Polymeric Membranes for H2S and CO2 Removal from Natural Gas for Hydrogen Production: A Review

Rao, Shraavya; Prasad, Babul; Han, Yang; Ho, W. S. Winston

doi:10.3390/en16155713

Polymeric Membranes for H2S and CO2 Removal from Natural Gas for Hydrogen Production: A Review

Journal Article · Mon Jul 31 00:00:00 EDT 2023 · Energies

DOI:https://doi.org/10.3390/en16155713· OSTI ID:1993084

Rao, Shraavya; ; ; Ho, W. S. Winston

Natural gas, an important source of hydrogen, is expected to be crucial in the transition to a hydrogen-based economy. The landscape of the gas processing industry is set to change in the near future with the development of highly acidic sour gas wells. Natural gas purification constitutes a major share of the gas separation membrane market, and the shift to low-quality sour gas wells has been mirrored in the trends of membrane material research. Purification also constitutes the major portion of the cost of natural gas, posing implications for the cost of hydrogen production. This review provides an update on the current state of research regarding polymeric membranes for H2S removal, along with CO2 separation, from natural gas that is used for hydrogen production via steam methane reforming. The challenges of adapting polymeric membranes to ternary H2S/CO2/CH4 separations are discussed in detail. Key polymeric materials are highlighted, and the prospects for their application in H2S removal from natural gas are evaluated. Finally, the growing interest in H2 production from H2S is discussed. Advances in the membrane industry and the emergence of new membrane materials may significantly improve the commercial viability of such processes.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0031635

OSTI ID:: 1993084

Journal Information:: Energies, Journal Name: Energies Journal Issue: 15 Vol. 16; ISSN 1996-1073; ISSN ENERGA

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

References (190)

Long-term permeation properties of poly(1-trimethylsilyl-1-propyne) membranes in hydrocarbon?Vapor environment Pinnau, I.; Casillas, C. G.; Morisato, A. Journal of Polymer Science Part B: Polymer Physics, Vol. 35, Issue 10 https://doi.org/10.1002/(SICI)1099-0488(19970730)35:10<1483::AID-POLB2>3.0.CO;2-T	journal	July 1997
Gas transport properties of poly(ether-b-amide) segmented block copolymers Bondar, V. I.; Freeman, B. D.; Pinnau, I. Journal of Polymer Science Part B: Polymer Physics, Vol. 38, Issue 15 https://doi.org/10.1002/1099-0488(20000801)38:15<2051::AID-POLB100>3.0.CO;2-D	journal	January 2000
Tailor-made Polymeric Membranes based on Segmented Block Copolymers for CO ₂ Separation Car, Anja; Stropnik, Chrtomir; Yave, Wilfredo Advanced Functional Materials, Vol. 18, Issue 18 https://doi.org/10.1002/adfm.200800436	journal	September 2008
Molecularly Tuned Free Volume of Vapor Cross-Linked 6FDA-Durene/ZIF-71 MMMs for H ₂ /CO ₂ Separation at 150 °C Japip, Susilo; Liao, Kuo-Sung; Chung, Tai-Shung Advanced Materials, Vol. 29, Issue 4 https://doi.org/10.1002/adma.201603833	journal	November 2016
Molecularly Engineered 6FDA‐Based Polyimide Membranes for Sour Natural Gas Separation Liu, Zhongyun; Liu, Yang; Qiu, Wulin Angewandte Chemie International Edition, Vol. 59, Issue 35 https://doi.org/10.1002/anie.202003910	journal	June 2020
Gas permeabilities of cellulose nitrate/poly(ethylene glycol) blend membranes Kawakami, M.; Iwanaga, H.; Hara, Y. Journal of Applied Polymer Science, Vol. 27, Issue 7 https://doi.org/10.1002/app.1982.070270708	journal	July 1982
Gas permeation properties of hexafluoro aromatic polyimides Matsumoto, Kenji; Xu, Ping Journal of Applied Polymer Science, Vol. 47, Issue 11 https://doi.org/10.1002/app.1993.070471106	journal	March 1993
Preparation of polyethyleneglycol (PEG) and cellulose acetate (CA) blend membranes and their gas permeabilities Li, Jintong; Nagai, Kazukiyo; Nakagawa, Tsutomu Journal of Applied Polymer Science, Vol. 58, Issue 9 https://doi.org/10.1002/app.1995.070580906	journal	November 1995
Fluorinated copolyimide membranes for sour mixed‐gas upgrading Hayek, Ali; Yahaya, Garba O.; Alsamah, Abdulkarim Journal of Applied Polymer Science, Vol. 137, Issue 5 https://doi.org/10.1002/app.48336	journal	August 2019
A Comprehensive Review of H₂S Scavenger Technologies from Oil and Gas Streams Agbroko, Obakore W.; Piler, Karishma; Benson, Tracy J. ChemBioEng Reviews, Vol. 4, Issue 6 https://doi.org/10.1002/cben.201600026	journal	August 2017
Middle Scale Hydrogen Sulphide Conversion and Valorisation Technologies: A Review Spatolisano, Elvira; de Angelis, Alberto R.; Pellegrini, Laura A. ChemBioEng Reviews, Vol. 9, Issue 4 https://doi.org/10.1002/cben.202100057	journal	May 2022
High Performance Polyimide with High Internal Free Volume Elements Cho, Yoon Jin; Park, Ho Bum Macromolecular Rapid Communications, Vol. 32, Issue 7 https://doi.org/10.1002/marc.201000690	journal	January 2011
Selective permeation of CO2 and CH4 through kapton polyimide: Effects of penetrant competition and gas-phase nonideality Chern, R. T.; Koros, W. J.; Yui, B. Journal of Polymer Science: Polymer Physics Edition, Vol. 22, Issue 6 https://doi.org/10.1002/pol.1984.180220610	journal	June 1984
Simplified analysis of gas/polymer selective solubility behavior Koros, William J. Journal of Polymer Science: Polymer Physics Edition, Vol. 23, Issue 8 https://doi.org/10.1002/pol.1985.180230813	journal	August 1985
Recent development of polyimides: Synthesis, processing, and application in gas separation Xu, Zhen; Croft, Zacary L.; Guo, Dong Journal of Polymer Science, Vol. 59, Issue 11 https://doi.org/10.1002/pol.20210001	journal	May 2021
Structure/permeability relationships of polyimide membranes. Applications to the separation of gas mixtures Stern, S. A.; Mi, Y.; Yamamoto, H. Journal of Polymer Science Part B: Polymer Physics, Vol. 27, Issue 9 https://doi.org/10.1002/polb.1989.090270908	journal	August 1989
Effect of methyl substituents on permeability and permselectivity of gases in polyimides prepared from methyl-substituted phenylenediamines Tanaka, Kazuhiro; Okano, Masaaki; Toshino, Hiroyuki Journal of Polymer Science Part B: Polymer Physics, Vol. 30, Issue 8 https://doi.org/10.1002/polb.1992.090300813	journal	July 1992
Membrane Handbook Ho, W. S. Winston; Sirkar, Kamalesh K. https://doi.org/10.1007/978-1-4615-3548-5	book	January 1992
High Performance Polymers: Their Origin and Development Seymour, Raymond B.; Kirshenbaum, Gerald S. Proceedings of the Symposium on the History of High Performance Polymers at the American Chemical Society Meeting held in New York, April 15–18, 1986 https://doi.org/10.1007/978-94-011-7073-4	conference	January 1986
Separation of dichloroethane-trichloroethylene mixtures by means of a membrane pervaporation process Sheng, Jin Desalination, Vol. 80, Issue 1 https://doi.org/10.1016/0011-9164(91)80007-I	journal	April 1991
Pervaporation of low volatility aromatics from water Böddeker, K. W.; Bengtson, G.; Bode, E. Journal of Membrane Science, Vol. 53, Issue 1-2 https://doi.org/10.1016/0376-7388(90)80010-J	journal	October 1990
Correlation of separation factor versus permeability for polymeric membranes Robeson, Lloyd M. Journal of Membrane Science, Vol. 62, Issue 2 https://doi.org/10.1016/0376-7388(91)80060-J	journal	October 1991
Properties of a polyimide gas separation membrane in natural gas streams White, Lloyd S.; Blinka, Thomas A.; Kloczewski, Harold A. Journal of Membrane Science, Vol. 103, Issue 1-2 https://doi.org/10.1016/0376-7388(94)00313-N	journal	July 1995
Relation of gas permeability with structure of aromatic polyimides I Hirayama, Y.; Yoshinaga, T.; Kusuki, Y. Journal of Membrane Science, Vol. 111, Issue 2 https://doi.org/10.1016/0376-7388(95)00172-7	journal	March 1996
Relation of gas permeability with structure of aromatic polyimides II Hirayama, Y.; Yoshinaga, T.; Kusuki, Y. Journal of Membrane Science, Vol. 111, Issue 2 https://doi.org/10.1016/0376-7388(95)00173-5	journal	March 1996
Recent advances in cellulosic membranes for gas separation and pervaporation Schell, W. J.; Wensley, C. G.; Chen, M. S. K. Gas Separation & Purification, Vol. 3, Issue 4 https://doi.org/10.1016/0950-4214(89)80001-5	journal	December 1989
Development of CO 2 Selective Poly(Ethylene Oxide)-Based Membranes: From Laboratory to Pilot Plant Scale Brinkmann, Torsten; Lillepärg, Jelena; Notzke, Heiko Engineering, Vol. 3, Issue 4 https://doi.org/10.1016/J.ENG.2017.04.004	journal	August 2017
Economics of thermal dissociation of H2S to produce hydrogen Cox, B. International Journal of Hydrogen Energy, Vol. 23, Issue 7 https://doi.org/10.1016/S0360-3199(97)00111-0	journal	July 1998
Isomeric polyimides based on fluorinated dianhydrides and diamines for gas separation applications Coleman, M. R.; Koros, W. J. Journal of Membrane Science, Vol. 50, Issue 3 https://doi.org/10.1016/S0376-7388(00)80626-2	journal	July 1990
Permeation behavior of carbon dioxide-methane mixtures in cellulose acetate membranes Donohue, M. D.; Minhas, B. S.; Lee, S. Y. Journal of Membrane Science, Vol. 42, Issue 3 https://doi.org/10.1016/S0376-7388(00)82376-5	journal	March 1989
The effect of degree of acetylation on gas sorption and transport behavior in cellulose acetate Puleo, A. C.; Paul, D. R.; Kelley, S. S. Journal of Membrane Science, Vol. 47, Issue 3 https://doi.org/10.1016/S0376-7388(00)83083-5	journal	December 1989
Relationship between gas separation properties and chemical structure in a series of aromatic polyimides Kim, T. H.; Koros, W. J.; Husk, G. R. Journal of Membrane Science, Vol. 37, Issue 1 https://doi.org/10.1016/S0376-7388(00)85068-1	journal	April 1988
Mixed-gas permeation of syngas components in poly(dimethylsiloxane) and poly(1-trimethylsilyl-1-propyne) at elevated temperatures Merkel, T. Journal of Membrane Science, Vol. 191, Issue 1-2 https://doi.org/10.1016/S0376-7388(01)00452-5	journal	September 2001
Upgrading low-quality natural gas with H2S- and CO2-selective polymer membranes Hao, J.; Rice, P. A.; Stern, S. A. Journal of Membrane Science, Vol. 209, Issue 1 https://doi.org/10.1016/S0376-7388(02)00318-6	journal	November 2002
Poly(ether urethane) and poly(ether urethane urea) membranes with high H2S/CH4 selectivity Chatterjee, G.; Houde, A. A.; Stern, S. A. Journal of Membrane Science, Vol. 135, Issue 1 https://doi.org/10.1016/S0376-7388(97)00134-8	journal	November 1997
Effect of polyethyleneglycol (PEG) on gas permeabilities and permselectivities in its cellulose acetate (CA) blend membranes Li, Jintong; Wang, Shichang; Nagai, Kazukiyo Journal of Membrane Science, Vol. 138, Issue 2 https://doi.org/10.1016/S0376-7388(97)00212-3	journal	January 1998
Microporous and dense inorganic membranes: current status and prospective Lin, Y. S. Separation and Purification Technology, Vol. 25, Issue 1-3 https://doi.org/10.1016/S1383-5866(01)00089-2	journal	October 2001
Plasticization-resistant glassy polyimide membranes for CO2/CO4 separations Bos, A.; Pünt, I. G. M.; Wessling, M. Separation and Purification Technology, Vol. 14, Issue 1-3 https://doi.org/10.1016/S1383-5866(98)00057-4	journal	August 1998
The role of natural gas in a low carbon Asia Pacific Aguilera, Roberto F. Applied Energy, Vol. 113 https://doi.org/10.1016/j.apenergy.2013.07.048	journal	January 2014
Hydrogen and syngas production by superadiabatic combustion – A review Abdul Mujeebu, Muhammad Applied Energy, Vol. 173 https://doi.org/10.1016/j.apenergy.2016.04.018	journal	July 2016
Aromatic block co-polyimide membranes for sour gas feed separations Yahaya, Garba O.; Qahtani, Mohammad S.; Ammar, Abdulaziz Y. Chemical Engineering Journal, Vol. 304 https://doi.org/10.1016/j.cej.2016.06.076	journal	November 2016
Synergistic decomposition of H2S into H2 by Ni3S2 over ZrO2 support via a sulfur looping scheme with CO2 enabled carrier regeneration Jangam, Kalyani V.; Joshi, Anuj S.; Chen, Yu-Yen Chemical Engineering Journal, Vol. 426 https://doi.org/10.1016/j.cej.2021.131815	journal	December 2021
Hydrogen sulfide (H2S) conversion to hydrogen (H2) and value-added chemicals: Progress, challenges and outlook Chan, Yi Herng; Loy, Adrian Chun Minh; Cheah, Kin Wai Chemical Engineering Journal, Vol. 458 https://doi.org/10.1016/j.cej.2023.141398	journal	February 2023
Natural gas purification from acid gases using membranes: A review of the history, features, techno-commercial challenges, and process intensification of commercial membranes Alcheikhhamdon, Yousif; Hoorfar, Mina Chemical Engineering and Processing - Process Intensification, Vol. 120 https://doi.org/10.1016/j.cep.2017.07.009	journal	October 2017
Cellulose acetate in fabrication of polymeric membranes: A review Vatanpour, Vahid; Pasaoglu, Mehmet Emin; Barzegar, Hossein Chemosphere, Vol. 295 https://doi.org/10.1016/j.chemosphere.2022.133914	journal	May 2022
Comparison of permeability performance of PEBAX-1074/TiO2, PEBAX-1074/SiO2 and PEBAX-1074/Al2O3 nanocomposite membranes for CO2/CH4 separation Azizi, Navid; Mohammadi, Toraj; Mosayebi Behbahani, Reza Chemical Engineering Research and Design, Vol. 117 https://doi.org/10.1016/j.cherd.2016.10.018	journal	January 2017
Worldwide development potential for sour gas Burgers, W. F. J.; Northrop, P. S.; Kheshgi, H. S. Energy Procedia, Vol. 4 https://doi.org/10.1016/j.egypro.2011.02.104	journal	January 2011
CO2 management at ExxonMobil’s LaBarge field, Wyoming, USA Michael E. Parker, P. E.; Northrop, Scott; Valencia, Jaime A. Energy Procedia, Vol. 4 https://doi.org/10.1016/j.egypro.2011.02.531	journal	January 2011
CO2 capture by sub-ambient membrane operation Hasse, David; Kulkarni, Sudhir; Sanders, Ed Energy Procedia, Vol. 37 https://doi.org/10.1016/j.egypro.2013.05.195	journal	January 2013
Global natural gas demand to 2025: A learning scenario development model Hafezi, Reza; Akhavan, AmirNaser; Pakseresht, Saeed Energy, Vol. 224 https://doi.org/10.1016/j.energy.2021.120167	journal	June 2021
Energy demand and production forecasting in Pakistan Raza, Muhammad Amir; Khatri, Krishan Lal; Israr, Amber Energy Strategy Reviews, Vol. 39 https://doi.org/10.1016/j.esr.2021.100788	journal	January 2022
Membrane gas separation applications in natural gas processing Scholes, Colin A.; Stevens, Geoff W.; Kentish, Sandra E. Fuel, Vol. 96 https://doi.org/10.1016/j.fuel.2011.12.074	journal	June 2012
Synthesis gas production using steam hydrogasification and steam reforming Raju, Arun S. K.; Park, Chan S.; Norbeck, Joseph M. Fuel Processing Technology, Vol. 90, Issue 2, p. 330-336 https://doi.org/10.1016/j.fuproc.2008.09.011	journal	February 2009
Novel sulfur looping scheme to convert H2S to H2 using Ni3S2 supported over ZrO2: Thermodynamic, kinetic, and comparative system analyses Joshi, Anuj S.; Jangam, Kalyani V.; Mohammad, Zain Fuel Processing Technology, Vol. 237 https://doi.org/10.1016/j.fuproc.2022.107443	journal	December 2022
Process simulation of a dual-stage Selexol process for 95% carbon capture efficiency at an integrated gasification combined cycle power plant Kapetaki, Zoe; Brandani, Pietro; Brandani, Stefano International Journal of Greenhouse Gas Control, Vol. 39 https://doi.org/10.1016/j.ijggc.2015.04.015	journal	August 2015
The exploitation of hydrogen sulfide for hydrogen production in geothermal areas Ouali, Salima; Chader, Samira; Belhamel, Maïouf International Journal of Hydrogen Energy, Vol. 36, Issue 6 https://doi.org/10.1016/j.ijhydene.2010.07.121	journal	March 2011
Core-shell bifunctional catalyst for steam methane reforming resistant to H2S: Activity and structure evolution Tsodikov, M. V.; Kurdymov, S. S.; Konstantinov, G. I. International Journal of Hydrogen Energy, Vol. 40, Issue 7 https://doi.org/10.1016/j.ijhydene.2015.01.016	journal	February 2015
New catalysts for hydrogen production from H 2 S: Preliminary results Guldal, N. O.; Figen, H. E.; Baykara, S. Z. International Journal of Hydrogen Energy, Vol. 40, Issue 24 https://doi.org/10.1016/j.ijhydene.2015.02.107	journal	June 2015
Experimental and modeling study of hydrogen production from catalytic steam reforming of methane mixture with hydrogen sulfide Sadooghi, Parham; Rauch, Reinhard International Journal of Hydrogen Energy, Vol. 40, Issue 33 https://doi.org/10.1016/j.ijhydene.2015.06.143	journal	September 2015
Hydrogen from hydrogen sulfide: towards a more sustainable hydrogen economy De Crisci, Antonio G.; Moniri, Armin; Xu, Yuming International Journal of Hydrogen Energy, Vol. 44, Issue 3 https://doi.org/10.1016/j.ijhydene.2018.10.035	journal	January 2019
Metal sulfide-based process analysis for hydrogen generation from hydrogen sulfide conversion Reddy, Sharath; Nadgouda, Sourabh G.; Tong, Andrew International Journal of Hydrogen Energy, Vol. 44, Issue 39 https://doi.org/10.1016/j.ijhydene.2019.06.180	journal	August 2019
Hydrogen production facility location selection for Black Sea using entropy based TOPSIS under IVPF environment Seker, Sukran; Aydin, Nezir International Journal of Hydrogen Energy, Vol. 45, Issue 32 https://doi.org/10.1016/j.ijhydene.2019.12.183	journal	June 2020
Ranking locations for producing hydrogen using geothermal energy in Afghanistan Mostafaeipour, Ali; Hosseini Dehshiri, Seyyed Jalaladdin; Hosseini Dehshiri, Seyyed Shahabaddin International Journal of Hydrogen Energy, Vol. 45, Issue 32 https://doi.org/10.1016/j.ijhydene.2020.04.079	journal	June 2020
Experimental investigation on H2S and SO2 sulphur poisoning and regeneration of a commercially available Ni-catalyst during methane tri-reforming Wachter, Philipp; Gaber, Christian; Raic, Juraj International Journal of Hydrogen Energy, Vol. 46, Issue 5 https://doi.org/10.1016/j.ijhydene.2020.10.214	journal	January 2021
Effective use of hydrogen sulfide and natural gas resources available in the Black Sea for hydrogen economy Ozturk, Merve; Midilli, Adnan; Dincer, Ibrahim International Journal of Hydrogen Energy, Vol. 46, Issue 18 https://doi.org/10.1016/j.ijhydene.2020.12.186	journal	March 2021
The role of hydrogen in the transition from a petroleum economy to a low-carbon society Espegren, Kari; Damman, Sigrid; Pisciella, Paolo International Journal of Hydrogen Energy, Vol. 46, Issue 45 https://doi.org/10.1016/j.ijhydene.2021.04.143	journal	July 2021
Hydrogen energy deployment in decarbonizing transportation sector using multi-supply-demand integrated scenario analysis with nonlinear programming — A Shanxi case study Zhao, Ying-jie; Liu, Qian; Duan, Yuan-yuan International Journal of Hydrogen Energy, Vol. 47, Issue 44 https://doi.org/10.1016/j.ijhydene.2022.04.102	journal	May 2022
Building the green hydrogen market – Current state and outlook on green hydrogen demand and electrolyzer manufacturing Wappler, Mona; Unguder, Dilek; Lu, Xing International Journal of Hydrogen Energy, Vol. 47, Issue 79 https://doi.org/10.1016/j.ijhydene.2022.07.253	journal	September 2022
A review on hydrogen production from hydrogen sulphide by chemical and photochemical methods Reverberi, Andrea Pietro; Klemeš, Jiří Jaromír; Varbanov, Petar Sabev Journal of Cleaner Production, Vol. 136 https://doi.org/10.1016/j.jclepro.2016.04.139	journal	November 2016
Hybrid systems: Combining membrane and absorption technologies leads to more efficient acid gases (CO 2 and H 2 S) removal from natural gas Rezakazemi, Mashallah; Heydari, Isa; Zhang, Zhien Journal of CO2 Utilization, Vol. 18 https://doi.org/10.1016/j.jcou.2017.02.006	journal	March 2017
Efficient estimation of natural gas compressibility factor using a rigorous method Fayazi, Amir; Arabloo, Milad; Mohammadi, Amir H. Journal of Natural Gas Science and Engineering, Vol. 16 https://doi.org/10.1016/j.jngse.2013.10.004	journal	January 2014
Comparative analysis of absorption, membrane, and hybrid technologies for CO2 recovery Torres, Fabiana Belén; Gutierrez, Juan Pablo; Ruiz, Liliana Ale Journal of Natural Gas Science and Engineering, Vol. 94 https://doi.org/10.1016/j.jngse.2021.104082	journal	October 2021
Membranes for separation of CO2/CH4 at harsh conditions Teixeira Cardoso, Anne Raquel; Ambrosi, Alan; Di Luccio, Marco Journal of Natural Gas Science and Engineering, Vol. 98 https://doi.org/10.1016/j.jngse.2021.104388	journal	February 2022
Thermodynamic analyses of hydrogen production from sub-quality natural gas Huang, Cunping; T-Raissi, Ali Journal of Power Sources, Vol. 163, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.02.081	journal	January 2007
Liquid hydrogen production via hydrogen sulfide methane reformation Huang, Cunping; T-Raissi, Ali Journal of Power Sources, Vol. 175, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.09.079	journal	January 2008
Effects of hydrogen sulfide on the mechanical and thermal properties of cellulose insulation paper: A molecular dynamics simulation Du, Dongyuan; Tang, Chao; Zhang, Jingwen Materials Chemistry and Physics, Vol. 240 https://doi.org/10.1016/j.matchemphys.2019.122153	journal	January 2020
Gas solubility, diffusivity and permeability in poly(ethylene oxide) Lin, H.; Freeman, B. D. Journal of Membrane Science, Vol. 239, Issue 1 https://doi.org/10.1016/j.memsci.2003.08.031	journal	August 2004
Mixed gas hydrogen sulfide permeability and separation using supported polyphosphazene membranes Orme, Christopher J.; Stewart, Frederick F. Journal of Membrane Science, Vol. 253, Issue 1-2 https://doi.org/10.1016/j.memsci.2004.12.034	journal	May 2005
Analysis of dual-mode model parameters for gas sorption in glassy polymers Kanehashi, Shinji; Nagai, Kazukiyo Journal of Membrane Science, Vol. 253, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.01.003	journal	May 2005
Gas separation membranes from polymers of intrinsic microporosity Budd, P.; Msayib, K.; Tattershall, C. Journal of Membrane Science, Vol. 251, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.01.009	journal	April 2005
Transport and structural characteristics of crosslinked poly(ethylene oxide) rubbers Lin, H.; Wagner, E.; Swinnea, J. Journal of Membrane Science, Vol. 276, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.09.040	journal	May 2006
Defect-free asymmetric hollow fiber membranes from Torlon®, a polyamide–imide polymer, for high-pressure CO2 separations Kosuri, Madhava R.; Koros, William J. Journal of Membrane Science, Vol. 320, Issue 1-2 https://doi.org/10.1016/j.memsci.2008.03.062	journal	July 2008
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Thermal treatment of poly(ethylene oxide)-segmented copolyimide based membranes: An effective way to improve the gas separation properties Munoz, D.; Maya, E.; Deabajo, J. Journal of Membrane Science, Vol. 323, Issue 1 https://doi.org/10.1016/j.memsci.2008.06.036	journal	October 2008
Gas permeability and free volume in poly(amide-b-ethylene oxide)/polyethylene glycol blend membranes Yave, Wilfredo; Car, Anja; Peinemann, Klaus-Viktor Journal of Membrane Science, Vol. 339, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.04.049	journal	September 2009
An empirical correlation of gas permeability and permselectivity in polymers and its theoretical basis Robeson, L. M.; Freeman, B. D.; Paul, D. R. Journal of Membrane Science, Vol. 341, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.06.005	journal	September 2009
Membrane separation of nitrogen from natural gas: A case study from membrane synthesis to commercial deployment Lokhandwala, Kaaeid A.; Pinnau, Ingo; He, Zhenjie Journal of Membrane Science, Vol. 346, Issue 2 https://doi.org/10.1016/j.memsci.2009.09.046	journal	January 2010
Antiplasticization and plasticization of Matrimid® asymmetric hollow fiber membranes—Part A. Experimental Lee, Jong Suk; Madden, William; Koros, William J. Journal of Membrane Science, Vol. 350, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.12.033	journal	March 2010
Investigation of gas permeation properties of systematically modified polybenzimidazoles by N-substitution Kumbharkar, Santosh C.; Kharul, Ulhas K. Journal of Membrane Science, Vol. 357, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.04.014	journal	July 2010
Influence of temperature on the upper bound: Theoretical considerations and comparison with experimental results Rowe, Brandon W.; Robeson, Lloyd M.; Freeman, Benny D. Journal of Membrane Science, Vol. 360, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.04.047	journal	September 2010
Toluene impurity effects on CO2 separation using a hollow fiber membrane for natural gas Omole, Imona C.; Bhandari, Dhaval A.; Miller, Stephen J. Journal of Membrane Science, Vol. 369, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.12.035	journal	March 2011
Effect of thermal annealing on a novel polyamide–imide polymer membrane for aggressive acid gas separations Vaughn, Justin T.; Koros, William J.; Johnson, J. R. Journal of Membrane Science, Vol. 401-402 https://doi.org/10.1016/j.memsci.2012.01.047	journal	May 2012
Dense film polyimide membranes for aggressive sour gas feed separations Kraftschik, Brian; Koros, William J.; Johnson, J. R. Journal of Membrane Science, Vol. 428 https://doi.org/10.1016/j.memsci.2012.10.025	journal	February 2013
Contributions of diffusion and solubility selectivity to the upper bound analysis for glassy gas separation membranes Robeson, Lloyd M.; Smith, Zachary P.; Freeman, Benny D. Journal of Membrane Science, Vol. 453 https://doi.org/10.1016/j.memsci.2013.10.066	journal	March 2014
Solubility controlled permeation of hydrocarbons: New membrane materials and results Yampolskii, Yu.; Starannikova, L.; Belov, N. Journal of Membrane Science, Vol. 453 https://doi.org/10.1016/j.memsci.2013.11.002	journal	March 2014
CO2-selective membranes for hydrogen production and CO2 capture – Part I: Membrane development Lin, Haiqing; He, Zhenjie; Sun, Zhen Journal of Membrane Science, Vol. 457 https://doi.org/10.1016/j.memsci.2014.01.020	journal	May 2014
Pure- and mixed-gas CO2/CH4 separation properties of PIM-1 and an amidoxime-functionalized PIM-1 Swaidan, Raja; Ghanem, Bader S.; Litwiller, Eric Journal of Membrane Science, Vol. 457 https://doi.org/10.1016/j.memsci.2014.01.055	journal	May 2014
Analysis of feed stream acid gas concentration effects on the transport properties and separation performance of polymeric membranes for natural gas sweetening: A comparison between a glassy and rubbery polymer Vaughn, Justin T.; Koros, William J. Journal of Membrane Science, Vol. 465 https://doi.org/10.1016/j.memsci.2014.03.029	journal	September 2014
Upper bound of polymeric membranes for mixed-gas CO2/CH4 separations Lin, Haiqing; Yavari, Milad Journal of Membrane Science, Vol. 475 https://doi.org/10.1016/j.memsci.2014.10.007	journal	February 2015
Comparison of transport properties of rubbery and glassy polymers and the relevance to the upper bound relationship Robeson, Lloyd M.; Liu, Qiang; Freeman, Benny D. Journal of Membrane Science, Vol. 476 https://doi.org/10.1016/j.memsci.2014.11.058	journal	February 2015
CO2-selective membranes for hydrogen production and CO2 capture – Part II: Techno-economic analysis Lin, Haiqing; He, Zhenjie; Sun, Zhen Journal of Membrane Science, Vol. 493 https://doi.org/10.1016/j.memsci.2015.02.042	journal	November 2015
Water vapor permeation through cellulose acetate membranes and its impact upon membrane separation performance for natural gas purification Chen, George Q.; Kanehashi, Shinji; Doherty, Cara M. Journal of Membrane Science, Vol. 487 https://doi.org/10.1016/j.memsci.2015.03.074	journal	August 2015
Influence of toluene on CO2 and CH4 gas transport properties in thermally rearranged (TR) polymers based on 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) Liu, Qiang; Galizia, Michele; Gleason, Kristofer L. Journal of Membrane Science, Vol. 514 https://doi.org/10.1016/j.memsci.2016.04.043	journal	September 2016
Molecular origins of fast and selective gas transport in pentiptycene-containing polyimide membranes and their physical aging behavior Luo, Shuangjiang; Wiegand, Jennifer R.; Gao, Peiyuan Journal of Membrane Science, Vol. 518 https://doi.org/10.1016/j.memsci.2016.06.034	journal	November 2016
Physical aging, CO 2 sorption and plasticization in thin films of polymer with intrinsic microporosity (PIM-1) Tiwari, Rajkiran R.; Jin, Jianyong; Freeman, B. D. Journal of Membrane Science, Vol. 537 https://doi.org/10.1016/j.memsci.2017.04.069	journal	September 2017
Cardo-type random co-polyimide membranes for high pressure pure and mixed sour gas feed separations Yahaya, Garba O.; Mokhtari, Ilham; Alghannam, Afnan A. Journal of Membrane Science, Vol. 550 https://doi.org/10.1016/j.memsci.2017.10.063	journal	March 2018
High pressure pure- and mixed sour gas transport properties of Cardo-type block co-polyimide membranes Alghannam, Afnan A.; Yahaya, Garba O.; Hayek, Ali Journal of Membrane Science, Vol. 553 https://doi.org/10.1016/j.memsci.2018.02.042	journal	May 2018
The impact of toluene and xylene on the performance of cellulose triacetate membranes for natural gas sweetening Lu, H. T.; Liu, L.; Kanehashi, S. Journal of Membrane Science, Vol. 555 https://doi.org/10.1016/j.memsci.2018.03.045	journal	June 2018
Post-crosslinking of triptycene-based Tröger's base polymers with enhanced natural gas separation performance Zhang, Caili; Fu, Linxiang; Tian, Zhikang Journal of Membrane Science, Vol. 556 https://doi.org/10.1016/j.memsci.2018.04.013	journal	June 2018
Crosslinkable TEGMC asymmetric hollow fiber membranes for aggressive sour gas separations Babu, Vinod P.; Kraftschik, Brian E.; Koros, William J. Journal of Membrane Science, Vol. 558 https://doi.org/10.1016/j.memsci.2018.04.028	journal	July 2018
Chilled membranes—Efficient gas permeation at sub-ambient temperatures Alders, M.; von Bargen, C.; König, A. Journal of Membrane Science, Vol. 576 https://doi.org/10.1016/j.memsci.2019.01.037	journal	April 2019
Surprising plasticization benefits in natural gas upgrading using polyimide membranes Liu, Yang; Liu, Zhongyun; Liu, Gongping Journal of Membrane Science, Vol. 593 https://doi.org/10.1016/j.memsci.2019.117430	journal	January 2020
Sour gas transport in poly(ether-b-amide) membranes for natural gas separations Harrigan, Daniel J.; Yang, John; Sundell, Benjamin J. Journal of Membrane Science, Vol. 595 https://doi.org/10.1016/j.memsci.2019.117497	journal	February 2020
Natural gas sweetening using a cellulose triacetate hollow fiber membrane illustrating controlled plasticization benefits Liu, Yang; Liu, Zhongyun; Morisato, Atsushi Journal of Membrane Science, Vol. 601 https://doi.org/10.1016/j.memsci.2020.117910	journal	March 2020
Tunable sour gas separations: Simultaneous H2S and CO2 removal from natural gas via crosslinked telechelic poly(ethylene glycol) membranes Harrigan, Daniel J.; Lawrence, John A.; Reid, Harrison W. Journal of Membrane Science, Vol. 602 https://doi.org/10.1016/j.memsci.2020.117947	journal	May 2020
Promoting acid gas separations via strategic alkoxysilyl substitution of vinyl-added poly(norbornene)s Lawrence, John A.; Harrigan, Daniel J.; Maroon, Christopher R. Journal of Membrane Science, Vol. 616 https://doi.org/10.1016/j.memsci.2020.118569	journal	December 2020
Penetrant competition and plasticization in membranes: How negatives can be positives in natural gas sweetening Liu, Yang; Chen, Zhijie; Qiu, Wulin Journal of Membrane Science, Vol. 627 https://doi.org/10.1016/j.memsci.2021.119201	journal	June 2021
Organic vapour permeation in amorphous and semi-crystalline rubbery membranes: Experimental data versus prediction by solubility parameters Jirsáková, Karolina; Stanovský, Petr; Dytrych, Pavel Journal of Membrane Science, Vol. 627 https://doi.org/10.1016/j.memsci.2021.119211	journal	June 2021
Polymeric membranes for CO2 separation and capture Han, Yang; Ho, W. S. Winston Journal of Membrane Science, Vol. 628 https://doi.org/10.1016/j.memsci.2021.119244	journal	June 2021
Natural gas sweetening using TEGMC polyimide hollow fiber membranes Liu, Yang; Liu, Zhongyun; Kraftschik, Brian E. Journal of Membrane Science, Vol. 632 https://doi.org/10.1016/j.memsci.2021.119361	journal	August 2021
The influence of propane and n-butane on the structure and separation performance of cellulose acetate membranes Liu, Liang; Doherty, Cara M.; Ricci, Eleonora Journal of Membrane Science, Vol. 638 https://doi.org/10.1016/j.memsci.2021.119677	journal	November 2021
Hydrogen sulfide mix gas permeation in Aquivion® perfluorosulfonic acid (PFSA) ionomer membranes for natural gas sweetening Signorini, Virginia; Giacinti Baschetti, Marco; Pizzi, Diego Journal of Membrane Science, Vol. 640 https://doi.org/10.1016/j.memsci.2021.119809	journal	December 2021
Membrane research beyond materials science Beuscher, U.; Kappert, E. J.; Wijmans, J. G. Journal of Membrane Science, Vol. 643 https://doi.org/10.1016/j.memsci.2021.119902	journal	March 2022
Materials selection guidelines for membranes that remove CO₂ from gas mixtures Lin, Haiqing; Freeman, Benny D. Journal of Molecular Structure, Vol. 739, Issue 1-3, p. 57-74 https://doi.org/10.1016/j.molstruc.2004.07.045	journal	April 2005
Polymers of intrinsic microporosity for energy-intensive membrane-based gas separations Wang, Y.; Ma, X.; Ghanem, B. S. Materials Today Nano, Vol. 3 https://doi.org/10.1016/j.mtnano.2018.11.003	journal	August 2018
Toluene and n-heptane sorption in Matrimid® asymmetric hollow fiber membranes Lee, Jong Suk; Adams, Ryan T.; Madden, William Polymer, Vol. 50, Issue 25 https://doi.org/10.1016/j.polymer.2009.10.015	journal	November 2009
Energy-efficient polymeric gas separation membranes for a sustainable future: A review Sanders, David F.; Smith, Zachary P.; Guo, Ruilan Polymer, Vol. 54, Issue 18 https://doi.org/10.1016/j.polymer.2013.05.075	journal	August 2013
Suppression of aging and plasticization in highly permeable polymers Yong, Wai Fen; Kwek, Kar Hui Andrel; Liao, Kuo-Sung Polymer, Vol. 77 https://doi.org/10.1016/j.polymer.2015.09.075	journal	October 2015
Cellulose triacetate doped with ionic liquids for membrane gas separation Lam, Benjamin; Wei, Min; Zhu, Lingxiang Polymer, Vol. 89 https://doi.org/10.1016/j.polymer.2016.02.033	journal	April 2016
Suppressed crystallization and enhanced gas permeability in thin films of cellulose acetate blends Nguyen, Hien; Hsiao, Ming-Yin; Nagai, Kazukiyo Polymer, Vol. 205 https://doi.org/10.1016/j.polymer.2020.122790	journal	September 2020
The strategies of molecular architecture and modification of polyimide-based membranes for CO2 removal from natural gas—A review Xiao, Youchang; Low, Bee Ting; Hosseini, Seyed Saeid Progress in Polymer Science, Vol. 34, Issue 6 https://doi.org/10.1016/j.progpolymsci.2008.12.004	journal	June 2009
A review of the latest development of polyimide based membranes for CO 2 separations Favvas, Evangelos P.; Katsaros, Fotios K.; Papageorgiou, Sergios K. Reactive and Functional Polymers, Vol. 120 https://doi.org/10.1016/j.reactfunctpolym.2017.09.002	journal	November 2017
An assessment of Iran's natural gas potential for transition toward low-carbon economy Hafeznia, Hamed; Pourfayaz, Fathollah; Maleki, Akbar Renewable and Sustainable Energy Reviews, Vol. 79 https://doi.org/10.1016/j.rser.2017.05.042	journal	November 2017
Possible pathways for oil and gas companies in a sustainable future: From the perspective of a hydrogen economy Hunt, Julian David; Nascimento, Andreas; Nascimento, Nazem Renewable and Sustainable Energy Reviews, Vol. 160 https://doi.org/10.1016/j.rser.2022.112291	journal	May 2022
Pebax®/polyethylene glycol blend thin film composite membranes for CO2 separation: Performance with mixed gases Car, Anja; Stropnik, Chrtomir; Yave, Wilfredo Separation and Purification Technology, Vol. 62, Issue 1 https://doi.org/10.1016/j.seppur.2008.01.001	journal	August 2008
Sour mixed-gas upper bounds of glassy polymeric membranes Hayek, Ali; Shalabi, Yasser A.; Alsamah, Abdulkarim Separation and Purification Technology, Vol. 277 https://doi.org/10.1016/j.seppur.2021.119535	journal	December 2021
Super high gas separation performance membranes derived from a brominated alternative PIM by thermal induced crosslinking and carbonization at low temperature Weng, Yatao; Li, Nanwen; Xu, Zelong Separation and Purification Technology, Vol. 314 https://doi.org/10.1016/j.seppur.2023.123548	journal	June 2023
Sustainable applications utilizing sulfur, a by-product from oil and gas industry: A state-of-the-art review Wagenfeld, Jan-Georg; Al-Ali, Khalid; Almheiri, Saif Waste Management, Vol. 95 https://doi.org/10.1016/j.wasman.2019.06.002	journal	July 2019
Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes Shah, Mansi S.; Tsapatsis, Michael; Siepmann, J. Ilja Chemical Reviews, Vol. 117, Issue 14 https://doi.org/10.1021/acs.chemrev.7b00095	journal	May 2017
Gas Permeation Properties, Physical Aging, and Its Mitigation in High Free Volume Glassy Polymers Low, Ze-Xian; Budd, Peter M.; McKeown, Neil B. Chemical Reviews, Vol. 118, Issue 12 https://doi.org/10.1021/acs.chemrev.7b00629	journal	May 2018
Problems Associated with Sour Gas in the Oilfield Industry and Their Solutions Goodwin, Melissa J.; Musa, Osama M.; Steed, Jonathan W. Energy & Fuels, Vol. 29, Issue 8 https://doi.org/10.1021/acs.energyfuels.5b00952	journal	August 2015
Tapping Singular Middle Eastern Ultrasour Gas Resources Combining Membrane and Absorption Systems: Potential for Energy Intensity Reduction Alkatheri, Mohammed; Grandas, Ricardo; Betancourt-Torcat, Alberto Industrial & Engineering Chemistry Research, Vol. 57, Issue 17 https://doi.org/10.1021/acs.iecr.7b02200	journal	November 2017
Experimental Study of a Hydrophobic Solvent for Natural Gas Sweetening Based on the Solubility and Selectivity for Light Hydrocarbons (CH ₄ , C ₂ H ₆ ) and Acid Gases (CO ₂ and H ₂ S) at 298–353 K Tanthana, Jak; Rayer, Aravind V.; Gupta, Vijay Journal of Chemical & Engineering Data, Vol. 64, Issue 2 https://doi.org/10.1021/acs.jced.8b00735	journal	January 2019
How to Get the Best Gas Separation Membranes from State-of-the-Art Glassy Polymers León, Nicholas E.; Liu, Zhongyun; Irani, Maryam Macromolecules, Vol. 55, Issue 5 https://doi.org/10.1021/acs.macromol.1c01758	journal	February 2022
Physical Aging, Plasticization and Their Effects on Gas Permeation in “Rigid” Polymers of Intrinsic Microporosity Swaidan, Raja; Ghanem, Bader; Litwiller, Eric Macromolecules, Vol. 48, Issue 18 https://doi.org/10.1021/acs.macromol.5b01581	journal	August 2015
Polymer Free Volume and Its Connection to the Glass Transition White, Ronald P.; Lipson, Jane E. G. Macromolecules, Vol. 49, Issue 11 https://doi.org/10.1021/acs.macromol.6b00215	journal	May 2016
Elimination of CO ₂ /N ₂ Langmuir Sorption and Promotion of “N ₂ -Phobicity” within High- T _g Glassy Membranes Maroon, Christopher R.; Townsend, Jacob; Gmernicki, Kevin R. Macromolecules, Vol. 52, Issue 4 https://doi.org/10.1021/acs.macromol.8b02497	journal	February 2019
Mitigation of Physical Aging with Mixed Matrix Membranes Based on Cross-Linked PIM-1 Fillers and PIM-1 Tamaddondar, Marzieh; Foster, Andrew B.; Carta, Mariolino ACS Applied Materials & Interfaces, Vol. 12, Issue 41 https://doi.org/10.1021/acsami.0c13838	journal	September 2020
Unprecedented Sour Mixed-Gas Permeation Properties of Fluorinated Polyazole-Based Membranes Hayek, Ali; Alsamah, Abdulkarim; Alaslai, Nasser ACS Applied Polymer Materials, Vol. 2, Issue 6 https://doi.org/10.1021/acsapm.0c00196	journal	May 2020
On the Effect of the Reaction Medium on the HydroClaus Process: A Novel Sustainable H₂S Valorization Strategy Spatolisano, Elvira; De Guido, Giorgia; Sangiorgio, Vito Andrea ACS Sustainable Chemistry & Engineering, Vol. 11, Issue 15 https://doi.org/10.1021/acssuschemeng.3c00821	journal	April 2023
Gas Separation, Free Volume Distribution, and Physical Aging of a Highly Microporous Spirobisindane Polymer Staiger, Chad L.; Pas, Steven J.; Hill, Anita J. Chemistry of Materials, Vol. 20, Issue 8 https://doi.org/10.1021/cm071722t	journal	April 2008
Catalytic Decomposition of Hydrogen Sulfide Fukuda, K.; Dokiya, M.; Kameyama, T. Industrial & Engineering Chemistry Fundamentals, Vol. 17, Issue 4 https://doi.org/10.1021/i160068a002	journal	November 1978
Separation of Binary Mixtures of CO and H ₂ by Permeation Through Polymeric Films McCandless, F. P. Industrial & Engineering Chemistry Process Design and Development, Vol. 11, Issue 4 https://doi.org/10.1021/i260044a003	journal	October 1972
Selective Transport of Sulfur Dioxide through Polymer Membranes. 1. Polyacrylate and Cellulose Triacetate Single-Layer Membranes Kuehne, Donald L.; Friedlander, Sheldon K. Industrial & Engineering Chemistry Process Design and Development, Vol. 19, Issue 4 https://doi.org/10.1021/i260076a018	journal	October 1980
Future Directions of Membrane Gas Separation Technology Baker, Richard W. Industrial & Engineering Chemistry Research, Vol. 41, Issue 6 https://doi.org/10.1021/ie0108088	journal	March 2002
Natural Gas Processing with Membranes: An Overview Baker, Richard W.; Lokhandwala, Kaaeid Industrial & Engineering Chemistry Research, Vol. 47, Issue 7 https://doi.org/10.1021/ie071083w	journal	April 2008
Acid Gas Permeation Behavior Through Poly(Ester Urethane Urea) Membrane Mohammadi, T.; Moghadam, M. Tavakol; Saeidi, M. Industrial & Engineering Chemistry Research, Vol. 47, Issue 19 https://doi.org/10.1021/ie071493k	journal	September 2008
Effect of Hydrocarbons on the Separation of Carbon Dioxide From Methane through a Polyimide Gas Separation Membrane Hasan, Raza; Scholes, Colin A.; Stevens, Geoff W. Industrial & Engineering Chemistry Research, Vol. 48, Issue 11 https://doi.org/10.1021/ie801537g	journal	April 2009
Gas permeation properties of poly(ether imide) segmented copolymers Okamoto, Ken-ichi; Fuji, Masafumi; Okamyo, Shuusaku Macromolecules, Vol. 28, Issue 20 https://doi.org/10.1021/ma00124a035	journal	September 1995
Comparison of Hydrogen Sulfide Transport Properties in Fluorinated and Nonfluorinated Polymers Merkel, T. C.; Toy, L. G. Macromolecules, Vol. 39, Issue 22 https://doi.org/10.1021/ma061072z	journal	October 2006
Structural Characterization of a Polymer of Intrinsic Microporosity: X-ray Scattering with Interpretation Enhanced by Molecular Dynamics Simulations McDermott, Amanda G.; Larsen, Gregory S.; Budd, Peter M. Macromolecules, Vol. 44, Issue 1 https://doi.org/10.1021/ma1024945	journal	January 2011
Synthesis and Gas Transport Properties of Hydroxyl-Functionalized Polyimides with Intrinsic Microporosity Ma, Xiaohua; Swaidan, Raja; Belmabkhout, Youssef Macromolecules, Vol. 45, Issue 9 https://doi.org/10.1021/ma300549m	journal	April 2012
Effect of the Amide Bond Diamine Structure on the CO ₂ , H ₂ S, and CH ₄ Transport Properties of a Series of Novel 6FDA-Based Polyamide–Imides for Natural Gas Purification Vaughn, J.; Koros, W. J. Macromolecules, Vol. 45, Issue 17 https://doi.org/10.1021/ma301249x	journal	August 2012
Silane Modification of Cellulose Acetate Dense Films as Materials for Acid Gas Removal Achoundong, Carine S. K.; Bhuwania, Nitesh; Burgess, Steven K. Macromolecules, Vol. 46, Issue 14 https://doi.org/10.1021/ma4010583	journal	July 2013
Cross-Linkable Polyimide Membranes for Improved Plasticization Resistance and Permselectivity in Sour Gas Separations Kraftschik, Brian; Koros, William J. Macromolecules, Vol. 46, Issue 17 https://doi.org/10.1021/ma401542j	journal	August 2013
Role of Intrachain Rigidity in the Plasticization of Intrinsically Microporous Triptycene-Based Polyimide Membranes in Mixed-Gas CO ₂ /CH ₄ Separations Swaidan, Raja; Ghanem, Bader; Al-Saeedi, Majed Macromolecules, Vol. 47, Issue 21 https://doi.org/10.1021/ma501798v	journal	October 2014
Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes Freeman, Benny D. Macromolecules, Vol. 32, Issue 2 https://doi.org/10.1021/ma9814548	journal	January 1999
Accelerated Physical Aging of Thin Poly[1-(trimethylsilyl)-1-propyne] Films Dorkenoo, Kokou D.; Pfromm, Peter H. Macromolecules, Vol. 33, Issue 10 https://doi.org/10.1021/ma9921145	journal	May 2000
A high-performance hydroxyl-functionalized polymer of intrinsic microporosity for an environmentally attractive membrane-based approach to decontamination of sour natural gas Yi, Shouliang; Ma, Xiaohua; Pinnau, Ingo Journal of Materials Chemistry A, Vol. 3, Issue 45 https://doi.org/10.1039/C5TA05928C	journal	January 2015
Preparation and gas transport properties of triptycene-containing polybenzoxazole (PBO)-based polymers derived from thermal rearrangement (TR) and thermal cyclodehydration (TC) processes Luo, Shuangjiang; Liu, Junyi; Lin, Haiqing Journal of Materials Chemistry A, Vol. 4, Issue 43 https://doi.org/10.1039/C6TA03951K	journal	January 2016
Ultra-selective defect-free interfacially polymerized molecular sieve thin-film composite membranes for H ₂ purification Ali, Z.; Pacheco, F.; Litwiller, E. Journal of Materials Chemistry A, Vol. 6, Issue 1 https://doi.org/10.1039/C7TA07819F	journal	January 2018
Redefining the Robeson upper bounds for CO ₂ /CH ₄ and CO ₂ /N ₂ separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity Comesaña-Gándara, Bibiana; Chen, Jie; Bezzu, C. Grazia Energy & Environmental Science, Vol. 12, Issue 9 https://doi.org/10.1039/C9EE01384A	journal	January 2019
Post-synthetic modification of CARDO-based materials: application in sour natural gas separation Hayek, Ali; Alsamah, Abdulkarim; Yahaya, Garba O. Journal of Materials Chemistry A, Vol. 8, Issue 44 https://doi.org/10.1039/D0TA06967A	journal	January 2020
Hydrogen sulfide removal from natural gas using membrane technology: a review Ma, Yulei; Guo, Hongfang; Selyanchyn, Roman Journal of Materials Chemistry A, Vol. 9, Issue 36 https://doi.org/10.1039/D1TA04693D	journal	January 2021
Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials Budd, Peter M.; Ghanem, Bader S.; Makhseed, Saad Chemical Communications, Issue 2 https://doi.org/10.1039/b311764b	journal	January 2004
On a General Relation Involving the Glass Temperature and Coefficients of Expansion of Polymers Simha, Robert; Boyer, R. F. The Journal of Chemical Physics, Vol. 37, Issue 5 https://doi.org/10.1063/1.1733201	journal	September 1962
Pentiptycene-based ladder polymers with configurational free volume for enhanced gas separation performance and physical aging resistance Corrado, Tanner J.; Huang, Zihan; Huang, Dezhao Proceedings of the National Academy of Sciences, Vol. 118, Issue 37 https://doi.org/10.1073/pnas.2022204118	journal	September 2021
Ultraselective glassy polymer membranes with unprecedented performance for energy-efficient sour gas separation Yi, Shouliang; Ghanem, Bader; Liu, Yang Science Advances, Vol. 5, Issue 5 https://doi.org/10.1126/sciadv.aaw5459	journal	May 2019
Plasticization-Enhanced Hydrogen Purification Using Polymeric Membranes Lin, H. Science, Vol. 311, Issue 5761 https://doi.org/10.1126/science.1118079	journal	February 2006
Characteristics of Gas Compositions in Giant Gas Fields of China Gong, Deyu; Huang, Shipeng; Wu, Wei Energy Exploration & Exploitation, Vol. 32, Issue 4 https://doi.org/10.1260/0144-5987.32.4.635	journal	August 2014
Extracting Profits From Abu Dhabi's Sour Gas Henni, Abdelghani Journal of Petroleum Technology, Vol. 65, Issue 03 https://doi.org/10.2118/0313-0076-JPT	journal	March 2013
Taking on the Technical Challenges of Sour Gas Processing Boschee, Pam Oil and Gas Facilities, Vol. 3, Issue 06 https://doi.org/10.2118/1214-0021-OGF	journal	December 2014
Selection of Materials for Sour Service in Petroleum Production Wilhelm, S. Mark; Kane, Russell D. Journal of Petroleum Technology, Vol. 38, Issue 10 https://doi.org/10.2118/16040-PA	journal	October 1986
Separation of organic azeotropic mixtures by pervaporation. Final technical report Baker, R. W. https://doi.org/10.2172/10114332	report	December 1991
Low-quality natural gas sulfur removal/recovery with membranes Lokhandwala, K. A.; Amo, K. A.; Baker, R. W. https://doi.org/10.2172/10119737	report	December 1993
Membrane separation processes in the petrochemical industry: Part 1: Phase 2, Final summary report, October 31, 1985—September 30, 1987 Li, N.; Funk, E.; Chang, Y. https://doi.org/10.2172/6290984	report	September 1987
Hybrid System – An Emerging Solution to Sour Gas Treatment Parekh, Siddharth Day 2 Tue, January 14, 2020 https://doi.org/10.2523/IPTC-19783-MS	conference	January 2020
The Impact of Various Natural Gas Contaminant Exposures on CO2/CH4 Separation by a Polyimide Membrane Nemestóthy, Nándor; Bakonyi, Péter; Lajtai-Szabó, Piroska Membranes, Vol. 10, Issue 11 https://doi.org/10.3390/membranes10110324	journal	October 2020
Impact of Prolonged Exposure to Sour Service on the Mechanical Properties and Corrosion Mechanism of NACE Carbon Steel Material Used in Wet Sour Gas Multiphase Pipeline Yadav, Manoj; Sliem, Mostafa H.; Abdullah, Aboubakr M. Sustainability, Vol. 14, Issue 13 https://doi.org/10.3390/su14138015	journal	June 2022
High H2S Gas Field Monetization: A Novel Approach Jariwala, Ankur Day 3 Wed, May 08, 2019 https://doi.org/10.4043/29370-MS	conference	April 2019

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