Ionothermally Synthesized Nanoporous Ti0.95W0.05Nb2O7: a Novel Anode Material for High-Performance Lithium-Ion Batteries

Tao, Runming; Zhang, Tianyu; Sun, Xiao‐Guang; Do‐Thanh, Chi‐Linh; Dai, Sheng

doi:10.1002/batt.202300101

Ionothermally Synthesized Nanoporous Ti_0.95W_0.05Nb₂O₇: a Novel Anode Material for High-Performance Lithium-Ion Batteries

Journal Article · Wed Apr 05 00:00:00 EDT 2023 · Batteries & Supercaps

DOI:https://doi.org/10.1002/batt.202300101· OSTI ID:1985381

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University of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
University of Tennessee, Knoxville, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Although TiNb₂O₇ is regarded as a fast-rechargeable lithium-ion battery (LIB) anode material, the intrinsic poor electrochemical kinetics of TiNb₂O₇ still dramatically impedes its development. Herein, an ionothermal synthesis-assisted doping strategy is proposed for the preparation of a new W⁶⁺-doped TiNb₂O₇ material (Ti_0.95W_0.05Nb₂O₇) with nanoporous structure (denoted as NPTWNO). The improved Li⁺ diffusion coefficient of NPTWNO suggests that the ionic-liquid-templated nanoporous architecture improves the Li+ diffusion kinetics. The density functional theory computational study reveals that the doped W⁶⁺ successfully boosts the electronic conductivity due to the narrowed conduction-valance bandgap resulted from charge redistribution, which is reflected by the electrochemical impedance spectroscopy data. With the simultaneously enhanced Li+ diffusivity and electronic conductivity, NPTWNO achieves fast-rechargeability in LIBs. So this work indicates the potential of ionothermal synthesis-assisted doping strategy on energy storage materials and offers NPTWNO material with promising electrochemical performance.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1985381

Journal Information:: Batteries & Supercaps, Journal Name: Batteries & Supercaps Journal Issue: 6 Vol. 6; ISSN 2566-6223

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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