Design and Application of Materials for Sequestration and Immobilization of 99Tc

Singh, Bhupendra Kumar; Mahzan, Nurul Syiffa; Abdul Rashid, Nur Shahidah; Isa, Samiratu Atibun; Hafeez, Muhammad Aamir; Saslow, Sarah A.; Wang, Guohui; Mo, Changki; Um, Wooyong

doi:10.1021/acs.est.3c00129

Title: Design and Application of Materials for Sequestration and Immobilization of ⁹⁹Tc

Journal Article · Tue Apr 18 00:00:00 EDT 2023 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.3c00129· OSTI ID:1989308

^[1]; Mahzan, Nurul Syiffa ^[1]; Abdul Rashid, Nur Shahidah ^[1]; Isa, Samiratu Atibun ^[1];

^[1];

^[2];

^[2]; Mo, Changki ^[3];

^[1]

Pohang Univ. of Science and Technology (POSTECH) (Korea, Republic of)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Washington State University Tri-Cities, Richland, WA (United States)

⁹⁹Technetium (⁹⁹Tc) is a hazardous radionuclide generated by the nuclear industry that poses a serious environmental threat. The wide variation and complex chemistries of nuclear waste streams containing ⁹⁹Tc often create unique, site specific challenges when sequestering and immobilizing the waste in a matrix suitable for long-term storage and disposal. Therefore, an effective management plan for ⁹⁹Tc containing radioactive waste will likely require a variety of suitable materials/matrices capable of adapting to and addressing these challenges. In this review, we discuss and highlight the key developments for effective removal and immobilization of ⁹⁹Tc in inorganic waste forms. Specifically, we review the synthesis, characterization, and application of materials for targeted removal of ⁹⁹Tc from (simulated) waste solutions under various experimental conditions. These materials include: i) layered double hydroxides (LDHs), ii) metal-organic frameworks (MOFs), iii) ion-exchange resins (IERs) as well as cationic organic polymers (COPs), and iv) surface modified natural clay materials (SMCMs). Secondly, we discuss some of the major and recent developments towards ⁹⁹Tc immobilization in i) glass, ii) cement, and iii) iron mineral waste forms. Finally, we present future challenges that need to be addressed for the design, synthesis, and selection of suitable matrices for the efficient sequestration and immobilization of ⁹⁹Tc from targeted wastes. Finally, the purpose of this review is to inspire the researches on the design and application of various suitable materials/matrices for selective removal of ⁹⁹Tc present globally in different radioactive wastes and its immobilization in stable/durable waste forms.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE; Korea Spent Nuclear Fuel (iKSNF); National Research Foundation, Korea (NRF); Ministry of Science and ICT, MSIT, Korea

Grant/Contract Number:: AC05-76RL01830; 2021M2E1A1085202

OSTI ID:: 1989308

Report Number(s):: PNNL-SA-175772

Journal Information:: Environmental Science and Technology, Vol. 57, Issue 17; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (134)

Adsorption and immobilization of radioactive ionic-corrosion-products using magnetic hydroxyapatite and cold-sintering for nuclear waste management applications Venkatesan, Suriya; Hassan, Muhmood ul; Ryu, Ho Jin Journal of Nuclear Materials, Vol. 514 https://doi.org/10.1016/j.jnucmat.2018.11.026	journal	February 2019
Chemistry of Technetium and Rhenium Species during Low-Level Radioactive Waste Vitrification Darab, John G.; Smith, Peter A. Chemistry of Materials, Vol. 8, Issue 5 https://doi.org/10.1021/cm950418+	journal	January 1996
Technetium Speciation in Cement Waste Forms Determined by X-ray Absorption Fine Structure Spectroscopy Allen, P. G.; Siemering, G. S.; Shuh, D. K. Radiochimica Acta, Vol. 76, Issue 1-2 https://doi.org/10.1524/ract.1997.76.12.77	journal	January 1997
Reduction and long-term immobilization of technetium by Fe(II) associated with clay mineral nontronite Jaisi, Deb P.; Dong, Hailiang; Plymale, Andrew E. Chemical Geology, Vol. 264, Issue 1-4 https://doi.org/10.1016/j.chemgeo.2009.02.018	journal	June 2009
Signatures of technetium oxidation states: a new approach Bauters, Stephen; Scheinost, Andreas C.; Schmeide, Katja Chemical Communications, Vol. 56, Issue 67 https://doi.org/10.1039/D0CC03905E	journal	January 2020
99TcO4− removal from legacy defense nuclear waste by an alkaline-stable 2D cationic metal organic framework Shen, Nannan; Yang, Zaixing; Liu, Shengtang Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19374-9	journal	November 2020
Getters for improved technetium containment in cementitious waste forms Asmussen, R. Matthew; Pearce, Carolyn I.; Miller, Brian W. Journal of Hazardous Materials, Vol. 341 https://doi.org/10.1016/j.jhazmat.2017.07.055	journal	January 2018
Special Issue: Materials for Nuclear Waste Immobilization Materials, Vol. 12, Issue 21 https://doi.org/10.3390/ma12213611	journal	November 2019
Volatile species of technetium and rhenium during waste vitrification Kim, Dongsang; Kruger, Albert A. Journal of Non-Crystalline Solids, Vol. 481 https://doi.org/10.1016/j.jnoncrysol.2017.10.013	journal	February 2018
Technetium-99m Transport and Immobilisation in Porous Media: Development of a Novel Nuclear Imaging Technique Corkhill, Claire L.; Bridge, Jonathan W.; Hillel, Philip MRS Proceedings, Vol. 1518 https://doi.org/10.1557/opl.2013.111	journal	January 2013
Immobilization of radioactive waste by cementation with purified kaolin clay Osmanlioglu, A. Erdal Waste Management, Vol. 22, Issue 5 https://doi.org/10.1016/S0956-053X(02)00036-3	journal	August 2002
Pyridinium salt-based covalent organic framework with well-defined nanochannels for efficient and selective capture of aqueous 99TcO4− Hao, Mengjie; Chen, Zhongshan; Yang, Hui Science Bulletin, Vol. 67, Issue 9 https://doi.org/10.1016/j.scib.2022.02.012	journal	May 2022
The Release of Technetium from Defense Waste Processing Facility Glasses Ebert, W. L.; Wolf, S. F.; Bates, J. K. MRS Proceedings, Vol. 412 https://doi.org/10.1557/PROC-412-221	journal	January 1995
Products of Pertechnetate Radiolysis in Highly Alkaline Solution: Structure of TcO₂·xH₂O Lukens,, Wayne W.; Bucher, Jerome J.; Edelstein, Norman M. Environmental Science & Technology, Vol. 36, Issue 5 https://doi.org/10.1021/es015653+	journal	February 2002
Creation of a new type of ion exchange material for rapid, high-capacity, reversible and selective ion exchange without swelling and entrainment Li, Baiyan; Zhang, Yiming; Ma, Dingxuan Chemical Science, Vol. 7, Issue 3 https://doi.org/10.1039/C5SC04507J	journal	January 2016
Magnesium potassium phosphate ceramic for ⁹⁹Tc immobilization Singh, D.; Mandalika, V. R.; Parulekar, S. J. Journal of Nuclear Materials, Vol. 348, Issue 3, p. 272-282 https://doi.org/10.1016/j.jnucmat.2005.09.026	journal	February 2006
Technetium Stabilization in Low-Solubility Sulfide Phases: A Review Pearce, Carolyn I.; Icenhower, Jonathan P.; Asmussen, R. Matthew ACS Earth and Space Chemistry, Vol. 2, Issue 6 https://doi.org/10.1021/acsearthspacechem.8b00015	journal	April 2018
Near-field behavior of 99Tc during the oxidative alteration of spent nuclear fuel Chen, Fanrong; Burns, Peter C.; Ewing, Rodney C. Journal of Nuclear Materials, Vol. 278, Issue 2-3 https://doi.org/10.1016/S0022-3115(99)00264-0	journal	April 2000
Impeding 99Tc(IV) mobility in novel waste forms Lee, Mal-Soon; Um, Wooyong; Wang, Guohui Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12067	journal	June 2016
Redox chemistry, solubility and hydrolysis of Re in reducing aquatic systems. Thermodynamic description and comparison with Tc Duckworth, S.; Gaona, X.; Castaño, D. Applied Geochemistry, Vol. 132 https://doi.org/10.1016/j.apgeochem.2021.105037	journal	September 2021
Preparation and Properties of Hydroceramic Waste Forms Made with Simulated Hanford Low-Activity Waste Bao, Yun; Grutzeck, Michael W.; Jantzen, Carol M. Journal of the American Ceramic Society, Vol. 88, Issue 12 https://doi.org/10.1111/j.1551-2916.2005.00775.x	journal	December 2005
Technetium Incorporation into Goethite (α-FeOOH): An Atomic-Scale Investigation Smith, Frances N.; Taylor, Christopher D.; Um, Wooyong Environmental Science & Technology, Vol. 49, Issue 22 https://doi.org/10.1021/acs.est.5b03354	journal	October 2015
Evaluation of Se(IV) removal from aqueous solution by GMZ Na-bentonite: batch experiment and modeling studies Shi, Keliang; Ye, Yuanlv; Guo, Ning Journal of Radioanalytical and Nuclear Chemistry, Vol. 299, Issue 1 https://doi.org/10.1007/s10967-013-2807-1	journal	November 2013
Development of a Geochemical Speciation Model for Use in Evaluating Leaching from a Cementitious Radioactive Waste Form Chen, Zhiliang; Zhang, Peng; Brown, Kevin G. Environmental Science & Technology, Vol. 55, Issue 13 https://doi.org/10.1021/acs.est.0c06227	journal	June 2021
Separation and Remediation of ⁹⁹ TcO ₄ ^– from Aqueous Solutions Xiao, Chengliang; Khayambashi, Afshin; Wang, Shuao Chemistry of Materials, Vol. 31, Issue 11 https://doi.org/10.1021/acs.chemmater.9b00329	journal	May 2019
Gemini ionic liquid modified nacre-like reduced graphene oxide click membranes for ReO4−/TcO4− removal Wang, Kechao; Yan, Zhuoyi; Fu, Langlang Separation and Purification Technology, Vol. 302 https://doi.org/10.1016/j.seppur.2022.122073	journal	December 2022
Structural Behavior of Tc and I Ions in Nuclear Waste Glass Muller, Isabelle S.; McKeown, David A.; Pegg, Ian L. Procedia Materials Science, Vol. 7 https://doi.org/10.1016/j.mspro.2014.10.008	journal	January 2014
Immobilizing Pertechnetate in Ettringite via Sulfate Substitution Saslow, Sarah A.; Kerisit, Sebastien N.; Varga, Tamas Environmental Science & Technology, Vol. 54, Issue 21 https://doi.org/10.1021/acs.est.0c03119	journal	September 2020
Immobilization of cesium and iodine into Cs3Bi2I9 perovskite-silica composites and core-shell waste forms with high waste loadings and chemical durability Yang, Kun; Zhu, Weiguang; Scott, Spencer Journal of Hazardous Materials, Vol. 401 https://doi.org/10.1016/j.jhazmat.2020.123279	journal	January 2021
Activated carbon additives for technetium immobilization in bentonite-based engineered barriers for radioactive waste repositories Makarov, A. V.; Safonov, A. V.; Konevnik, Yu. V. Journal of Hazardous Materials, Vol. 401 https://doi.org/10.1016/j.jhazmat.2020.123436	journal	January 2021
Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water Banerjee, Debasis; Xu, Wenqian; Nie, Zimin Inorganic Chemistry, Vol. 55, Issue 17 https://doi.org/10.1021/acs.inorgchem.6b01004	journal	August 2016
Enhanced immobilization of ReO4− by nanoscale zerovalent iron supported on layered double hydroxide via an advanced XAFS approach: Implications for TcO4− sequestration Sheng, Guodong; Tang, Yanna; Linghu, Wensheng Applied Catalysis B: Environmental, Vol. 192 https://doi.org/10.1016/j.apcatb.2016.04.001	journal	September 2016
Organic modification of bentonite and its application for perrhenate (an analogue of pertechnetate) removal from aqueous solution Yaming, Li; Mingliang, Bi; Zhipeng, Wang Journal of the Taiwan Institute of Chemical Engineers, Vol. 62 https://doi.org/10.1016/j.jtice.2016.01.018	journal	May 2016
Evolution of Technetium Speciation in Reducing Grout Lukens, Wayne W.; Bucher, Jerome J.; Shuh, David K. Environmental Science & Technology, Vol. 39, Issue 20 https://doi.org/10.1021/es050155c	journal	October 2005
Synroc technology: Perspectives and current status (Review) Gregg, Daniel J.; Farzana, Rifat; Dayal, Pranesh Journal of the American Ceramic Society, Vol. 103, Issue 10 https://doi.org/10.1111/jace.17322	journal	July 2020
Highly Efficient Enrichment of Radionuclides on Graphene Oxide-Supported Polyaniline Sun, Yubing; Shao, Dadong; Chen, Changlun Environmental Science & Technology, Vol. 47, Issue 17 https://doi.org/10.1021/es401174n	journal	August 2013
Glass Property Models and Constraints for Estimating the Glass to be Produced at Hanford by Implementing Current Advanced Glass Formulation Efforts Vienna, John D.; Kim, Dong-Sang; Skorski, Daniel C. https://doi.org/10.2172/1170502	report	July 2013
Technetium immobilization by chukanovite and its oxidative transformation products: Neural network analysis of EXAFS spectra Schmeide, Katja; Rossberg, André; Bok, Frank Science of The Total Environment, Vol. 770 https://doi.org/10.1016/j.scitotenv.2021.145334	journal	May 2021
Competitive Adsorption of Pb ^II , Ni ^II , and Sr ^II Ions on Graphene Oxides: A Combined Experimental and Theoretical Study Yang, Shubin; Chen, Changlun; Chen, Yue ChemPlusChem, Vol. 80, Issue 3 https://doi.org/10.1002/cplu.201402284	journal	November 2014
Interaction Mechanism of Re(VII) with Zirconium Dioxide Nanoparticles Archored onto Reduced Graphene Oxides Gao, Yang; Chen, Ke; Tan, Xiaoli ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 3 https://doi.org/10.1021/acssuschemeng.6b02317	journal	February 2017
Retention of technetium-99 by grout and backfill cements: Implications for the safe disposal of radioactive waste Isaacs, Matthew; Lange, Steve; Deissmann, Guido Applied Geochemistry, Vol. 116 https://doi.org/10.1016/j.apgeochem.2020.104580	journal	May 2020
A Focused Ion Beam-Scanning Transmission Electron Microscopy with Energy-Dispersive X-ray Spectroscopy Study on Technetium Incorporation within Iron Oxides through Fe(OH) ₂ (s) Mineral Transformation Wang, Guohui; Olszta, Matthew J.; Saslow, Sarah A. ACS Earth and Space Chemistry, Vol. 5, Issue 3 https://doi.org/10.1021/acsearthspacechem.0c00305	journal	March 2021
Immobilization of Technetium and Nitrate in Cement-Based Materials Tallent, O. K.; McDaniel, E. W.; Cul, G. D. Del MRS Proceedings, Vol. 112 https://doi.org/10.1557/PROC-112-23	journal	January 1987
Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications Lin, Zu-Jin; Lü, Jian; Hong, Maochun Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C3CS60483G	journal	January 2014
Development of Bifunctional Anion-Exchange Resins with Improved Selectivity and Sorptive Kinetics for Pertechnetate: Batch-Equilibrium Experiments Bonnesen, Peter V.; Brown, Gilbert M.; Alexandratos, Spiro D. Environmental Science & Technology, Vol. 34, Issue 17 https://doi.org/10.1021/es990858s	journal	September 2000
Compositional and structural control on anion sorption capability of layered double hydroxides (LDHs) Wang, Yifeng; Gao, Huizhen Journal of Colloid and Interface Science, Vol. 301, Issue 1 https://doi.org/10.1016/j.jcis.2006.04.061	journal	September 2006
A review on the development and application of graphene based materials for the fabrication of modified asphalt and cement Han, Meizhao; Muhammad, Yaseen; Wei, Yunhao Construction and Building Materials, Vol. 285 https://doi.org/10.1016/j.conbuildmat.2021.122885	journal	May 2021
Environmental geochemistry of technetium Meena, Amanda H.; Arai, Yuji Environmental Chemistry Letters, Vol. 15, Issue 2 https://doi.org/10.1007/s10311-017-0605-7	journal	February 2017
Sorption coefficients and molecular mechanisms of Pu, U, Np, Am and Tc to Fe (hydr)oxides: A review Li, Dien; Kaplan, Daniel I. Journal of Hazardous Materials, Vol. 243 https://doi.org/10.1016/j.jhazmat.2012.09.011	journal	December 2012
Bentonite colloids immobilization and release in quartz column and its influence on selenite migration Li, Yao; Guo, Ning; Xian, Dongfan Science of The Total Environment, Vol. 820 https://doi.org/10.1016/j.scitotenv.2021.152833	journal	May 2022
Improving Re(VII) Adsorption on Diisobutylamine-Functionalized Graphene Oxide Xiong, Ying; Cui, Xurui; Zhang, Peng ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1 https://doi.org/10.1021/acssuschemeng.6b02322	journal	December 2016
Removal of TcO ₄ ⁻ ions from solution: materials and future outlook Banerjee, Debasis; Kim, Dongsang; Schweiger, Michael J. Chemical Society Reviews, Vol. 45, Issue 10 https://doi.org/10.1039/C5CS00330J	journal	January 2016
Application of layered double hydroxides for 99Tc remediation Daniels, N.; Franzen, C.; Murphy, G. L. Applied Clay Science, Vol. 176 https://doi.org/10.1016/j.clay.2019.04.006	journal	August 2019
Electrochemical Exfoliation of Graphite into Nitrogen-doped Graphene in Glycine Solution and its Energy Storage Properties Yang, Yingchang; Shi, Wei; Zhang, Renhui Electrochimica Acta, Vol. 204 https://doi.org/10.1016/j.electacta.2016.04.063	journal	June 2016
Synthesis of rhenium-doped tin dioxide for technetium radioactive waste immobilization Khan, Mumtaz; Um, Wooyong; Kim, Won-Seok Journal of Nuclear Materials, Vol. 505 https://doi.org/10.1016/j.jnucmat.2018.04.014	journal	July 2018
The evolution of hydrated lime-based cementitious waste forms during leach testing leading to enhanced technetium retention Bourchy, Agathe; Saslow, Sarah A.; Williams, Benjamin D. Journal of Hazardous Materials, Vol. 430 https://doi.org/10.1016/j.jhazmat.2022.128507	journal	May 2022
Porous metal–organic framework-based filters: Synthesis methods and applications for environmental remediation Xiao, Huan; Low, Ze-Xian; Gore, Damian B. Chemical Engineering Journal, Vol. 430 https://doi.org/10.1016/j.cej.2021.133160	journal	February 2022
Analysis of technetium immobilization and its molecular retention mechanisms by Fe(II)-Al(III)-Cl layered double hydroxide Mayordomo, Natalia; Rodríguez, Diana M.; Rossberg, André Chemical Engineering Journal, Vol. 408 https://doi.org/10.1016/j.cej.2020.127265	journal	March 2021
Study on coordination structure of Re adsorbed on Mg–Al layered double hydroxide using X-ray absorption fine structure Tanaka, Kazuya; Kozai, Naofumi; Ohnuki, Toshihiko Journal of Porous Materials, Vol. 26, Issue 2 https://doi.org/10.1007/s10934-018-0634-z	journal	June 2018
Cr(VI) Effect on Tc-99 Removal from Hanford Low-Activity Waste Simulant by Ferrous Hydroxide Saslow, Sarah A.; Um, Wooyong; Pearce, Carolyn I. Environmental Science & Technology https://doi.org/10.1021/acs.est.8b03314	journal	October 2018
Radionuclide transport in multi-scale fractured rocks: A review Zhang, Xiaoying; Ma, Funing; Dai, Zhenxue Journal of Hazardous Materials, Vol. 424 https://doi.org/10.1016/j.jhazmat.2021.127550	journal	February 2022
Advanced Vitreous Wasteforms for Radioactive Salt Cake Waste Immobilisation Kashcheev, Vladimir A.; Musatov, Nikolay D.; Ojovan, Michael I. MRS Advances, Vol. 5, Issue 3-4 https://doi.org/10.1557/adv.2020.45	journal	January 2020
Layered double hydroxide as multifunctional materials for environmental remediation: from chemical pollutants to microorganisms Sharma, Rohit; Arizaga, Gregorio Guadalupe Carbajal; Saini, Adesh K. Sustainable Materials and Technologies, Vol. 29 https://doi.org/10.1016/j.susmat.2021.e00319	journal	September 2021
Heteroatom-doped graphene-based materials for sustainable energy applications: A review Lee, Seung Jun; Theerthagiri, Jayaraman; Nithyadharseni, Palaniyandy Renewable and Sustainable Energy Reviews, Vol. 143 https://doi.org/10.1016/j.rser.2021.110849	journal	June 2021
Exceptional TcO ₄ ⁻ sorption capacity and highly efficient ReO ₄ ⁻ luminescence sensing by Zr ⁴⁺ MOFs Rapti, Sofia; Diamantis, Stavros A.; Dafnomili, Argyro Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/C8TA07901C	journal	January 2018
Technetium immobilization by materials through sorption and redox-driven processes: A literature review Pearce, Carolyn I.; Moore, Robert C.; Morad, Joseph W. Science of The Total Environment https://doi.org/10.1016/j.scitotenv.2019.06.195	journal	June 2019
Incorporation and Retention of 99-Tc(IV) in Magnetite under High pH Conditions Marshall, Timothy A.; Morris, Katherine; Law, Gareth T. W. Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es503438e	journal	October 2014
Organophilic bentonites as adsorbents for radionuclides II. Chemical and mineralogical properties of HDPy-montmorillonite Dultz, S. Applied Clay Science, Vol. 16, Issue 1-2 https://doi.org/10.1016/S0169-1317(99)00042-3	journal	January 2000
BASIC PHYSICAL AND CHEMICAL PROPERTIES OF REILLEX^TM-HPQ ANION EXCHANGE RESIN AND ITS SORPTION BEHAVIOR OF HALIDES IN AQUEOUS NITRIC ACID SOLUTION Wu, Yen-Yuan J.; Williamson, Michelle A.; Zhang, Qihui Solvent Extraction and Ion Exchange, Vol. 14, Issue 2 https://doi.org/10.1080/07366299608918340	journal	March 1996
Effects of iron oxalate on rhenium incorporation into low-activity waste glass George, Jaime L.; Kim, Dongsang; Kruger, Albert A. Journal of Non-Crystalline Solids, Vol. 545 https://doi.org/10.1016/j.jnoncrysol.2020.120257	journal	October 2020
Selective Removal of Technetium from Water Using Graphene Oxide Membranes Williams, Christopher D.; Carbone, Paola Environmental Science & Technology, Vol. 50, Issue 7 https://doi.org/10.1021/acs.est.5b06032	journal	March 2016
A review on heavy metal ions adsorption from water by layered double hydroxide and its composites Feng, Xiaofang; Long, Runxuan; Wang, Lingling Separation and Purification Technology, Vol. 284 https://doi.org/10.1016/j.seppur.2021.120099	journal	February 2022
Metal–organic frameworks (MOFs) based nanofiber architectures for the removal of heavy metal ions Adil, Heja Ibrahim; Thalji, Mohammad R.; Yasin, Suhad A. RSC Advances, Vol. 12, Issue 3 https://doi.org/10.1039/D1RA07034G	journal	January 2022
Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions Milićević, Sonja; Matović, Ljiljana; Petrović, Đorđe Journal of Radioanalytical and Nuclear Chemistry, Vol. 310, Issue 2 https://doi.org/10.1007/s10967-016-4850-1	journal	April 2016
Recent advances in graphene‐based materials for fuel cell applications Su, Hanrui; Hu, Yun Hang Energy Science & Engineering https://doi.org/10.1002/ese3.833	journal	October 2020
Inorganic Waste Forms for Efficient Immobilization of Radionuclides Singh, Bhupendra Kumar; Hafeez, Muhammad Aamir; Kim, Hyojoo ACS ES&T Engineering, Vol. 1, Issue 8 https://doi.org/10.1021/acsestengg.1c00184	journal	June 2021
Enhanced 99Tc retention in glass waste form using Tc(IV)-incorporated Fe minerals Um, Wooyong; Luksic, Steven A.; Wang, Guohui Journal of Nuclear Materials, Vol. 495 https://doi.org/10.1016/j.jnucmat.2017.09.007	journal	November 2017
Rhenium as analog for fissiogenic technetium: Eh-pH diagram (25°C, 1 bar) constraints Brookins, Douglas G. Applied Geochemistry, Vol. 1, Issue 4 https://doi.org/10.1016/0883-2927(86)90056-9	journal	July 1986
Breakthrough volumes of TcO 4 − on Reillex™-HPQ anion exchange resin in a Hanford Double Shell Tank simulant Ashley, K. R.; Ball, J. R.; Abney, K. D. Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 194, Issue 1 https://doi.org/10.1007/BF02037614	journal	July 1995
Efficient uptake of perrhenate/pertechnenate from aqueous solutions by the bifunctional anion-exchange resin Li, Jie; Zhu, Lin; Xiao, Chengliang Radiochimica Acta, Vol. 106, Issue 7 https://doi.org/10.1515/ract-2017-2829	journal	July 2018
Immobilization of low and intermediate level of organic radioactive wastes in cement matrices Eskander, S. B.; Abdel Aziz, S. M.; El-Didamony, H. Journal of Hazardous Materials, Vol. 190, Issue 1-3 https://doi.org/10.1016/j.jhazmat.2011.04.036	journal	June 2011
REILLEX ^™ -HPQ ANION EXCHANGE COLUMN CHROMATOGRAPHY: REMOVAL OF PERTECHNETATE FROM DSSF-5 SIMULANT AT VARIOUS FLOW RATES Ashley, Kenneth R.; Whitener, Glenn D.; Schroeder, Norman C. Solvent Extraction and Ion Exchange, Vol. 17, Issue 6 https://doi.org/10.1080/07366299908934664	journal	November 1999
Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and Limited Reoxidation Um, Wooyong; Chang, Hyun-Shik; Icenhower, Jonathan P. Environmental Science & Technology, Vol. 45, Issue 11 https://doi.org/10.1021/es104343p	journal	June 2011
Rhenium(VII) and technetium(VII) separation from aqueous solutions using a polyethylenimine–epichlorohydrin resin Sarri, S.; Misaelides, P.; Zamboulis, D. Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 1 https://doi.org/10.1007/s10967-015-4213-3	journal	May 2015
Efficient sequestration of radioactive 99TcO4- by a rare 3-fold interlocking cationic metal-organic framework: A combined batch experiments, pair distribution function, and crystallographic investigation Kang, Kang; Shen, Nannan; Wang, Yanlong Chemical Engineering Journal, Vol. 427 https://doi.org/10.1016/j.cej.2021.130942	journal	January 2022
Aqueous ultracapacitors using amorphous MnO2 and reduced graphene oxide Mery, Adrien; Ghamouss, Fouad; Autret, Cécile Journal of Power Sources, Vol. 305 https://doi.org/10.1016/j.jpowsour.2015.11.046	journal	February 2016
Synergistic effect of Sr 2+ and ReO 4 − adsorption on hexadecyl pyridinium-modified montmorillonite Luo, Wuhui; Inoue, Akihiro; Hirajima, Tsuyoshi Applied Surface Science, Vol. 394 https://doi.org/10.1016/j.apsusc.2016.10.135	journal	February 2017
99TcO4− remediation by a cationic polymeric network Li, Jie; Dai, Xing; Zhu, Lin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05380-5	journal	August 2018
Aluminum-based metal-organic frameworks (CAU-1) highly efficient UO22+ and TcO4− ions immobilization from aqueous solution Zhong, Xin; Liang, Wen; Wang, Huifang Journal of Hazardous Materials, Vol. 407 https://doi.org/10.1016/j.jhazmat.2020.124729	journal	April 2021
Phosphate modified calcium aluminate cement for radioactive waste encapsulation Swift, P.; Kinoshita, H.; Collier, N. C. Advances in Applied Ceramics, Vol. 112, Issue 1 https://doi.org/10.1179/1743676112Y.0000000033	journal	January 2013
Removal of 99Tc from low level radioactive liquid waste using di-tert-butyldibenzo-18-crown-6 impregnated sorbent Thakur, D. A.; Sonar, N. L.; Sharma, J. N. Journal of Radioanalytical and Nuclear Chemistry, Vol. 328, Issue 1 https://doi.org/10.1007/s10967-020-07553-3	journal	February 2021
Metal-organic frameworks with different dimensionalities: An ideal host platform for enzyme@MOF composites Du, Yingjie; Jia, Xiaotong; Zhong, Le Coordination Chemistry Reviews, Vol. 454 https://doi.org/10.1016/j.ccr.2021.214327	journal	March 2022
Microstructure and Leaching Characteristics of a Technetium Containing Metal Waste Form Johnson, S. G.; Keiser, D. D.; Noy, M. MRS Proceedings, Vol. 556 https://doi.org/10.1557/PROC-556-953	journal	January 1999
Immobilization of Hanford LAW in iron phosphate glasses Kim, Cheol-Woon; Day, Delbert E. Journal of Non-Crystalline Solids, Vol. 331, Issue 1-3 https://doi.org/10.1016/j.jnoncrysol.2003.08.070	journal	December 2003
Metallic technetium sequestration in nickel core/shell microstructure during Fe(OH)2 transformation with Ni doping Wang, Guohui; Kim, Dong-Sang; Olszta, Matthew J. Journal of Hazardous Materials, Vol. 425 https://doi.org/10.1016/j.jhazmat.2021.127779	journal	March 2022
Few-Layered Graphene Oxide Nanosheets As Superior Sorbents for Heavy Metal Ion Pollution Management Zhao, Guixia; Li, Jiaxing; Ren, Xuemei Environmental Science & Technology, Vol. 45, Issue 24 https://doi.org/10.1021/es203439v	journal	December 2011
Chemically Bonded Phosphate Ceramics: I, A Dissolution Model of Formation Wagh, Arun S.; Jeong, Seung Y. Journal of the American Ceramic Society, Vol. 86, Issue 11 https://doi.org/10.1111/j.1151-2916.2003.tb03569.x	journal	November 2003
Effective decontamination of 99TcO4−/ReO4− from Hanford low-activity waste by functionalized graphene oxide–chitosan sponges Zhang, Hao; Yang, Fan; Lu, Chuan Environmental Chemistry Letters, Vol. 18, Issue 4 https://doi.org/10.1007/s10311-020-01005-w	journal	April 2020
Sorption of technetium on inorganic sorbents and natural minerals El-Wear, S.; German, K. E.; Peretrukhin, V. F. Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 157, Issue 1 https://doi.org/10.1007/BF02039772	journal	February 1992
Synthesis of imidazolium-based cationic organic polymer for highly efficient and selective removal of ReO4−/TcO4− Hu, Qing-Hua; Jiang, Wei; Liang, Ru-Ping Chemical Engineering Journal, Vol. 419 https://doi.org/10.1016/j.cej.2021.129546	journal	September 2021
Review: Waste-Pretreatment Technologies for Remediation of Legacy Defense Nuclear Wastes Wilmarth, William R.; Lumetta, Gregg J.; Johnson, Michael E. Solvent Extraction and Ion Exchange, Vol. 29, Issue 1 https://doi.org/10.1080/07366299.2011.539134	journal	January 2011
Removal of 99Tc(VII) by organo-modified bentonite Milutinović-Nikolić, A.; Maksin, D.; Jović-Jovičić, N. Applied Clay Science, Vol. 95 https://doi.org/10.1016/j.clay.2014.04.027	journal	June 2014
Effect of humic acid on the diffusion of ReO4 − in GMZ bentonite Wang, Hai; Wu, Tao; Chen, Jiang Journal of Radioanalytical and Nuclear Chemistry, Vol. 303, Issue 1 https://doi.org/10.1007/s10967-014-3403-8	journal	August 2014
Magnesium alloys and graphite wastes encapsulated in cementitious materials: Reduction of galvanic corrosion using alkali hydroxide activated blast furnace slag Chartier, D.; Muzeau, B.; Stefan, L. Journal of Hazardous Materials, Vol. 326 https://doi.org/10.1016/j.jhazmat.2016.12.022	journal	March 2017
Highly efficient and selective capture of TcO4− or ReO4− by imidazolium-based ionic liquid polymers Huang, Mengnan; Kan, Lixin; Zhao, Wenyan Chemical Engineering Journal, Vol. 421 https://doi.org/10.1016/j.cej.2020.127763	journal	October 2021
Redox-dependent solubility of technetium in low activity waste glass Soderquist, Chuck Z.; Schweiger, Michael J.; Kim, Dong-Sang Journal of Nuclear Materials, Vol. 449, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2014.03.008	journal	June 2014
Efficient capture of ReO4− on magnetic amine-functionalized MIL-101(Cr): Revealing from selectivity to mechanism Cai, Yawen; Feng, Jinghua; Tan, Xiaoli Science of The Total Environment, Vol. 771 https://doi.org/10.1016/j.scitotenv.2020.144840	journal	June 2021
Hexadecylpyridinium (HDPy) modified bentonite for efficient and selective removal of 99Tc from wastewater Yang, Junqiang; Shi, Keliang; Gao, Xiaoqing Chemical Engineering Journal, Vol. 382 https://doi.org/10.1016/j.cej.2019.122894	journal	February 2020
Aqueous 99Tc, 129I and 137Cs removal from contaminated groundwater and sediments using highly effective low-cost sorbents Li, Dien; Kaplan, Daniel I.; Knox, Anna S. Journal of Environmental Radioactivity, Vol. 136 https://doi.org/10.1016/j.jenvrad.2014.05.010	journal	October 2014
Porous Organic Materials: Strategic Design and Structure–Function Correlation Das, Saikat; Heasman, Patrick; Ben, Teng Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00439	journal	December 2016
Application of natural zeolites in environmental remediation: A short review Misaelides, Panagiotis Microporous and Mesoporous Materials, Vol. 144, Issue 1-3 https://doi.org/10.1016/j.micromeso.2011.03.024	journal	October 2011
Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective zur Loye, Hans-Conrad; Besmann, Theodore; Amoroso, Jake Chemistry of Materials, Vol. 30, Issue 14 https://doi.org/10.1021/acs.chemmater.8b00766	journal	June 2018
Investigation of the sorption behavior of Cd(II) on GMZ bentonite as affected by solution chemistry Zhao, Donglin; Chen, Shaohua; Yang, Shubin Chemical Engineering Journal, Vol. 166, Issue 3 https://doi.org/10.1016/j.cej.2010.11.092	journal	February 2011
Selective removal of uranium from an aqueous solution of mixed radionuclides of uranium, cesium, and strontium via a viable recyclable GO@chitosan based magnetic nanocomposite Sharma, Manish; Laddha, Harshita; Yadav, Priya Materials Today Communications, Vol. 32 https://doi.org/10.1016/j.mtcomm.2022.104020	journal	August 2022
Systematic XAS study on the reduction and uptake of Tc by magnetite and mackinawite Yalçıntaş, Ezgi; Scheinost, Andreas C.; Gaona, Xavier Dalton Transactions, Vol. 45, Issue 44 https://doi.org/10.1039/C6DT02872A	journal	January 2016
High Surface Area “3D Graphene Oxide” for Enhanced Sorption of Radionuclides Boulanger, Nicolas; Kuzenkova, Anastasiia S.; Iakunkov, Artem Advanced Materials Interfaces, Vol. 9, Issue 18 https://doi.org/10.1002/admi.202200510	journal	May 2022
Incorporation of Technetium into Spinel Ferrites Lukens, Wayne W.; Magnani, Nicola; Tyliszczak, Tolek Environmental Science & Technology, Vol. 50, Issue 23 https://doi.org/10.1021/acs.est.6b04209	journal	November 2016
The impact of iron nanoparticles on technetium-contaminated groundwater and sediment microbial communities Newsome, Laura; Morris, Katherine; Cleary, Adrian Journal of Hazardous Materials, Vol. 364 https://doi.org/10.1016/j.jhazmat.2018.10.008	journal	February 2019
Glassy Wasteforms for Nuclear Waste Immobilization Ojovan, Michael I.; Lee, William E. Metallurgical and Materials Transactions A, Vol. 42, Issue 4 https://doi.org/10.1007/s11661-010-0525-7	journal	November 2010
Iron oxide waste form for stabilizing 99Tc Um, Wooyong; Chang, Hyunshik; Icenhower, Jonathan P. Journal of Nuclear Materials, Vol. 429, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2012.06.004	journal	October 2012
Reductive immobilization of Re(VII) by graphene modified nanoscale zero-valent iron particles using a plasma technique Li, Jie; Chen, Changlun; Zhang, Rui Science China Chemistry, Vol. 59, Issue 1 https://doi.org/10.1007/s11426-015-5452-4	journal	November 2015
Node-Accessible Zirconium MOFs Lu, Zhiyong; Liu, Jian; Zhang, Xuan Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c09782	journal	December 2020
Structuring of metal–organic frameworks at the mesoscopic/macroscopic scale Furukawa, Shuhei; Reboul, Julien; Diring, Stéphane Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00106K	journal	January 2014
Development of Novel Bifunctional Anion-Exchange Resins with Improved Selectivity for Pertechnetate Sorption from Contaminated Groundwater Gu, Baohua; Brown, Gilbert M.; Bonnesen, Peter V. Environmental Science & Technology, Vol. 34, Issue 6 https://doi.org/10.1021/es990951g	journal	March 2000
Incorporating technetium in minerals and other solids: A review Luksic, Steven A.; Riley, Brian J.; Schweiger, Michael Journal of Nuclear Materials, Vol. 466 https://doi.org/10.1016/j.jnucmat.2015.08.052	journal	November 2015
Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal–Organic Framework and Examination of Anion Binding Motifs Drout, Riki J.; Otake, Kenichi; Howarth, Ashlee J. Chemistry of Materials, Vol. 30, Issue 4 https://doi.org/10.1021/acs.chemmater.7b04619	journal	January 2018
Three-Dimensional Co(II)-Metal–Organic Frameworks with Varying Porosities and Open Metal Sites toward Multipurpose Heterogeneous Catalysis under Mild Conditions Chand, Santanu; Pal, Shyam Chand; Mondal, Manas Crystal Growth & Design, Vol. 19, Issue 9 https://doi.org/10.1021/acs.cgd.9b00823	journal	August 2019
Sorption of pertechnetate anion by cation modified bentonites Buzetzky, D.; Kovács, E. M.; Nagy, M. N. Journal of Radioanalytical and Nuclear Chemistry, Vol. 322, Issue 3 https://doi.org/10.1007/s10967-019-06852-8	journal	October 2019
Alkali-activated slag cement based radioactive waste forms Xuequan, Wu; Sheng, Yen; Xiaodong, Shen Cement and Concrete Research, Vol. 21, Issue 1 https://doi.org/10.1016/0008-8846(91)90026-E	journal	January 1991
Ceramic Mineral Waste-Forms for Nuclear Waste Immobilization Orlova, Albina I.; Ojovan, Michael I. Materials, Vol. 12, Issue 16 https://doi.org/10.3390/ma12162638	journal	August 2019
SORPTION BEHAVIOR OF PERTECHNETATE ION ON REILLEX ^TM -HPQ ANION EXCHANGE RESIN FROM HANFORD AND MELTON VALLEY TANK WASTE SIMULANTS AND SODIUM HYDROXIDE/SODIUM NITRATE SOLUTIONS Ashley, Kenneth R.; Whitener, Glenn D.; Schroeder, Norman C. Solvent Extraction and Ion Exchange, Vol. 16, Issue 3 https://doi.org/10.1080/07366299808934556	journal	May 1998
The nature of the volatile technetium species formed during vitrification of borosilicate glass Childs, Bradley C.; Poineau, Frederic; Czerwinski, Kenneth R. Journal of Radioanalytical and Nuclear Chemistry, Vol. 306, Issue 2 https://doi.org/10.1007/s10967-015-4203-5	journal	May 2015
Solubility control of technetium release from Saltstone by TcO2·xH2O Cantrell, Kirk J.; Williams, Benjamin D. Journal of Nuclear Materials, Vol. 437, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2013.02.049	journal	June 2013
Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption Sun, Qi; Zhu, Lin; Aguila, Briana Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09630-y	journal	April 2019

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Title: Design and Application of Materials for Sequestration and Immobilization of 99Tc

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Title: Design and Application of Materials for Sequestration and Immobilization of ⁹⁹Tc