All-vanadium sulfate acid redox flow battery system

Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Liu, Jun; Sprenkle, Vincent L.

Title: All-vanadium sulfate acid redox flow battery system

Patent · Tue Dec 20 00:00:00 EST 2022

OSTI ID:1986954

Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Liu, Jun; Sprenkle, Vincent L.

All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl₂, and the phosphate ions are provided by (NH₄)₂HPO₄.

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 11,532,832

Application Number:: 16/859,142

OSTI ID:: 1986954

Resource Relation:: Patent File Date: 04/27/2020

Country of Publication:: United States

Language:: English

References (45)

Novel Vanadium Halide Redox Flow Battery Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100291420 US Patent Document 12/843521; 20100291420	patent-application	November 2010
Redox Flow Batteries Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140234753 US Patent Document 14/261262; 20140234753	patent-application	August 2014
Flow Battery Systems Wilson, Gregory J.; Hanson, Kyle M. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120052347 US Patent Document 12/868489; 20120052347	patent-application	March 2012
Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries Zhang, Jianlu; Li, Liyu; Nie, Zimin Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1215-1221 https://doi.org/10.1007/s10800-011-0312-1	journal	June 2011
Use of polyelectrolyte for incorporation of ion-exchange groups in composite membranes for vanadium redox flow battery applications Mohammadi, T.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 56, Issue 1, p. 91-96 https://doi.org/10.1016/0378-7753(95)80014-8	journal	July 1995
Fe-V Redox Flow Batteries Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077067 US Patent Document 12/892698; 20120077067	patent-application	March 2012
Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method Tanaka, Yasuyuki; Mita, Muneo; Horikawa, Ken https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6872376 US Patent Document 6,872,376	patent	March 2005
Instrumented fluid-surfaced electrode Deane, Geoffrey F.; Ferren, Bran; Gates, William https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110027629 US Patent Document 12/803122; 20110027629	patent-application	February 2011
Redox Flow Batteries Having Multiple Electroactive Elements Wang, Wei; Li, Liyu; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077068 US Patent Document 13/246444; 20120077068	patent-application	March 2012
Flow Battery Having a Separator Membrane Comprising An Ionomer Lloyd, Ralph Birchard; Unlu, Murat https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150311541 US Patent Application 14/650665; 20150311541	patent-application	October 2015
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9123931 US Patent Document 9,123,931	patent	September 2015
Novel vanadium halide redox flow battery Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholasl https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060183016 US Patent Document 10/548555; 20060183016	patent-application	August 2006
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9077011 US Patent Document 9,077,011	patent	July 2015
Redox Flow Cell Rebalancing Keshavarz, Majid; Karuppaiah, Chockkalingam; Zu, Ge https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110086247 US Patent Document 12/790573; 20110086247	patent-application	April 2011
High Energy Battery Materials Adamson, George W.; Ortiz, Jr., Luis A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100230632 US Patent Document 11/992378; 20100230632	patent-application	September 2010
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8628880 US Patent Document 8,628,880	patent	January 2014
A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage Li, Liyu; Kim, Soowhan; Wang, Wei Advanced Energy Materials, Vol. 1, Issue 3, p. 394-400 https://doi.org/10.1002/aenm.201100008	journal	March 2011
A new redox flow battery using Fe/V redox couples in chloride supporting electrolyte Wang, Wei; Kim, Soowhan; Chen, Baowei Energy & Environmental Science, Vol. 4, Issue 10, p. 4068-4073 https://doi.org/10.1039/c0ee00765j	journal	January 2011
Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries Kazacos, George Christopher; Kazacos, Nicholas Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080292964 US Patent Document 11/917989; 20080292964	patent-application	November 2008
Redox Flow Batteries Based On Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140199607 US Patent Application 14/105823; 20140199607	patent-application	July 2014
Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries Kazacos, Maria Skyllas; Kazacos, Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6562514 US Patent Document 6,562,514	patent	May 2003
Method for Storing Electrical Energy in Ionic Liquids Noack, Jens; Tubke, Jens; Pinkwart, Karsten https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120115069 US Patent Application 13/201813; 20120115069	patent-application	May 2012
Novel vanadium chloride/polyhalide redox flow battery Skyllas-Kazacos, Maria Journal of Power Sources, Vol. 124, Issue 1, p. 299-302 https://doi.org/10.1016/S0378-7753(03)00621-9	journal	October 2003
Electrolytes for redox flow batteries Nagashima, Ikuo; Fukui, Jun; Gotoh, Hidenori https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4814241 US Patent Document 4,814,241	patent	March 1989
Investigation of the V(V)/V(IV) system for use in the positive half-cell of a redox battery Sum, E.; Rychcik, M.; Skyllas-kazacos, M. Journal of Power Sources, Vol. 16, Issue 2, p. 85-95 https://doi.org/10.1016/0378-7753(85)80082-3	journal	October 1985
Redox Flow Battery System for Distributed Energy Storage Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110045332 US Patent Document 12/883511; 20110045332	patent-application	February 2011
Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method Giner, Jose D.; Stark, Herbert https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4469760 US Patent Document 4,469,760	patent	September 1984
Redox Fuel Cell Boeke, Jan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3540933 US Patent Document 3,540,933	patent	November 1970
Electrolyte for Redox Flow Battery and Redox Flow Battery Sekine, Ryojun; Dong, Yongrong; Kubata, Michiru https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150221969 US Patent Document 14/422792; 20150221969	patent-application	August 2015
Redox Flow Batteries Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077079 US Patent Document 12/892693; 20120077079	patent-application	March 2012
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions Kazacos, Michael; Kazacos, Maria Skyllas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7078123 US Patent Document 7,078,123	patent	July 2006
Fe-V redox flow batteries Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8771856 US Patent Document 8,771,856	patent	July 2014
Fully flexible financial instrument pricing system with intelligent user interfaces Lim, Cheong Kee Jeffrey https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030014345 US Patent Document 10/182462; 20030014345	patent-application	January 2003
Metal halide redox flow battery Skyllas-Kazacos, Maria; Kazacos, Michael; Mousa, Asem https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050244707 US Patent Document 10/512417; 20050244707	patent-application	November 2005
Electrically rechargeable REDOX flow cell Thaller, Lawrence H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3996064 US Patent Document 3,996,064	patent	December 1976
Production of Vanadium Electrolyte for a Vanadium Flow Cell Keshavarz, Majid; Zu, Ge https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150050570 US Patent Application 14/526435; 20150050570	patent-application	February 2015
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions Kazacos, Michael; Kazacos, Maria Skyllas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030143456 US Patent Document 10/226751; 20030143456	patent-application	July 2003
Redox Flow Battery Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150380757 US Patent Document 14/815037; 20150380757	patent	December 2015
Vanadium/polyhalide redox flow battery Skyllas-Kazacos, Maria https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7320844 US Patent Document 7,320,844	patent	January 2008
All-vanadium redox battery Skyllas-Kazacos, Maria; Rychick, Miron; Robins, Robert R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4786567 US Patent Document 4,786,567	patent	November 1988
High Energy Density Redox Flow Device Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140248521 US Patent Document 14/276723; 20140248521	patent-application	September 2014
System Dongle Parakulam, Gopalakrishnan R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120040216 US Patent Document 12/855059; 20120040216	patent-application	February 2012
A study of the V(II)/V(III) redox couple for redox flow cell applications Sum, E.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 15, Issue 2-3, p. 179-190 https://doi.org/10.1016/0378-7753(85)80071-9	journal	June 1985
Solubility of vanadyl sulfate in concentrated sulfuric acid solutions Rahman, F.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 72, Issue 2 https://doi.org/10.1016/S0378-7753(97)02692-X	journal	April 1998
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011

Similar Records

All-vanadium sulfate acid redox flow battery system

Patent · Tue Jun 02 00:00:00 EDT 2020 · OSTI ID:1986954

Nie, Zimin; Wang, Wei; Wei, Xiaoliang; +3 more

Thin-Film Electrolytes for High-Energy-Density and Low-Cost Polychalcogenide-Based Redox Flow Batteries

Technical Report · Sun Dec 05 00:00:00 EST 2021 · OSTI ID:1986954

Hughes, Kevin; Spradling, Drew; Garza-Ramos, Pedro; +4 more

Redox flow batteries based on supporting solutions containing chloride

Patent · Tue Jul 07 00:00:00 EDT 2015 · OSTI ID:1986954

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; +5 more

Title: All-vanadium sulfate acid redox flow battery system

Citation Formats

References (45)

Similar Records

Related Subjects