Thermodynamics and Kinetics of Refractory Multi-principal Element Alloys: An Experimental and Modeling Comparison

Puerling, R.; Miklas, A.; Coury, F. G.; Philips, N. R.; Mason, P.; Peterson, N. E.; Deal, A.; Klemm-Toole, J.; Clarke, A. J.

doi:10.1007/s11661-023-06980-7

Thermodynamics and Kinetics of Refractory Multi-principal Element Alloys: An Experimental and Modeling Comparison

Journal Article · Mon Feb 20 23:00:00 EST 2023 · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science

DOI:https://doi.org/10.1007/s11661-023-06980-7· OSTI ID:1989196

Puerling, R. ^[1]; Miklas, A. ^[1]; Coury, F. G. ^[2]; Philips, N. R. ^[3]; Mason, P. ^[4]; Peterson, N. E. ^[1]; Deal, A. ^[5]; Klemm-Toole, J. ^[1]; Clarke, A. J. ^[1]

Colorado School of Mines, Golden, CO (United States)
Colorado School of Mines, Golden, CO (United States); Universidade Federal de São Carlos (Brazil)
Allegheny Technologies Incorporated, Albany, OR (United States)
Thermo-Calc Software, McMurray, PA (United States)
Kansas City National Security Campus, Kansas City, MO (United States)

Here, the search for structural alloys capable of ultrahigh temperature performance has led to the exploration of refractory multi-principal element alloys (RMPEAs). In this work, experimental results for solidification segregation and homogenization of two RMPEAs, NbTaTiW and MoNbTaTi, are compared to simulations using the Scheil and DICTRA modules in Thermo-Calc®. Scheil calculations accurately predict the observed solidification segregation, while DICTRA predicts general trends and can provide a minimum time to achieve homogenization at a given temperature.

View Accepted Manuscript (DOE)

Research Organization:: Kansas City Nuclear Security Campus (KCNSC), Kansas City, MO (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); Colorado School of Mines and the Conselho Nacional de Desenvolvimento Científico e Tecnológico - Brasil (CNPq)

Grant/Contract Number:: NA0002839

OSTI ID:: 1989196

Report Number(s):: NSC-614-4990

Journal Information:: Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, Journal Name: Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science Journal Issue: 4 Vol. 54; ISSN 1073-5623

Publisher:: ASM InternationalCopyright Statement

Country of Publication:: United States

Language:: English

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