenhao; Zhu, Minghui Angewandte Chemie International Edition, Vol. 62, Issue 4 https://doi.org/10.1002/anie.202212278	journal	December 2022
Ultrasonication‐Induced Strong Metal‐Support Interaction Construction in Water Towards Enhanced Catalysis Siniard, Kevin M.; Li, Meijia; Yang, Shi‐Ze Angewandte Chemie International Edition, Vol. 62, Issue 20 https://doi.org/10.1002/anie.202214322	journal	February 2023
Formation of Intermetallic Compounds by Reactive Metal-Support Interaction: A Frequently Encountered Phenomenon in Catalysis Penner, Simon; Armbrüster, Marc ChemCatChem, Vol. 7, Issue 3 https://doi.org/10.1002/cctc.201402635	journal	December 2014
Machine Learning Method Reveals Hidden Strong Metal‐Support Interaction in Microscopy Datasets Blum, Thomas; Graves, Jeffery; Zachman, Michael J. Small Methods, Vol. 5, Issue 5 https://doi.org/10.1002/smtd.202100035	journal	February 2021
New routes for the construction of strong metal—support interactions Wang, Hai; Wang, Liang; Xiao, Feng-Shou Science China Chemistry, Vol. 65, Issue 11 https://doi.org/10.1007/s11426-022-1356-3	journal	August 2022
Thermal stability and the role of oxygen vacancy defects in strong metal support interaction — Pt on Nb-doped TiO2(100) Gao, Y.; Liang, Y.; Chambers, S. A. Surface Science, Vol. 365, Issue 3 https://doi.org/10.1016/0039-6028(96)00763-7	journal	October 1996
Effects of Au nanoparticle size and metal-support interaction on plasmon-induced photocatalytic water oxidation Wang, Shengyang; Zeng, Bin; Li, Can Chinese Journal of Catalysis, Vol. 39, Issue 7 https://doi.org/10.1016/S1872-2067(18)63094-3	journal	July 2018
Sintering-resistant Au/iron oxide-hydroxyapatite nanocatalysts achieved by tuning strong metal-support interactions Liu, Shaofeng; Xu, Wei; Liu, Wei Catalysis Today, Vol. 382 https://doi.org/10.1016/j.cattod.2021.01.012	journal	December 2021
High-entropy catalysts: Supremacy of diversity Sun, Yifan; Dai, Sheng Chem Catalysis, Vol. 1, Issue 3 https://doi.org/10.1016/j.checat.2021.06.019	journal	August 2021
Colloidal Nanostructures of Transition-Metal Dichalcogenides Sun, Yifan; Terrones, Mauricio; Schaak, Raymond E. Accounts of Chemical Research, Vol. 54, Issue 6 https://doi.org/10.1021/acs.accounts.1c00006	journal	March 2021
Engineering Nanostructured Interfaces of Hexagonal Boron Nitride-Based Materials for Enhanced Catalysis Chen, Hao; Jiang, De-en; Yang, Zhenzhen Accounts of Chemical Research, Vol. 56, Issue 1 https://doi.org/10.1021/acs.accounts.2c00564	journal	November 2022
Size-Dependent Pt-TiO ₂ Strong Metal–Support Interaction Wu, Zongfang; Li, Yangyang; Huang, Weixin The Journal of Physical Chemistry Letters, Vol. 11, Issue 12 https://doi.org/10.1021/acs.jpclett.0c01560	journal	May 2020
Oxidative Strong Metal–Support Interactions between Metals and Inert Boron Nitride Song, Tongyuan; Dong, Jinhu; Li, Rongtan The Journal of Physical Chemistry Letters, Vol. 12, Issue 17 https://doi.org/10.1021/acs.jpclett.1c00934	journal	April 2021
Hexagonal Boron Nitride Meeting Metal: A New Opportunity and Territory in Heterogeneous Catalysis Dong, Jinhu; Gao, Lijun; Fu, Qiang The Journal of Physical Chemistry Letters, Vol. 12, Issue 39 https://doi.org/10.1021/acs.jpclett.1c02626	journal	September 2021
Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction Zhang, Shuyi; Plessow, Philipp N.; Willis, Joshua J. Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01769	journal	June 2016
Sacrificial Adsorbate Strategy Achieved Strong Metal–Support Interaction of Stable Cu Nanocatalysts Wang, Xiuyun; Liu, Yi; Peng, Xuanbei ACS Applied Energy Materials, Vol. 1, Issue 4 https://doi.org/10.1021/acsaem.8b00049	journal	March 2018
Deep Understanding of Strong Metal Interface Confinement: A Journey of Pd/FeO _x Catalysts Liu, Jixing; Wang, Lu; Okejiri, Francis ACS Catalysis, Vol. 10, Issue 15 https://doi.org/10.1021/acscatal.0c01447	journal	July 2020
Alcohol-Induced Low-Temperature Blockage of Supported-Metal Catalysts for Enhanced Catalysis Polo-Garzon, Felipe; Blum, Thomas F.; Fung, Victor ACS Catalysis, Vol. 10, Issue 15 https://doi.org/10.1021/acscatal.0c02452	journal	July 2020
Encapsulation of Platinum by Titania under an Oxidative Atmosphere: Contrary to Classical Strong Metal–Support Interactions Liu, Shaofeng; Qi, Haifeng; Zhou, Junhui ACS Catalysis, Vol. 11, Issue 10 https://doi.org/10.1021/acscatal.1c01347	journal	May 2021
Exsolution–Dissolution of Supported Metals on High-Entropy Co₃MnNiCuZnO_x: Toward Sintering-Resistant Catalysis Zhao, Jiahua; Bao, Jiafeng; Yang, Shize ACS Catalysis, Vol. 11, Issue 19 https://doi.org/10.1021/acscatal.1c03228	journal	September 2021
Metal–Support Interactions in Metal/Oxide Catalysts and Oxide–Metal Interactions in Oxide/Metal Inverse Catalysts Li, Yangyang; Zhang, Yunshang; Qian, Kun ACS Catalysis, Vol. 12, Issue 2 https://doi.org/10.1021/acscatal.1c04854	journal	January 2022
Low-Temperature CO ₂ Methanation over CeO ₂ -Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support Interactions and H-Spillover Effect Guo, Yu; Mei, Sheng; Yuan, Kun ACS Catalysis, Vol. 8, Issue 7 https://doi.org/10.1021/acscatal.7b04469	journal	May 2018
Sinter-Resistant Nanoparticle Catalysts Achieved by 2D Boron Nitride-Based Strong Metal–Support Interactions: A New Twist on an Old Story Chen, Hao; Yang, Shi-Ze; Yang, Zhenzhen ACS Central Science, Vol. 6, Issue 9 https://doi.org/10.1021/acscentsci.0c00822	journal	September 2020
Defect Engineering of Ceria Nanocrystals for Enhanced Catalysis via a High-Entropy Oxide Strategy Sun, Yifan; Wu, Tao; Bao, Zhenghong ACS Central Science, Vol. 8, Issue 8 https://doi.org/10.1021/acscentsci.2c00340	journal	June 2022
Mechanochemistry: A Force of Synthesis Do, Jean-Louis; Friščić, Tomislav ACS Central Science, Vol. 3, Issue 1 https://doi.org/10.1021/acscentsci.6b00277	journal	December 2016
Probing and Leveraging the Structural Heterogeneity of Nanomaterials for Enhanced Catalysis Yang, Rui; Bao, Zhenghong; Sun, Yifan ACS Nanoscience Au, Vol. 3, Issue 2 https://doi.org/10.1021/acsnanoscienceau.2c00057	journal	January 2023
Strong metal-support interactions Tauster, S. J. Accounts of Chemical Research, Vol. 20, Issue 11 https://doi.org/10.1021/ar00143a001	journal	November 1987
Interface-Confined Oxide Nanostructures for Catalytic Oxidation Reactions Fu, Qiang; Yang, Fan; Bao, Xinhe Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300249b	journal	March 2013
Strong Metal-Support Interaction in Pt/TiO ₂ Induced by Mild HCHO and NaBH ₄ Solution Reduction and Its Effect on Catalytic Toluene Combustion Rui, Zebao; Chen, Lingye; Chen, Huayao Industrial & Engineering Chemistry Research, Vol. 53, Issue 41 https://doi.org/10.1021/ie5029107	journal	October 2014
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide Tauster, S. J.; Fung, S. C.; Garten, R. L. Journal of the American Chemical Society, Vol. 100, Issue 1 https://doi.org/10.1021/ja00469a029	journal	January 1978
Strong Metal–Support Interactions between Gold Nanoparticles and ZnO Nanorods in CO Oxidation Liu, Xiaoyan; Liu, Ming-Han; Luo, Yi-Chia Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja3033235	journal	June 2012
Reaction-Induced Strong Metal–Support Interactions between Metals and Inert Boron Nitride Nanosheets Dong, Jinhu; Fu, Qiang; Li, Haobo Journal of the American Chemical Society, Vol. 142, Issue 40 https://doi.org/10.1021/jacs.0c08139	journal	September 2020
Photoinduced Strong Metal–Support Interaction for Enhanced Catalysis Chen, Hao; Yang, Zhenzhen; Wang, Xiang Journal of the American Chemical Society, Vol. 143, Issue 23 https://doi.org/10.1021/jacs.0c12817	journal	June 2021
Strong Metal–Support Interaction Boosts Activity, Selectivity, and Stability in Electrosynthesis of H₂O₂ Zhang, Junming; Ma, Jun; Choksi, Tej S. Journal of the American Chemical Society, Vol. 144, Issue 5 https://doi.org/10.1021/jacs.1c12157	journal	January 2022
Overturning CO₂ Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions Xin, Hui; Lin, Le; Li, Rongtan Journal of the American Chemical Society, Vol. 144, Issue 11 https://doi.org/10.1021/jacs.1c12603	journal	March 2022
Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides Tang, Hailian; Wei, Jiake; Liu, Fei Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b11306	journal	December 2015
A Sacrificial Coating Strategy Toward Enhancement of Metal–Support Interaction for Ultrastable Au Nanocatalysts Zhan, Wangcheng; He, Qian; Liu, Xiaofei Journal of the American Chemical Society, Vol. 138, Issue 49 https://doi.org/10.1021/jacs.6b10472	journal	December 2016
Carbide-Supported Au Catalysts for Water–Gas Shift Reactions: A New Territory for the Strong Metal–Support Interaction Effect Dong, Jinhu; Fu, Qiang; Jiang, Zheng Journal of the American Chemical Society, Vol. 140, Issue 42 https://doi.org/10.1021/jacs.8b08246	journal	September 2018
Wet-Chemistry Strong Metal–Support Interactions in Titania-Supported Au Catalysts Zhang, Jian; Wang, Hai; Wang, Liang Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b10864	journal	January 2019
Atomically Thin Metal Sulfides Kubie, Lenore; Martinez, Marissa S.; Miller, Elisa M. Journal of the American Chemical Society, Vol. 141, Issue 30 https://doi.org/10.1021/jacs.9b05807	journal	July 2019
Reduced and n-Type Doped TiO ₂ : Nature of Ti ³⁺ Species Di Valentin, Cristiana; Pacchioni, Gianfranco; Selloni, Annabella The Journal of Physical Chemistry C, Vol. 113, Issue 48 https://doi.org/10.1021/jp9061797	journal	September 2009
Size-dependent catalytic activity of supported metal clusters Xu, Z.; Xiao, F. -S.; Purnell, S. K. Nature, Vol. 372, Issue 6504 https://doi.org/10.1038/372346a0	journal	November 1994
Self-regeneration of a Pd-perovskite catalyst for automotive emissions control Nishihata, Y.; Mizuki, J.; Akao, T. Nature, Vol. 418, Issue 6894 https://doi.org/10.1038/nature00893	journal	July 2002
Electronic perturbations Campbell, Charles T. Nature Chemistry, Vol. 4, Issue 8 https://doi.org/10.1038/nchem.1412	journal	July 2012
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts Matsubu, John C.; Zhang, Shuyi; DeRita, Leo Nature Chemistry, Vol. 9, Issue 2 https://doi.org/10.1038/nchem.2607	journal	September 2016
Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production Ran, Jingrun; Gao, Guoping; Li, Fa-Tang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms13907	journal	January 2017
Taming interfacial electronic properties of platinum nanoparticles on vacancy-abundant boron nitride nanosheets for enhanced catalysis Zhu, Wenshuai; Wu, Zili; Foo, Guo Shiou Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15291	journal	June 2017
Two-dimensional transition metal carbides as supports for tuning the chemistry of catalytic nanoparticles Li, Zhe; Yu, Liang; Milligan, Cory Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07502-5	journal	December 2018
Ultrastable Au nanoparticles on titania through an encapsulation strategy under oxidative atmosphere Liu, Shaofeng; Xu, Wei; Niu, Yiming Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13755-5	journal	December 2019
Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts Liu, Kaipeng; Zhao, Xintian; Ren, Guoqing Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14984-9	journal	March 2020
Harnessing strong metal–support interactions via a reverse route Wu, Peiwen; Tan, Shuai; Moon, Jisue Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16674-y	journal	June 2020
Tuning reactivity of Fischer–Tropsch synthesis by regulating TiOx overlayer over Ru/TiO2 nanocatalysts Zhang, Yaru; Yang, Xiaoli; Yang, Xiaofeng Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17044-4	journal	June 2020
The dynamics of overlayer formation on catalyst nanoparticles and strong metal-support interaction Beck, Arik; Huang, Xing; Artiglia, Luca Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17070-2	journal	June 2020
Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts Du, Xiaorui; Huang, Yike; Pan, Xiaoli Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19484-4	journal	November 2020
Self-regeneration of supported transition metals by a high entropy-driven principle Hou, Shengtai; Ma, Xuefeng; Shu, Yuan Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-26160-8	journal	October 2021
Strong metal-support interactions induced by an ultrafast laser Zhang, Jian; Zhu, Dezhi; Yan, Jianfeng Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27000-5	journal	November 2021
Reversing sintering effect of Ni particles on γ-Mo2N via strong metal support interaction Lin, Lili; Liu, Jinjia; Liu, Xi Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27116-8	journal	November 2021
Measuring and directing charge transfer in heterogenous catalysts Zachman, Michael J.; Fung, Victor; Polo-Garzon, Felipe Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-30923-2	journal	June 2022
Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2−x/Ni catalysts Xu, Ming; Qin, Xuetao; Xu, Yao Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-34463-7	journal	November 2022
Interface-mediated noble metal deposition on transition metal dichalcogenide nanostructures Sun, Yifan; Wang, Yuanxi; Chen, Jamie Y. C. Nature Chemistry, Vol. 12, Issue 3 https://doi.org/10.1038/s41557-020-0418-3	journal	February 2020
Platinum incorporation into titanate perovskites to deliver emergent active and stable platinum nanoparticles Kothari, Maadhav; Jeon, Yukwon; Miller, David N. Nature Chemistry, Vol. 13, Issue 7 https://doi.org/10.1038/s41557-021-00696-0	journal	May 2021
Engineering stable electrocatalysts by synergistic stabilization between carbide cores and Pt shells Göhl, Daniel; Garg, Aaron; Paciok, Paul Nature Materials, Vol. 19, Issue 3 https://doi.org/10.1038/s41563-019-0555-5	journal	December 2019
Nanoscale engineering of catalytic materials for sustainable technologies Mitchell, Sharon; Qin, Ruixuan; Zheng, Nanfeng Nature Nanotechnology, Vol. 16, Issue 2 https://doi.org/10.1038/s41565-020-00799-8	journal	November 2020
Synergizing metal–support interactions and spatial confinement boosts dynamics of atomic nickel for hydrogenations Gu, Jian; Jian, Minzhen; Huang, Li Nature Nanotechnology, Vol. 16, Issue 10 https://doi.org/10.1038/s41565-021-00951-y	journal	July 2021
Heterogeneous single-atom catalysis Wang, Aiqin; Li, Jun; Zhang, Tao Nature Reviews Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/s41570-018-0010-1	journal	May 2018
Reactive metal–support interactions at moderate temperature in two-dimensional niobium-carbide-supported platinum catalysts Li, Zhe; Cui, Yanran; Wu, Zhenwei Nature Catalysis, Vol. 1, Issue 5 https://doi.org/10.1038/s41929-018-0067-8	journal	May 2018
Structure of the catalytically active copper–ceria interfacial perimeter Chen, Aling; Yu, Xiaojuan; Zhou, Yan Nature Catalysis, Vol. 2, Issue 4 https://doi.org/10.1038/s41929-019-0226-6	journal	February 2019
Transition state and product diffusion control by polymer–nanocrystal hybrid catalysts Riscoe, Andrew R.; Wrasman, Cody J.; Herzing, Andrew A. Nature Catalysis, Vol. 2, Issue 10 https://doi.org/10.1038/s41929-019-0322-7	journal	August 2019
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity van Deelen, Tom W.; Hernández Mejía, Carlos; de Jong, Krijn P. Nature Catalysis, Vol. 2, Issue 11 https://doi.org/10.1038/s41929-019-0364-x	journal	November 2019
Boosting CO2 hydrogenation via size-dependent metal–support interactions in cobalt/ceria-based catalysts Parastaev, Alexander; Muravev, Valery; Huertas Osta, Elisabet Nature Catalysis, Vol. 3, Issue 6 https://doi.org/10.1038/s41929-020-0459-4	journal	May 2020
Strong metal–support interactions on gold nanoparticle catalysts achieved through Le Chatelier’s principle Wang, Hai; Wang, Liang; Lin, Dong Nature Catalysis, Vol. 4, Issue 5 https://doi.org/10.1038/s41929-021-00611-3	journal	May 2021
Mechanochemistry and sonochemistry: concluding remarks Suslick, Kenneth S. Faraday Discuss., Vol. 170 https://doi.org/10.1039/C4FD00148F	journal	January 2014
Oxidative strong metal–support interactions (OMSI) of supported platinum-group metal catalysts Tang, Hailian; Su, Yang; Guo, Yalin Chemical Science, Vol. 9, Issue 32 https://doi.org/10.1039/C8SC01392F	journal	January 2018
Self-regenerative noble metal catalysts supported on high-entropy oxides Chen, Hao; Sun, Yifan; Yang, Shize Chemical Communications, Vol. 56, Issue 95 https://doi.org/10.1039/D0CC05860B	journal	January 2020
Dynamic transformation between bilayer islands and dinuclear clusters of Cr oxide on Au(111) through environment and interface effects Yi, Zhiyu; Lin, Le; Chang, Yuan Proceedings of the National Academy of Sciences, Vol. 119, Issue 22 https://doi.org/10.1073/pnas.2120716119	journal	May 2022
Imaging Cluster Surfaces with Atomic Resolution: The Strong Metal-Support Interaction State of Pt Supported on TiO 2 ( 110 ) Dulub, Olga; Hebenstreit, Wilhelm; Diebold, Ulrike Physical Review Letters, Vol. 84, Issue 16 https://doi.org/10.1103/PhysRevLett.84.3646	journal	April 2000
Classical strong metal–support interactions between gold nanoparticles and titanium dioxide Tang, Hailian; Su, Yang; Zhang, Bingsen Science Advances, Vol. 3, Issue 10 https://doi.org/10.1126/sciadv.1700231	journal	October 2017
High-entropy materials for catalysis: A new frontier Sun, Yifan; Dai, Sheng Science Advances, Vol. 7, Issue 20 https://doi.org/10.1126/sciadv.abg1600	journal	May 2021
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Catalysis by Small Metal Clusters Hamilton, J. F.; Baetzold, R. C. Science, Vol. 205, Issue 4412 https://doi.org/10.1126/science.205.4412.1213	journal	September 1979
Strong Interactions in Supported-Metal Catalysts Tauster, S. J.; Fung, S. C.; Baker, R. T. K. Science, Vol. 211, Issue 4487, p. 1121-1125 https://doi.org/10.1126/science.211.4487.1121	journal	March 1981
Selective oxidative dehydrogenation of propane to propene using boron nitride catalysts Grant, J. T.; Carrero, C. A.; Goeltl, F. Science, Vol. 354, Issue 6319 https://doi.org/10.1126/science.aaf7885	journal	December 2016
Dynamic interplay between metal nanoparticles and oxide support under redox conditions Frey, H.; Beck, A.; Huang, X. Science, Vol. 376, Issue 6596 https://doi.org/10.1126/science.abm3371	journal	May 2022

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