Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity

Vance, Brandon C.; Najmi, Sean; Kots, Pavel A.; Wang, Cong; Jeon, Sungho; Stach, Eric A.; Zakharov, Dmitri N.; Marinkovic, Nebojsa; Ehrlich, Steven N.; Ma, Lu; Vlachos, Dionisios G.

doi:10.1021/jacsau.3c00232

Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity

Journal Article · Fri Jul 14 00:00:00 EDT 2023 · JACS Au

DOI:https://doi.org/10.1021/jacsau.3c00232· OSTI ID:1989723

Vance, Brandon C. ^[1]; Najmi, Sean ^[2]; ^[2]; ^[2]; Jeon, Sungho ^[3]; ^[3]; Zakharov, Dmitri N. ^[4]; Marinkovic, Nebojsa ^[5]; Ehrlich, Steven N. ^[6]; Ma, Lu ^[6]; ^[1]

Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States, Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street, Newark, Delaware 19716, United States
Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States
Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States
Center for Functional Nanomaterials, Brookhaven National Laboratory, 735 Brookhaven Avenue, Upton, New York 11973, United States
Department of Chemical Engineering, Columbia University, 500W 120th Street, New York, New York 10027, United States
National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973, United States

Not Available

View Journal Article

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); University of Delaware, Newark, DE (United States)

Sponsoring Organization:: National Institute of General Medical Sciences (NIGMS); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0021166; SC0021173

OSTI ID:: 1989723

Alternate ID(s):: OSTI ID: 2005145
OSTI ID: 1997337

Report Number(s):: BNL--224831-2023-JAAM

Journal Information:: JACS Au, Journal Name: JACS Au Journal Issue: 8 Vol. 3; ISSN 2691-3704

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (63)

Lewis Acid Strength of Interfacial Metal Sites Drives CH ₃ OH Selectivity and Formation Rates on Cu‐Based CO ₂ Hydrogenation Catalysts Noh, Gina; Lam, Erwin; Bregante, Daniel T. Angewandte Chemie International Edition, Vol. 60, Issue 17 https://doi.org/10.1002/ANIE.202100672	journal	March 2021
Lewis Acid-Promoted Heterogeneous Platinum Catalysts for Hydrogenation of Amides to Amines Shimizu, Ken-ichi; Onodera, Wataru; Touchy, Abeda S. ChemistrySelect, Vol. 1, Issue 4 https://doi.org/10.1002/SLCT.201600088	journal	April 2016
Infrared studies of CO, O2, and CO2 gases and their interaction products, chemically adsorbed on nickel oxide Courtois, M. Journal of Catalysis, Vol. 1, Issue 2 https://doi.org/10.1016/0021-9517(62)90016-7	journal	May 1962
Hydrogenolysis of saturated hydrocarbons on a nickel catalyst I. Kinetics of hydrogenolysis of ethylcyclohexane and reactivity of alkylcyclohexanes Kochloefl, K. Journal of Catalysis, Vol. 8, Issue 3 https://doi.org/10.1016/0021-9517(67)90312-0	journal	July 1967
Hydrogenolysis of saturated hydrocarbons on a nickel catalyst II. Selectivity of hydrogenolytic cleavage of some aliphatic and alicyclic hydrocarbons and their reactivity Kochloefl, K. Journal of Catalysis, Vol. 10, Issue 2 https://doi.org/10.1016/0021-9517(68)90166-8	journal	February 1968
Contrast between nickel and platinum catalysts in hydrogenolysis of saturated hydrocarbons Matsumoto, H. Journal of Catalysis, Vol. 19, Issue 2 https://doi.org/10.1016/0021-9517(70)90272-1	journal	November 1970
The classification of metal catalysts in hydrogenolysis of hexane isomers Matsumoto, H. Journal of Catalysis, Vol. 22, Issue 2 https://doi.org/10.1016/0021-9517(71)90184-9	journal	August 1971
The adsorption sites of CO on Ni(111) as determined by infrared reflection-absorption spectroscopy Campuzano, Juan Carlos; Greenler, Robert G. Surface Science, Vol. 83, Issue 1 https://doi.org/10.1016/0039-6028(79)90495-3	journal	April 1979
Comparison of reducibility and stability of alumina-supported Ni catalysts prepared by impregnation and co-precipitation Li, Guohui; Hu, Linjie; Hill, Josephine M. Applied Catalysis A: General, Vol. 301, Issue 1 https://doi.org/10.1016/J.APCATA.2005.11.013	journal	February 2006
Partial oxidation of methane to syngas on bulk NiAl2O4 catalyst. Comparison with alumina supported nickel, platinum and rhodium catalysts López-Fonseca, Rubén; Jiménez-González, Cristina; de Rivas, Beatriz Applied Catalysis A: General, Vol. 437-438 https://doi.org/10.1016/J.APCATA.2012.06.014	journal	September 2012
Effect of Ni/Al molar ratio on the performance of substoichiometric NiAl 2 O 4 spinel-based catalysts for partial oxidation of methane Gil-Calvo, Miryam; Jiménez-González, Cristina; de Rivas, Beatriz Applied Catalysis B: Environmental, Vol. 209 https://doi.org/10.1016/J.APCATB.2017.02.063	journal	July 2017
Nickel aluminate spinel-derived catalysts for the aqueous phase reforming of glycerol: Effect of reduction temperature Morales-Marín, A.; Ayastuy, J. L.; Iriarte-Velasco, U. Applied Catalysis B: Environmental, Vol. 244 https://doi.org/10.1016/J.APCATB.2018.12.020	journal	May 2019
Structure-activity relationship in hydrogenolysis of polyolefins over Ru/support catalysts Tamura, Masazumi; Miyaoka, Shuhei; Nakaji, Yosuke Applied Catalysis B: Environmental, Vol. 318 https://doi.org/10.1016/J.APCATB.2022.121870	journal	December 2022
Non-thermal plasma-assisted hydrogenolysis of polyethylene to light hydrocarbons Yao, Libo; King, Jaelynne; Wu, Dezhen Catalysis Communications, Vol. 150 https://doi.org/10.1016/J.CATCOM.2020.106274	journal	February 2021
Plastic waste upgrade to olefins via mild slurry microwave pyrolysis over solid acids Selvam, Esun; Kots, Pavel A.; Hernandez, Borja Chemical Engineering Journal, Vol. 454 https://doi.org/10.1016/J.CEJ.2022.140332	journal	February 2023
A highly effective and stable nano-sized Ni/MgO–Al₂O₃ catalyst for gas to liquids (GTL) process Koo, Kee Young; Roh, Hyun-Seog; Seo, Yu Taek International Journal of Hydrogen Energy, Vol. 33, Issue 8, p. 2036-2043 https://doi.org/10.1016/J.IJHYDENE.2008.02.029	journal	April 2008
Development of highly effective supported nickel catalysts for pre-reforming of liquefied petroleum gas under low steam to carbon molar ratios Zou, Xiujing; Wang, Xueguang; Li, Lin International Journal of Hydrogen Energy, Vol. 35, Issue 22 https://doi.org/10.1016/J.IJHYDENE.2010.08.080	journal	November 2010
Physico-chemical properties and syngas production via dry reforming of methane over NiAl2O4 catalyst Benrabaa, Rafik; Barama, Akila; Boukhlouf, Hamza International Journal of Hydrogen Energy, Vol. 42, Issue 18 https://doi.org/10.1016/J.IJHYDENE.2017.04.030	journal	May 2017
Pyrolysis of plastic species: A review of resources and products Maqsood, Tariq; Dai, Jinze; Zhang, Yaning Journal of Analytical and Applied Pyrolysis, Vol. 159 https://doi.org/10.1016/J.JAAP.2021.105295	journal	October 2021
A review on microplastics and nanoplastics in the environment: Their occurrence, exposure routes, toxic studies, and potential effects on human health Sangkham, Sarawut; Faikhaw, Orasai; Munkong, Narongsuk Marine Pollution Bulletin, Vol. 181 https://doi.org/10.1016/J.MARPOLBUL.2022.113832	journal	August 2022
Waste cooking oil transformation into third generation green diesel catalyzed by nickel – Alumina catalysts Nikolopoulos, Ioannis; Kogkos, George; Kordouli, Eleana Molecular Catalysis, Vol. 482 https://doi.org/10.1016/J.MCAT.2019.110697	journal	February 2020
Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule Hadjiivanov, Konstantin I.; Vayssilov, Georgi N. Advances in Catalysis https://doi.org/10.1016/S0360-0564(02)47008-3	book	January 2002
Green diesel production over nickel-alumina co-precipitated catalysts Gousi, Mantha; Andriopoulou, Chrysanthi; Bourikas, Kyriakos Applied Catalysis A: General, Vol. 536 https://doi.org/10.1016/j.apcata.2017.02.010	journal	April 2017
Single Pot Catalyst Strategy to Branched Products via Adhesive Isomerization and Hydrocracking of Polyethylene over Platinum Tungstated Zirconia Vance, Brandon C.; Kots, Pavel A.; Wang, Cong Applied Catalysis B: Environmental https://doi.org/10.1016/j.apcatb.2021.120483	journal	June 2021
Metathesis, molecular redistribution of alkanes, and the chemical upgrading of low-density polyethylene Kim, Doyoung; Hinton, Zachary R.; Bai, Peng Applied Catalysis B: Environmental, Vol. 318 https://doi.org/10.1016/j.apcatb.2022.121873	journal	December 2022
A general strategy and a consolidated mechanism for low-methane hydrogenolysis of polyethylene over ruthenium Wang, Cong; Yu, Kewei; Sheludko, Boris Applied Catalysis B: Environmental, Vol. 319 https://doi.org/10.1016/j.apcatb.2022.121899	journal	December 2022
Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanism Vance, Brandon C.; Kots, Pavel A.; Wang, Cong Applied Catalysis B: Environmental, Vol. 322 https://doi.org/10.1016/j.apcatb.2022.122138	journal	March 2023
Ni–Al2O3 catalysts prepared by solution combustion method for syngas methanation Zhao, Anmin; Ying, Weiyong; Zhang, Haitao Catalysis Communications, Vol. 17 https://doi.org/10.1016/j.catcom.2011.10.010	journal	January 2012
Systematic study on the properties of nickel aluminate (NiAl2O4) as a catalytic precursor for aqueous phase hydrogenolysis of glycerol Pamphile-Adrian, Aracelis J.; Passos, Fabio B.; Florez-Rodriguez, Pedro P. Catalysis Today, Vol. 394-396 https://doi.org/10.1016/j.cattod.2021.07.002	journal	July 2022
Catalytic hydrogenolysis of plastic to liquid hydrocarbons over a nickel-based catalyst Zhao, Zhigang; Li, Zheng; Zhang, Xiangkun Environmental Pollution, Vol. 313 https://doi.org/10.1016/j.envpol.2022.120154	journal	November 2022
Understanding correlation of the interaction between nickel and alumina with the catalytic behaviors in steam reforming and methanation Zhang, Zhanming; Wei, Tao; Chen, Guozhu Fuel, Vol. 250 https://doi.org/10.1016/j.fuel.2019.04.005	journal	August 2019
Plastic pollution in the marine environment Thushari, G. G. N.; Senevirathna, J. D. M. Heliyon, Vol. 6, Issue 8 https://doi.org/10.1016/j.heliyon.2020.e04709	journal	August 2020
Nickel on alumina catalysts for the production of hydrogen rich mixtures via the biogas dry reforming reaction: Influence of the synthesis method Goula, Maria A.; Charisiou, Nikolaos D.; Papageridis, Kiriakos N. International Journal of Hydrogen Energy, Vol. 40, Issue 30 https://doi.org/10.1016/j.ijhydene.2015.05.129	journal	August 2015
NiAl2O4 as a beneficial precursor for Ni/Al2O3 catalysts for the dry reforming of methane Kwon, Yongtak; Eichler, J. Ehren; Mullins, C. Buddie Journal of CO2 Utilization, Vol. 63 https://doi.org/10.1016/j.jcou.2022.102112	journal	September 2022
N ₂ O Pulse Titration of Ni/α-Al ₂ O ₃ Catalysts: A New Technique Applicable to Nickel Surface-Area Determination of Nickel-Based Catalysts Tada, Shohei; Yokoyama, Misato; Kikuchi, Ryuji The Journal of Physical Chemistry C, Vol. 117, Issue 28 https://doi.org/10.1021/JP404291K	journal	July 2013
The Global Plastic Toxicity Debt Rillig, Matthias C.; Kim, Shin Woong; Kim, Tae-Young Environmental Science & Technology, Vol. 55, Issue 5 https://doi.org/10.1021/acs.est.0c07781	journal	February 2021
Catalyzing the Hydrocracking of Low Density Polyethylene Bin Jumah, Abdulrahman; Anbumuthu, Vanithasri; Tedstone, Aleksander A. Industrial & Engineering Chemistry Research, Vol. 58, Issue 45 https://doi.org/10.1021/acs.iecr.9b04263	journal	October 2019
Direct Observation of Ni–Mo Bimetallic Catalyst Formation via Thermal Reduction of Nickel Molybdate Nanorods Patil, Rituja B.; House, Stephen D.; Mantri, Aayush ACS Catalysis, Vol. 10, Issue 18 https://doi.org/10.1021/acscatal.0c02264	journal	August 2020
Disordered, Sub-Nanometer Ru Structures on CeO₂ are Highly Efficient and Selective Catalysts in Polymer Upcycling by Hydrogenolysis Chen, Linxiao; Meyer, Laura C.; Kovarik, Libor ACS Catalysis, Vol. 12, Issue 8 https://doi.org/10.1021/acscatal.2c00684	journal	April 2022
Differences in the Nature of Active Sites for Methane Dry Reforming and Methane Steam Reforming over Nickel Aluminate Catalysts Rogers, Jessica L.; Mangarella, Michael C.; D’Amico, Andrew D. ACS Catalysis, Vol. 6, Issue 9 https://doi.org/10.1021/acscatal.6b01133	journal	August 2016
Structure Sensitivity in Steam and Dry Methane Reforming over Nickel: Activity and Carbon Formation Vogt, Charlotte; Kranenborg, Jelle; Monai, Matteo ACS Catalysis, Vol. 10, Issue 2 https://doi.org/10.1021/acscatal.9b04193	journal	December 2019
Tandem Heterogeneous Catalysis for Polyethylene Depolymerization via an Olefin-Intermediate Process Ellis, Lucas D.; Orski, Sara V.; Kenlaw, Grace A. ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 2 https://doi.org/10.1021/acssuschemeng.0c07612	journal	January 2021
Managing Plastic Waste─Sorting, Recycling, Disposal, and Product Redesign Lange, Jean-Paul ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 47 https://doi.org/10.1021/acssuschemeng.1c05013	journal	November 2021
Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis Tao, Franklin (Feng); Crozier, Peter A. Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/cr5002657	journal	March 2016
Behavior of Coprecipitated NiAl₂O₄/Al₂O₃ Catalysts for Low-Temperature Methane Steam Reforming Jiménez-González, Cristina; Boukha, Zouhair; de Rivas, Beatriz Energy & Fuels, Vol. 28, Issue 11 https://doi.org/10.1021/ef501612y	journal	October 2014
Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia Wang, Cong; Xie, Tianjun; Kots, Pavel A. JACS Au, Vol. 1, Issue 9 https://doi.org/10.1021/jacsau.1c00200	journal	August 2021
Hydrogenolysis of Polyethylene and Polypropylene into Propane over Cobalt-Based Catalysts Zichittella, Guido; Ebrahim, Amani M.; Zhu, Jie JACS Au, Vol. 2, Issue 10 https://doi.org/10.1021/jacsau.2c00402	journal	October 2022
Inverse NiAl ₂ O ₄ on LaAlO ₃ –Al ₂ O ₃ : Unique Catalytic Structure for Stable CO ₂ Reforming of Methane Kathiraser, Yasotha; Thitsartarn, Warintorn; Sutthiumporn, Kesada The Journal of Physical Chemistry C, Vol. 117, Issue 16 https://doi.org/10.1021/jp401855x	journal	April 2013
IR spectroscopic detection of Lewis acid sites on alumina using adsorbed carbon monoxide. Correlation with aluminum-hydroxyl group removal Ballinger, Todd H.; Yates, John T. Langmuir, Vol. 7, Issue 12 https://doi.org/10.1021/la00060a022	journal	December 1991
Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts Kots, Pavel A.; Xie, Tianjun; Vance, Brandon C. Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-32934-5	journal	September 2022
Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst Mason, Alexander H.; Motta, Alessandro; Das, Anusheela Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-34707-6	journal	November 2022
Towards a better understanding of Lewis acidic aluminium in zeolites Ravi, Manoj; Sushkevich, Vitaly L.; van Bokhoven, Jeroen A. Nature Materials, Vol. 19, Issue 10 https://doi.org/10.1038/s41563-020-0751-3	journal	September 2020
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity van Deelen, Tom W.; Hernández Mejía, Carlos; de Jong, Krijn P. Nature Catalysis, Vol. 2, Issue 11 https://doi.org/10.1038/s41929-019-0364-x	journal	November 2019
Zeolite shape selectivity impact on LDPE and PP catalytic pyrolysis products and coke nature Hasan, Md M.; Batalha, Nuno; Fraga, Gabriel Sustainable Energy & Fuels, Vol. 6, Issue 6 https://doi.org/10.1039/D2SE00146B	journal	January 2022
Surface configurations and infra-red studies on nickel oxide supported on η- and γ-Al₂O₃ Borello, E.; Cimino, A.; Ghiotti, G. Discuss. Faraday Soc., Vol. 52, Issue 0 https://doi.org/10.1039/DF9715200149	journal	January 1971
Influence of preparation method on the characteristics of nickel/sepiolite catalysts Anderson, James A.; Daza, Loreto; Fierro, Jose Luis G. Journal of the Chemical Society, Faraday Transactions, Vol. 89, Issue 19 https://doi.org/10.1039/FT9938903651	journal	January 1993
A novel method for synthesis of a Ni/Al2O3 catalyst with a mesoporous structure using stearic acid salts Kim, Younghun; Kim, Pil; Kim, Changmook Journal of Materials Chemistry, Vol. 13, Issue 9 https://doi.org/10.1039/b303049k	journal	January 2003
Effect of reaction conditions on the hydrogenolysis of polypropylene and polyethylene into gas and liquid alkanes Chen, Linxiao; Zhu, Yifeng; Meyer, Laura C. Reaction Chemistry & Engineering, Vol. 7, Issue 4 https://doi.org/10.1039/d1re00431j	journal	January 2022
Polyolefin plastic waste hydroconversion to fuels, lubricants, and waxes: a comparative study Kots, Pavel A.; Vance, Brandon C.; Vlachos, Dionisios G. Reaction Chemistry & Engineering, Vol. 7, Issue 1 https://doi.org/10.1039/d1re00447f	journal	December 2021
Toxicity in vitro reveals potential impacts of microplastics and nanoplastics on human health: A review Shi, Qingying; Tang, Jingchun; Liu, Rutao Critical Reviews in Environmental Science and Technology, Vol. 52, Issue 21 https://doi.org/10.1080/10643389.2021.1951528	journal	July 2021
Gamma-Alumina (γ-Al ₂ O ₃ ) by XPS Rotole, John A.; Sherwood, Peter M. A. Surface Science Spectra, Vol. 5, Issue 1 https://doi.org/10.1116/1.1247852	journal	January 1998
Plastic waste to fuels by hydrocracking at mild conditions Liu, Sibao; Kots, Pavel A.; Vance, Brandon C. Science Advances, Vol. 7, Issue 17 https://doi.org/10.1126/SCIADV.ABF8283	journal	April 2021
Production, use, and fate of all plastics ever made Geyer, Roland; Jambeck, Jenna R.; Law, Kara Lavender Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700782	journal	July 2017

Similar Records

A general strategy and a consolidated mechanism for low-methane hydrogenolysis of polyethylene over ruthenium

Journal Article · Fri Aug 26 20:00:00 EDT 2022 · Applied Catalysis. B, Environmental · OSTI ID:2421776

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalyst restructuring
catalysts
circular economy
earth-abundant metals
hydrocarbons
nanoparticles
nickel
plastics waste
redox reactions
selectivity

Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity

Citation Formats

References (63)

Similar Records

Related Subjects