Analysis of Crossover-Induced Capacity Fade in Redox Flow Batteries with Non-Selective Separators

Nemani, Venkat Pavan; Smith, Kyle C.

doi:10.1149/2.0701813jes

Title: Analysis of Crossover-Induced Capacity Fade in Redox Flow Batteries with Non-Selective Separators

Journal Article · Mon Oct 01 00:00:00 EDT 2018 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0701813jes· OSTI ID:1988801

Nemani, Venkat Pavan; Smith, Kyle C.

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Joint Center for Energy Storage Research, an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences(United States Department of Energy (DOE)); Department of Mechanical Science and Engineering at the University of Illinois at Urbana-Champaign

OSTI ID:: 1988801

Journal Information:: Journal of the Electrochemical Society, Vol. 165, Issue 13

Country of Publication:: United States

Language:: English

References (62)

Redox flow batteries a review Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P. Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1137-1164 https://doi.org/10.1007/s10800-011-0348-2	journal	September 2011
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011
Progress in redox flow batteries, remaining challenges and their applications in energy storage Leung, Puiki; Li, Xiaohong; Ponce de León, Carlos RSC Advances, Vol. 2, Issue 27 https://doi.org/10.1039/c2ra21342g	journal	January 2012
Recent Progress in Redox Flow Battery Research and Development Wang, Wei; Luo, Qingtao; Li, Bin Advanced Functional Materials, Vol. 23, Issue 8, p. 970-986 https://doi.org/10.1002/adfm.201200694	journal	September 2012
Redox flow batteries for the storage of renewable energy: A review Alotto, Piergiorgio; Guarnieri, Massimo; Moro, Federico Renewable and Sustainable Energy Reviews, Vol. 29 https://doi.org/10.1016/j.rser.2013.08.001	journal	January 2014
Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries Darling, Robert M.; Gallagher, Kevin G.; Kowalski, Jeffrey A. Energy & Environmental Science, Vol. 7, Issue 11, p. 3459-3477 https://doi.org/10.1039/C4EE02158D	journal	January 2014
Cost and performance model for redox flow batteries Viswanathan, Vilayanur; Crawford, Alasdair; Stephenson, David Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2012.12.023	journal	February 2014
Characteristics of a new all-vanadium redox flow battery Rychcik, M.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 22, Issue 1 https://doi.org/10.1016/0378-7753(88)80005-3	journal	January 1988
Bromine Complexation in Zinc‐Bromine Circulating Batteries Eustace, Daniel J. Journal of The Electrochemical Society, Vol. 127, Issue 3 https://doi.org/10.1149/1.2129706	journal	March 1980
Properties of modified electrolyte for zinc-bromine cells Cedzynska, Krystyna Electrochimica Acta, Vol. 40, Issue 8 https://doi.org/10.1016/0013-4686(94)00372-8	journal	June 1995
Electron-reservoir complexes and other redox-robust reagents: functions and applications Astruc, Didier New Journal of Chemistry, Vol. 33, Issue 6 https://doi.org/10.1039/b903188j	journal	January 2009
Sustainable Electrical Energy Storage through the Ferrocene/Ferrocenium Redox Reaction in Aprotic Electrolyte Zhao, Yu; Ding, Yu; Song, Jie Angewandte Chemie International Edition, Vol. 53, Issue 41 https://doi.org/10.1002/anie.201406135	journal	August 2014
TEMPO-Based Catholyte for High-Energy Density Nonaqueous Redox Flow Batteries Wei, Xiaoliang; Xu, Wu; Vijayakumar, Murugesan Advanced Materials, Vol. 26, Issue 45 https://doi.org/10.1002/adma.201403746	journal	October 2014
Alkaline quinone flow battery Lin, K.; Chen, Q.; Gerhardt, M. R. Science, Vol. 349, Issue 6255, p. 1529-1532 https://doi.org/10.1126/science.aab3033	journal	September 2015
Impact of Redox-Active Polymer Molecular Weight on the Electrochemical Properties and Transport Across Porous Separators in Nonaqueous Solvents Nagarjuna, Gavvalapalli; Hui, Jingshu; Cheng, Kevin J. Journal of the American Chemical Society, Vol. 136, Issue 46, p. 16309-16316 https://doi.org/10.1021/ja508482e	journal	October 2014
Room temperature ionic liquid electrolytes for redox flow batteries Ejigu, Andinet; Greatorex-Davies, Peter A.; Walsh, Darren A. Electrochemistry Communications, Vol. 54 https://doi.org/10.1016/j.elecom.2015.01.016	journal	May 2015
Li-Redox Flow Batteries Based on Hybrid Electrolytes: At the Cross Road between Li-ion and Redox Flow Batteries Wang, Yarong; He, Ping; Zhou, Haoshen Advanced Energy Materials, Vol. 2, Issue 7, p. 770-779 https://doi.org/10.1002/aenm.201200100	journal	June 2012
An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery Brushett, Fikile R.; Vaughey, John T.; Jansen, Andrew N. Advanced Energy Materials, Vol. 2, Issue 11, p. 1390-1396 https://doi.org/10.1002/aenm.201200322	journal	June 2012
Silica modified nanofiltration membranes with improved selectivity for redox flow battery application Zhang, Hongzhang; Zhang, Huamin; Li, Xianfeng Energy Environ. Sci., Vol. 5, Issue 4 https://doi.org/10.1039/C1EE02571F	journal	January 2012
Advanced porous membranes with ultra-high selectivity and stability for vanadium flow batteries Yuan, Zhizhang; Duan, Yinqi; Zhang, Hongzhang Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE02896E	journal	January 2016
Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications Wei, X.; Nie, Z.; Luo, Q. Journal of the Electrochemical Society, Vol. 160, Issue 8, p. A1215-A1218 https://doi.org/10.1149/2.087308jes	journal	January 2013
A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage Yang, Yuan; Zheng, Guangyuan; Cui, Yi Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee00072a	journal	January 2013
Membrane-less organic–inorganic aqueous flow batteries with improved cell potential Leung, P. K.; Martin, T.; Shah, A. A. Chemical Communications, Vol. 52, Issue 99 https://doi.org/10.1039/C6CC07692K	journal	January 2016
Membrane-less hydrogen bromine flow battery Braff, William A.; Bazant, Martin Z.; Buie, Cullen R. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3346	journal	August 2013
Membraneless Vanadium Redox Fuel Cell Using Laminar Flow Ferrigno, Rosaria; Stroock, Abraham D.; Clark, Thomas D. Journal of the American Chemical Society, Vol. 124, Issue 44 https://doi.org/10.1021/ja020812q	journal	November 2002
A Microfluidic Fuel Cell with Flow-Through Porous Electrodes Kjeang, Erik; Michel, Raphaelle; Harrington, David A. Journal of the American Chemical Society, Vol. 130, Issue 12 https://doi.org/10.1021/ja078248c	journal	March 2008
A Membrane-Free Redox Flow Battery with Two Immiscible Redox Electrolytes Navalpotro, Paula; Palma, Jesus; Anderson, Marc Angewandte Chemie International Edition, Vol. 56, Issue 41 https://doi.org/10.1002/anie.201704318	journal	July 2017
Cost-driven materials selection criteria for redox flow battery electrolytes Dmello, Rylan; Milshtein, Jarrod D.; Brushett, Fikile R. Journal of Power Sources, Vol. 330 https://doi.org/10.1016/j.jpowsour.2016.08.129	journal	October 2016
Feasibility of a Supporting‐Salt‐Free Nonaqueous Redox Flow Battery Utilizing Ionic Active Materials Milshtein, Jarrod D.; Fisher, Sydney L.; Breault, Tanya M. ChemSusChem, Vol. 10, Issue 9 https://doi.org/10.1002/cssc.201700028	journal	March 2017
Progress and prospects of next-generation redox flow batteries Zhang, Changkun; Zhang, Leyuan; Ding, Yu Energy Storage Materials, Vol. 15 https://doi.org/10.1016/j.ensm.2018.06.008	journal	November 2018
A dynamic performance model for redox-flow batteries involving soluble species Shah, A. A.; Watt-Smith, M. J.; Walsh, F. C. Electrochimica Acta, Vol. 53, Issue 27, p. 8087-8100 https://doi.org/10.1016/j.electacta.2008.05.067	journal	November 2008
3-D pore-scale resolved model for coupled species/charge/fluid transport in a vanadium redox flow battery Qiu, Gang; Joshi, Abhijit S.; Dennison, C. R. Electrochimica Acta, Vol. 64 https://doi.org/10.1016/j.electacta.2011.12.065	journal	March 2012
A simple analytical model of coupled single flow channel over porous electrode in vanadium redox flow battery with serpentine flow channel Ke, Xinyou; Alexander, J. Iwan D.; Prahl, Joseph M. Journal of Power Sources, Vol. 288 https://doi.org/10.1016/j.jpowsour.2015.04.138	journal	August 2015
Mathematical Modeling of Electrolyte Flow in a Segment of Flow Channel over Porous Electrode Layered System in Vanadium Flow Battery with Flow Field Design Ke, Xinyou; Prahl, Joseph M.; Alexander, J. Iwan D. Electrochimica Acta, Vol. 223 https://doi.org/10.1016/j.electacta.2016.12.017	journal	January 2017
Real-time monitoring of capacity loss for vanadium redox flow battery Wei, Zhongbao; Bhattarai, Arjun; Zou, Changfu Journal of Power Sources, Vol. 390 https://doi.org/10.1016/j.jpowsour.2018.04.063	journal	June 2018
Modeling of vanadium ion diffusion across the ion exchange membrane in the vanadium redox battery Skyllas-Kazacos, Maria; Goh, Leesean Journal of Membrane Science, Vol. 399-400 https://doi.org/10.1016/j.memsci.2012.01.024	journal	May 2012
Dynamic modelling of the effects of ion diffusion and side reactions on the capacity loss for vanadium redox flow battery Tang, Ao; Bao, Jie; Skyllas-Kazacos, Maria Journal of Power Sources, Vol. 196, Issue 24 https://doi.org/10.1016/j.jpowsour.2011.09.003	journal	December 2011
Coupled Membrane Transport Parameters for Ionic Species in All-Vanadium Redox Flow Batteries Ashraf Gandomi, Yasser; Aaron, D. S.; Mench, M. M. Electrochimica Acta, Vol. 218 https://doi.org/10.1016/j.electacta.2016.09.087	journal	November 2016
Numerical and Analytic Modeling of a Membraneless Hydrogen Bromine Laminar Flow Batter Braff, W. A.; Buie, C. R.; Bazant, M. Z. ECS Transactions, Vol. 53, Issue 7 https://doi.org/10.1149/05307.0051ecst	journal	May 2013
High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Cho, Kyu Taek; Ridgway, Paul; Weber, Adam Z. Journal of The Electrochemical Society, Vol. 159, Issue 11 https://doi.org/10.1149/2.018211jes	journal	January 2012
Numerical modelling of a bromide–polysulphide redox flow battery Scamman, Daniel P.; Reade, Gavin W.; Roberts, Edward P. L. Journal of Power Sources, Vol. 189, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.01.071	journal	April 2009
Modeling and simulation study of a metal free organic–inorganic aqueous flow battery with flow through electrode Li, Xin Electrochimica Acta, Vol. 170 https://doi.org/10.1016/j.electacta.2015.04.075	journal	July 2015
Uncovering the role of flow rate in redox-active polymer flow batteries: simulation of reaction distributions with simultaneous mixing in tanks Nemani, V. Pavan; Smith, Kyle C. Electrochimica Acta, Vol. 247 https://doi.org/10.1016/j.electacta.2017.07.008	journal	September 2017
Assessing the impact of electrolyte conductivity and viscosity on the reactor cost and pressure drop of redox-active polymer flow batteries Iyer, Vinay A.; Schuh, Jonathon K.; Montoto, Elena C. Journal of Power Sources, Vol. 361 https://doi.org/10.1016/j.jpowsour.2017.06.052	journal	September 2017
Transport Property Requirements for Flow Battery Separators Darling, Robert; Gallagher, Kevin; Xie, Wei Journal of The Electrochemical Society, Vol. 163, Issue 1 https://doi.org/10.1149/2.0051601jes	journal	July 2015
Marcus–Hush–Chidsey theory of electron transfer applied to voltammetry: A review Henstridge, Martin C.; Laborda, Eduardo; Rees, Neil V. Electrochimica Acta, Vol. 84 https://doi.org/10.1016/j.electacta.2011.10.026	journal	December 2012
Simple formula for Marcus–Hush–Chidsey kinetics Zeng, Yi; Smith, Raymond B.; Bai, Peng Journal of Electroanalytical Chemistry, Vol. 735 https://doi.org/10.1016/j.jelechem.2014.09.038	journal	December 2014
Enhancing Mass Transport in Redox Flow Batteries by Tailoring Flow Field and Electrode Design Dennison, C. R.; Agar, Ertan; Akuzum, Bilen Journal of The Electrochemical Society, Vol. 163, Issue 1 https://doi.org/10.1149/2.0231601jes	journal	November 2015
Porous-electrode theory with battery applications Newman, John; Tiedemann, William AIChE Journal, Vol. 21, Issue 1 https://doi.org/10.1002/aic.690210103	journal	January 1975
On the Theory of Oxidation‐Reduction Reactions Involving Electron Transfer. I Marcus, R. A. The Journal of Chemical Physics, Vol. 24, Issue 5 https://doi.org/10.1063/1.1742723	journal	May 1956
Chemical and Electrochemical Electron-Transfer Theory Marcus, R. A. Annual Review of Physical Chemistry, Vol. 15, Issue 1 https://doi.org/10.1146/annurev.pc.15.100164.001103	journal	October 1964
Quantifying Mass Transfer Rates in Redox Flow Batteries Milshtein, Jarrod D.; Tenny, Kevin M.; Barton, John L. Journal of The Electrochemical Society, Vol. 164, Issue 11 https://doi.org/10.1149/2.0201711jes	journal	January 2017
From random sphere packings to regular pillar arrays: Analysis of transverse dispersion Daneyko, Anton; Hlushkou, Dzmitry; Khirevich, Siarhei Journal of Chromatography A, Vol. 1257 https://doi.org/10.1016/j.chroma.2012.08.024	journal	September 2012
A Newton-Raphson method for the solution of systems of equations Ben-Israel, Adi Journal of Mathematical Analysis and Applications, Vol. 15, Issue 2 https://doi.org/10.1016/0022-247X(66)90115-6	journal	August 1966
Historical Development of the Newton–Raphson Method Ypma, Tjalling J. SIAM Review, Vol. 37, Issue 4 https://doi.org/10.1137/1037125	journal	December 1995
Nanofluidic Redox Cycling Amplification for the Selective Detection of Catechol Wolfrum, Bernhard; Zevenbergen, Marcel; Lemay, Serge Analytical Chemistry, Vol. 80, Issue 4 https://doi.org/10.1021/ac7016647	journal	February 2008
Temperature Dependence of Self-Diffusion Coefficients of Ions and Solvents in Ethylene Carbonate, Propylene Carbonate, and Diethyl Carbonate Single Solutions and Ethylene Carbonate + Diethyl Carbonate Binary Solutions of LiPF ₆ Studied by NMR Hayamizu, Kikuko Journal of Chemical & Engineering Data, Vol. 57, Issue 7 https://doi.org/10.1021/je3003089	journal	June 2012
Transport Properties of LiPF[sub 6]-Based Li-Ion Battery Electrolytes Valo̸en, Lars Ole; Reimers, Jan N. Journal of The Electrochemical Society, Vol. 152, Issue 5 https://doi.org/10.1149/1.1872737	journal	January 2005
The Influence of Electric Field on Crossover in Redox-Flow Batteries Darling, Robert M.; Weber, Adam Z.; Tucker, Michael C. Journal of The Electrochemical Society, Vol. 163, Issue 1 https://doi.org/10.1149/2.0031601jes	journal	July 2015
Quantifying tortuosity in porous Li-ion battery materials Thorat, Indrajeet V.; Stephenson, David E.; Zacharias, Nathan A. Journal of Power Sources, Vol. 188, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.12.032	journal	March 2009
Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. I. Dielektrizitätskonstanten und Leitfähigkeiten der Mischkörper aus isotropen Substanzen Bruggeman, D. A. G. Annalen der Physik, Vol. 416, Issue 7 https://doi.org/10.1002/andp.19354160705	journal	January 1935
Scanning Electrochemical Microscopy and Hydrodynamic Voltammetry Investigation of Charge Transfer Mechanisms on Redox Active Polymers Burgess, M.; Hernandez-Burgos, K.; Simpson, B. H. Journal of the Electrochemical Society, Vol. 163, Issue 4, p. H3006-H3013 https://doi.org/10.1149/2.0021604jes	journal	November 2015

Similar Records

Understanding and Mitigating Capacity Fade in Aqueous Organic Redox Flow Batteries

Journal Article · Tue Apr 24 00:00:00 EDT 2018 · Journal of the Electrochemical Society · OSTI ID:1988801

Murali, Advaith; Nirmalchandar, Archith; Krishnamoorthy, Sankarganesh; +5 more

Assessing the levelized cost of vanadium redox flow batteries with capacity fade and rebalancing

Journal Article · Mon Jun 01 00:00:00 EDT 2020 · Journal of Power Sources · OSTI ID:1988801

Rodby, Kara E.; Carney, Thomas J.; Gandomi, Yasser Ashraf; +3 more

Long-Term Stability of Ferri-/Ferrocyanide as an Electroactive Component for Redox Flow Battery Applications: On the Origin of Apparent Capacity Fade

Journal Article · Fri Jul 28 00:00:00 EDT 2023 · Journal of the Electrochemical Society · OSTI ID:1988801

Fell, Eric M.; De Porcellinis, Diana; Jing, Yan; +5 more

Title: Analysis of Crossover-Induced Capacity Fade in Redox Flow Batteries with Non-Selective Separators

Citation Formats

References (62)

Similar Records

Related Subjects