Dynamic high pressure phase transformation of ZrW2O8

Bishop, Sean R.; Lowry, Daniel R.; Peretti, Amanda S.; Kalita, Pat; Knudson, Marcus D.; Sarracino, Alex; Mahaffey, Jacob T.; Murray, Shannon E.

doi:10.1063/5.0147942

Dynamic high pressure phase transformation of ZrW₂O₈

Journal Article · Thu Jun 01 00:00:00 EDT 2023 · AIP Advances

DOI:https://doi.org/10.1063/5.0147942· OSTI ID:1984281

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Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Institute for Shock Physics, Washington State University
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Phase transformations under high strain rates (dynamic compression) are examined in situ on ZrW₂O₈, a negative thermal expansion ternary ceramic displaying polymorphism. Amorphization, consistent with prior quasi-static measurements, was observed at a peak pressure of 3.0 GPa under dynamic conditions, which approximate those expected during fabrication. Evidence of partial amorphization was observed at lower pressure (1.8 GPa) that may be kinetically restrained by the short (<~150 ns) time scale of the applied high pressure. The impact of kinetics of pressure-induced amorphization from material fabrication methods is briefly discussed.

View Accepted Manuscript (DOE)

Research Organization:: Washington State University, Pullman, WA (United States); Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Programs (DP); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: NA0003525; NA0003957; AC02-06CH11357

OSTI ID:: 1984281

Alternate ID(s):: OSTI ID: 2311596

Journal Information:: AIP Advances, Journal Name: AIP Advances Journal Issue: 6 Vol. 13; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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