A Bi-Layer Dense/Porous Solid Electrolyte Interphase for Enhanced Lithium-Metal Stability

Conference · Wed Oct 13 04:00:00 EDT 2021

DOI:https://doi.org/10.1149/MA2021-021141mtgabs· OSTI ID:1987466

Efaw, Corey Michael ^[1]; Lu, Bingyu ^[2]; Lin, Yuxiao ^[1]; Pawar, Gorakh M ^[1]; Chinnam, Parameswara Rao ^[1]; Hurley, Michael F. ^[3]; Meng, Ying Shirley ^[2]; Dufek, Eric J ^[1]; Li, Bin ^[1]

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1. Idaho National Laboratory
2. Department of NanoEngineering, University of California San Diego
3. Micron School of Materials Science & Engineering, Boise State University

Due to its high theoretical capacity and low electrochemical potential, lithium metal is a highly investigated anode for next-generation high-energy batteries. However, the unstable chemical and topographical heterogeneous surface of lithium gives rise to safety and efficiency concerns that prevent it from being utilized in practical applications. Exposure to electrolyte leads to non-uniform, mixed organic-inorganic solid-electrolyte interphase (SEI) formation, starting a cascading to non-uniform flux distribution, consumption of active materials, and dendrite growth. The SEI is the key feature that will lead to harnessing the capabilities possible with lithium metal. In this work, the formation of a closed-host bi-layer solid electrolyte interphase (SEI) improves the stability of lithium anode. This is successfully realized by forming an interconnected porous LiF-rich artificial SEI in contact with Li metal, and a dense, stable in-situ formed upper layer SEI. The porous layer increases the number of Li/LiF interfaces, which reduces local volume fluctuations and improves Li+ diffusion along these interfaces. Additionally, the tortuous porous structure guides uniform Li+ flux distribution and mechanically suppresses dendrite propagation. The dense upper layer of the SEI accomplishes a closed-host design through reaction with LiNO3 additive and prevents continuous consumption of active materials seen without the additive included in the electrolyte. The duality of a dense top layer with porous bottom layer led to extended cycle life and improved rate performance, evidenced with symmetric cell testing, as well as full cell testing paired with sulfur and LiFePO4 (LFP) cathodes. This work is a good example of a rational design of the SEI, based on comprehensive consideration of various critical factors to improve Li-metal anode stability, and highlights a new pathway to improve cycling and rate performances of Li metal batteries.

• Research Organization: Idaho National Laboratory (INL), Idaho Falls, ID (United States)
• Sponsoring Organization: 13
• DOE Contract Number: AC07-05ID14517
• OSTI ID: 1987466
• Report Number(s): INL/CON-21-62457-Rev000
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
Artificial solid-electrolyte interphase
Closed-host design
Li-metal batteries