Hydrothermal catalytic conversion of oleic acid to heptadecane over Ni/ZrO2

Cronmiller, L. Estelle; Crawford, James M.; Zhang, Jing; Vardon, Derek R.; Strathmann, Timothy J.

doi:10.1016/j.hazadv.2023.100273

Hydrothermal catalytic conversion of oleic acid to heptadecane over Ni/ZrO₂

Journal Article · Sat Mar 04 23:00:00 EST 2023 · Journal of Hazardous Materials Advances

DOI:https://doi.org/10.1016/j.hazadv.2023.100273· OSTI ID:1993431

^[1]; Crawford, James M. ^[2]; Zhang, Jing ^[3]; Vardon, Derek R. ^[4]; Strathmann, Timothy J. ^[1]

Colorado School of Mines, Golden, CO (United States)
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Harbin Institute of Technology (China)
Alder Fuels, Washington, D.C. (United States)

There is growing interest in the substitution of expensive noble metal catalysts with low-cost earth-abundant metals in applications targeting biofuels production from waste organic feedstocks. Here, nickel (Ni) catalysts supported on zirconium dioxide (ZrO₂), both with and without copper (Cu) as a co-metal, were tested in hydrothermal reactions of unsaturated and saturated C18 fatty acids as models for waste oil feedstocks. In contrast to recent reports, this study showed no enhancement of nickel's activity for fatty acid conversion to alkane products when Cu was present. Ni/ZrO₂ prepared by metal coprecipitation methods converted 100% of oleic acid with 25% selectivity to heptadecane after 5h of reaction at 350 °C using methanol as a hydrogen donor source, increasing to 41% heptadecane after 20 h. Lower yields were observed with catalysts prepared by wet impregnation and using alternative hydrogen donor sources (glycerol, formic acid). Greater selectivity to heptadecane was also observed at higher temperatures (370 °C) and when the initial fatty acid had greater saturation. Longer term exposure to hydrothermal media led to metal sintering and catalyst deactivation. Findings support a path forward to the development of earth-abundant metal catalysts for the upgrading of waste organic feedstocks.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: National Science Foundation (NSF)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1993431

Report Number(s):: NREL/JA-5100-87064; MainId:87839; UUID:7713e8e7-dde7-42c4-9bb2-b80086221977; MainAdminID:70084

Journal Information:: Journal of Hazardous Materials Advances, Journal Name: Journal of Hazardous Materials Advances Vol. 10; ISSN 2772-4166

Country of Publication:: United States

Language:: English

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Hydrothermal catalytic conversion of oleic acid to heptadecane over Ni/ZrO2

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