Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities

Li, Xiaoxiao; Cai, Runlong; Hao, Jiming; Smith, James N.; Jiang, Jingkun

doi:10.1016/j.trac.2023.117195

Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities

Journal Article · Mon Jul 17 00:00:00 UTC 2023 · TrAC, Trends in Analytical Chemistry

DOI:https://doi.org/10.1016/j.trac.2023.117195· OSTI ID:2421807

Li, Xiaoxiao ^[1]; Cai, Runlong ^[2]; Hao, Jiming ^[3]; Smith, James N. ^[4]; Jiang, Jingkun ^[3]

Tsinghua Univ., Beijing (China); Wuhan Univ. (China); OSTI
Univ. of Helsinki (Finland)
Tsinghua Univ., Beijing (China)
Univ. of California, Irvine, CA (United States)

Airborne nanoparticles are receiving growing attention due to their impacts on human health, air quality, and climate. Additionally, there are increasing applications of aerosol-based nanotechnology. Real-time measurement of airborne nanoparticle composition is challenging due to their small masses and the difficulties in effectively separating them from larger particles. Custom-built instruments based on mass spectrometry have been developed for nanoparticle composition, including thermal desorption-based, laser-based, and solution-based techniques. They have significantly promoted the understanding of airborne nanoparticles in the last two decades. However, they are affected by molecular fragmentation, lack of mass-resolving power, incomplete species detection, and difficulties in directly comparing to gas-phase measurements. Recent developments in atmospheric mass spectrometry provide possible solutions. Here, this review presents the potential application of these new advances to real-time measurements of the molecular nanoparticle composition and discusses the associated challenges. Such measurements present opportunities for a more comprehensive view of airborne nanoparticles and their impacts.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); National Science Foundation (NSF); USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0021208

OSTI ID:: 2421807

Alternate ID(s):: OSTI ID: 1992694

Journal Information:: TrAC, Trends in Analytical Chemistry, Journal Name: TrAC, Trends in Analytical Chemistry Journal Issue: C Vol. 166; ISSN 0165-9936

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation Wang, Dongyu S.; Lee, Chuan Ping; Krechmer, Jordan E. Atmospheric Measurement Techniques, Vol. 14, Issue 11 https://doi.org/10.5194/amt-14-6955-2021	journal	November 2021
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A field-deployable, chemical ionization time-of-flight mass spectrometer Bertram, T. H.; Kimmel, J. R.; Crisp, T. A. Atmospheric Measurement Techniques, Vol. 4, Issue 7 https://doi.org/10.5194/amt-4-1471-2011	journal	January 2011
A chemical analyzer for charged ultrafine particles Gonser, S. G.; Held, A. Atmospheric Measurement Techniques, Vol. 6, Issue 9 https://doi.org/10.5194/amt-6-2339-2013	journal	January 2013
High-resolution chemical ionization mass spectrometry (ToF-CIMS): application to study SOA composition and processing Aljawhary, D.; Lee, A. K. Y.; Abbatt, J. P. D. Atmospheric Measurement Techniques, Vol. 6, Issue 11 https://doi.org/10.5194/amt-6-3211-2013	journal	January 2013
The ToF-ACSM: a portable aerosol chemical speciation monitor with TOFMS detection Fröhlich, R.; Cubison, M. J.; Slowik, J. G. Atmospheric Measurement Techniques, Vol. 6, Issue 11 https://doi.org/10.5194/amt-6-3225-2013	journal	January 2013
A novel method for online analysis of gas and particle composition: description and evaluation of a Filter Inlet for Gases and AEROsols (FIGAERO) Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M. Atmospheric Measurement Techniques, Vol. 7, Issue 4 https://doi.org/10.5194/amt-7-983-2014	journal	January 2014
Application of high-resolution time-of-flight chemical ionization mass spectrometry measurements to estimate volatility distributions of α-pinene and naphthalene oxidation products Chhabra, P. S.; Lambe, A. T.; Canagaratna, M. R. Atmospheric Measurement Techniques, Vol. 8, Issue 1 https://doi.org/10.5194/amt-8-1-2015	journal	January 2015
Statistical precision of the intensities retrieved from constrained fitting of overlapping peaks in high-resolution mass spectra Cubison, M. J.; Jimenez, J. L. Atmospheric Measurement Techniques, Vol. 8, Issue 6 https://doi.org/10.5194/amt-8-2333-2015	journal	January 2015
A switchable reagent ion high resolution time-of-flight chemical ionization mass spectrometer for real-time measurement of gas phase oxidized species: characterization from the 2013 southern oxidant and aerosol study Brophy, P.; Farmer, D. K. Atmospheric Measurement Techniques, Vol. 8, Issue 7 https://doi.org/10.5194/amt-8-2945-2015	journal	January 2015
Characterization of the mass-dependent transmission efficiency of a CIMS Heinritzi, Martin; Simon, Mario; Steiner, Gerhard Atmospheric Measurement Techniques, Vol. 9, Issue 4 https://doi.org/10.5194/amt-9-1449-2016	journal	January 2016
Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds Kim, Michelle J.; Zoerb, Matthew C.; Campbell, Nicole R. Atmospheric Measurement Techniques, Vol. 9, Issue 4 https://doi.org/10.5194/amt-9-1473-2016	journal	January 2016
A high-resolution time-of-flight chemical ionization mass spectrometer utilizing hydronium ions (H ₃ O ⁺ ToF-CIMS) for measurements of volatile organic compounds in the atmosphere Yuan, Bin; Koss, Abigail; Warneke, Carsten Atmospheric Measurement Techniques, Vol. 9, Issue 6 https://doi.org/10.5194/amt-9-2735-2016	journal	January 2016
Evaluation of NO ⁺ reagent ion chemistry for online measurements of atmospheric volatile organic compounds Koss, Abigail R.; Warneke, Carsten; Yuan, Bin Atmospheric Measurement Techniques, Vol. 9, Issue 7 https://doi.org/10.5194/amt-9-2909-2016	journal	January 2016
A new technique for the direct detection of HO ₂ radicals using bromide chemical ionization mass spectrometry (Br-CIMS): initial characterization Sanchez, Javier; Tanner, David J.; Chen, Dexian Atmospheric Measurement Techniques, Vol. 9, Issue 8 https://doi.org/10.5194/amt-9-3851-2016	journal	January 2016

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Online detection of airborne nanoparticle composition with mass spectrometry: Recent advances, challenges, and opportunities

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