Electrolyte for stable cycling of rechargeable alkali metal and alkali ion batteries

Cao, Xia; Zhang, Ji-Guang; Xu, Wu

Electrolyte for stable cycling of rechargeable alkali metal and alkali ion batteries

Patent · Tue Mar 07 04:00:00 EST 2023

OSTI ID:1987212

Cao, Xia; Zhang, Ji-Guang; Xu, Wu

Localized superconcentrated electrolytes (LSEs) and electrochemical devices including the LSEs are disclosed. The LSE includes an active salt, a solvent in which the active salt is soluble, and a diluent in which the active salt is insoluble or poorly soluble, wherein the diluent includes a fluorinated orthoformate.

View Patent

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 11,600,859

Application Number:: 16/688,929

OSTI ID:: 1987212

Country of Publication:: United States

Language:: English

References (34)

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode Ding, Fei; Xu, Wu; Chen, Xilin Journal of The Electrochemical Society, Vol. 160, Issue 10 https://doi.org/10.1149/2.100310jes	journal	January 2013
Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries Zhu, Ye; Casselman, Matthew D.; Li, Yan Journal of Power Sources, Vol. 246 https://doi.org/10.1016/j.jpowsour.2013.07.070	journal	January 2014
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Flame-retardant additives for lithium-ion batteries Hyung, Yoo E.; Vissers, Donald R.; Amine, Khalil Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00225-8	journal	June 2003
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions Ren, Xiaodi; Zou, Lianfeng; Cao, Xia Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.05.006	journal	July 2019
Review—Superconcentrated Electrolytes for Lithium Batteries Yamada, Yuki; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0041514jes	journal	January 2015
The Evaluation of Triphenyl Phosphate as A Flame Retardant Additive to Improve The Safety of Lithium-Ion Battery Electrolytes Smart, Marshall C.; Krause, Frederick C.; Hwang, Constanza ECS Transactions, Vol. 35, Issue 13 https://doi.org/10.1149/1.3646164	journal	April 2011
Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: I. Fundamental Properties Wang, Xianming; Yasukawa, Eiki; Kasuya, Shigeaki Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1397773	journal	January 2001
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range Zhang, Xianhui; Zou, Lianfeng; Xu, Yaobin Advanced Energy Materials, Vol. 10, Issue 22 https://doi.org/10.1002/aenm.202000368	journal	April 2020
Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics Smith, Kiah A.; Smart, Marshall C.; Prakash, G. K. Surya ECS Transactions, Vol. 16, Issue 35 https://doi.org/10.1149/1.3123125	journal	August 2009
Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances Li, Qiuyan; Lu, Dongping; Zheng, Jianming ACS Applied Materials & Interfaces, Vol. 9, Issue 49 https://doi.org/10.1021/acsami.7b13887	journal	November 2017
Fire-extinguishing organic electrolytes for safe batteries Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0033-8	journal	November 2017
Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries Zhang, S. S.; Xu, K.; Jow, T. R. Journal of Power Sources, Vol. 113, Issue 1 https://doi.org/10.1016/S0378-7753(02)00537-2	journal	January 2003
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Solvate Ionic Liquid Electrolyte for Li–S Batteries Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.111308jes	journal	January 2013
Dilution of Highly Concentrated LiBF ₄ /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi _0.5 Mn _1.5 O ₄ Positive Electrodes Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0611701jes	journal	January 2017
Electrochemical performance of lithium-ion batteries with triphenylphosphate as a flame-retardant additive Shim, Eun-Gi; Nam, Tae-Heum; Kim, Jung-Gu Journal of Power Sources, Vol. 172, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.04.088	journal	October 2007
Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries Yao, X. L.; Xie, S.; Chen, C. H. Journal of Power Sources, Vol. 144, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.11.042	journal	June 2005
A highly safe battery with a non-flammable triethyl-phosphate-based electrolyte Matsumoto, Kazuaki; Inoue, Kazuhiko; Utsugi, Koji Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.086	journal	January 2015
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate Xu, Kang; Zhang, Shengshui; Allen, Jan L. Journal of The Electrochemical Society, Vol. 149, Issue 8 https://doi.org/10.1149/1.1490356	journal	January 2002
Engineering Needs Immigration Jan, Alexander The Engineer, Vol. 298, Issue 7904 https://doi.org/10.12968/S0013-7758(23)90341-7	journal	January 2019
An Attempt to Formulate Nonflammable Lithium Ion Electrolytes with Alkyl Phosphates and Phosphazenes Xu, Kang; Ding, Michael S.; Zhang, Shengshui Journal of The Electrochemical Society, Vol. 149, Issue 5 https://doi.org/10.1149/1.1467946	journal	January 2002
Superconcentrated electrolytes for a high-voltage lithium-ion battery Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12032	journal	June 2016
Determining oxidative stability of battery electrolytes: validity of common electrochemical stability window (ESW) data and alternative strategies Kasnatscheew, J.; Streipert, B.; Röser, S. Physical Chemistry Chemical Physics, Vol. 19, Issue 24 https://doi.org/10.1039/C7CP03072J	journal	January 2017
A Novel Flame-Retardant Additive for Lithium Batteries Lee, Chang Woo Electrochemical and Solid-State Letters, Vol. 3, Issue 2 https://doi.org/10.1149/1.1390959	journal	January 1999
Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries Shiga, Tohru; Kato, Yuichi; Kondo, Hiroki Journal of Materials Chemistry A, Vol. 5, Issue 10 https://doi.org/10.1039/C6TA09915G	journal	January 2017
Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries Chalasani, Dinesh; Li, Jing; Jackson, Nicole M. Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.004	journal	June 2012
Thermal Behavior of Charged Graphite and Li[sub x]CoO[sub 2] in Electrolytes Containing Alkyl Phosphate for Lithium-Ion Cells Shigematsu, Yasuyuki; Ue, Makoto; Yamaki, Jun-ichi Journal of The Electrochemical Society, Vol. 156, Issue 3 https://doi.org/10.1149/1.3056035	journal	January 2009
Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes Xiang, H. F.; Xu, H. Y.; Wang, Z. Z. Journal of Power Sources, Vol. 173, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.05.001	journal	November 2007
Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: II. The Use of an Amorphous Carbon Anode Wang, Xianming; Yasukawa, Eiki; Kasuya, Shigeaki Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1397774	journal	January 2001

Similar Records

Localized superconcentrated electrolytes for stable cycling of electrochemical devices

Patent · Tue Jul 30 00:00:00 EDT 2019 · OSTI ID:1568661

Low flammability electrolytes for stable operation of lithium and sodium ion batteries

Patent · Mon Nov 30 23:00:00 EST 2020 · OSTI ID:1771695

Low flammability electrolytes for stable operation of electrochemical devices

Patent · Mon Nov 11 23:00:00 EST 2019 · OSTI ID:1600264

Electrolyte for stable cycling of rechargeable alkali metal and alkali ion batteries

Citation Formats

References (34)

Similar Records

Related Subjects