Amorphous-to-crystalline transition of thin-film TiO2 precursor films to brookite, anatase, and rutile polymorphs

Ağırseven, Okan; Biswas, Pritha; Tate, Janet

doi:10.1557/s43578-021-00478-x

Amorphous-to-crystalline transition of thin-film TiO2 precursor films to brookite, anatase, and rutile polymorphs

Journal Article · Tue Jan 04 23:00:00 EST 2022 · Journal of Materials Research

DOI:https://doi.org/10.1557/s43578-021-00478-x· OSTI ID:1983063

; Biswas, Pritha; Tate, Janet

Not provided.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Next Generation of Materials by Design: Incorporating Metastability (CNGMD)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1983063

Journal Information:: Journal of Materials Research, Journal Name: Journal of Materials Research Journal Issue: 6 Vol. 37; ISSN 0884-2914

Publisher:: Springer Nature

Country of Publication:: United States

Language:: English

References (24)

Why is anatase a better photocatalyst than rutile? - Model studies on epitaxial TiO2 films Luttrell, Tim; Halpegamage, Sandamali; Tao, Junguang Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04043	journal	February 2014
Investigation of the Origin of the Empirical Relationship between Refractive Index and Density on the Basis of First Principles Calculations for the Refractive Indices of Various TiO ₂ Phases Rocquefelte, Xavier; Goubin, Fabrice; Koo, Hyun-Joo Inorganic Chemistry, Vol. 43, Issue 7 https://doi.org/10.1021/ic035383r	journal	April 2004
Kinetic Study on Phosphate Enrichment Behavior in CaO–SiO2–FeO–Fe2O3–P2O5 Steelmaking Slags Li, Jin-yan; Zhang, Mei; Guo, Min High Temperature Materials and Processes, Vol. 37, Issue 5 https://doi.org/10.1515/htmp-2016-0241	journal	April 2018
Influence of specimen thickness on isothermal crystallization kinetics. A theoretical analysis Escleine, J. M.; Monasse, B.; Wey, E. Colloid & Polymer Science, Vol. 262, Issue 5 https://doi.org/10.1007/BF01410254	journal	May 1984
Utilizing TiO ₂ amorphous precursors for polymorph selection: An in situ TEM study of phase formation and kinetics Mangum, John S.; Garten, Lauren M.; Ginley, David S. Journal of the American Ceramic Society, Vol. 103, Issue 4 https://doi.org/10.1111/jace.16965	journal	December 2019
In-situ X-ray diffraction studies of time and thickness dependence of crystallization of amorphous TiO2 thin films and stress evolution Kužel, R.; Nichtová, L.; Matěj, Z. Thin Solid Films, Vol. 519, Issue 5 https://doi.org/10.1016/j.tsf.2010.08.122	journal	December 2010
Thin film phase transformation kinetics: From theory to experiment Moghadam, M. M.; Voorhees, P. W. Scripta Materialia, Vol. 124 https://doi.org/10.1016/j.scriptamat.2016.07.010	journal	November 2016
TiO2 anatase thin films as gas sensors Tang, H.; Prasad, K.; Sanjinés, R. Sensors and Actuators B: Chemical, Vol. 26, Issue 1-3 https://doi.org/10.1016/0925-4005(94)01559-Z	journal	January 1995
Size-Dependent Surface-Induced Heterogeneous Nucleation Driven Phase-Change in Ge ₂ Sb ₂ Te ₅ Nanowires Lee, Se-Ho; Jung, Yeonwoong; Agarwal, Ritesh Nano Letters, Vol. 8, Issue 10 https://doi.org/10.1021/nl801698h	journal	October 2008
The effect of finite film thickness on the crystallization kinetics of amorphous film and microstructure of crystallized film Trofimov, Vladimir I.; Trofimov, Ilya V.; Kim, Jong-Il Thin Solid Films, Vol. 495, Issue 1-2 https://doi.org/10.1016/j.tsf.2005.08.221	journal	January 2006
Simulation of phase transformation kinetics in thin films under a constant nucleation rate Moghadam, M. M.; Pang, E. L.; Philippe, T. Thin Solid Films, Vol. 612 https://doi.org/10.1016/j.tsf.2016.06.035	journal	August 2016
Nucleation and growth kinetics of preferred C54 TiSi2 orientations: time-resolved x-ray diffraction measurements Özcan, A. S.; Ludwig, K. F.; Lavoie, C. Journal of Applied Physics, Vol. 92, Issue 9 https://doi.org/10.1063/1.1512687	journal	November 2002
Crystallization mechanism and kinetics of Cr2Ge2Te6 phase change material Hatayama, S.; Sutou, Y.; Ando, D. MRS Communications, Vol. 8, Issue 3 https://doi.org/10.1557/mrc.2018.176	journal	August 2018
Nucleation and Growth of Crystalline Grains in RF-Sputtered TiO₂Films Johnson, J. C.; Ahrenkiel, S. P.; Dutta, P. Research Letters in Nanotechnology, Vol. 2009 https://doi.org/10.1155/2009/280797	journal	January 2009
Selective brookite polymorph formation related to the amorphous precursor state in TiO2 thin films Mangum, John S.; Agirseven, Okan; Haggerty, James E. S. Journal of Non-Crystalline Solids, Vol. 505 https://doi.org/10.1016/j.jnoncrysol.2018.10.049	journal	February 2019
Nanocrystallization of anatase in amorphous TiO2 Švadlák, Daniel; Shánělová, Jana; Málek, Jiřı́ Thermochimica Acta, Vol. 414, Issue 2 https://doi.org/10.1016/j.tca.2003.12.009	journal	May 2004
High-fraction brookite films from amorphous precursors Haggerty, James E. S.; Schelhas, Laura T.; Kitchaev, Daniil A. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-15364-y	journal	November 2017
Crystallization kinetics in Fe−B−Si metallic glasses Ramanan, V. R. V.; Fish, G. E. Journal of Applied Physics, Vol. 53, Issue 3 https://doi.org/10.1063/1.330797	journal	March 1982
Crystallization of Carbamazepine in Proximity to Its Precursor Iminostilbene and a Silica Surface Christian, Paul; Röthel, Christian; Tazreiter, Martin Crystal Growth & Design, Vol. 16, Issue 5 https://doi.org/10.1021/acs.cgd.6b00090	journal	April 2016
Energetics of nanoparticle oxides: interplay between surface energy and polymorphism† Navrotsky, Alexandra Geochemical Transactions, Vol. 4, Issue 1 https://doi.org/10.1186/1467-4866-4-34	journal	November 2003
Avrami exponent under transient and heterogeneous nucleation transformation conditions Sinha, I.; Mandal, R. K. Journal of Non-Crystalline Solids, Vol. 357, Issue 3 https://doi.org/10.1016/j.jnoncrysol.2010.11.005	journal	February 2011
Non-isothermal crystallization kinetics of nano-sized amorphous TiO2 prepared by facile sonochemical hydrolysis route Mansour, Shehab A. Ceramics International, Vol. 45, Issue 2 https://doi.org/10.1016/j.ceramint.2018.07.273	journal	February 2019
Brookite, the Least Known TiO2 Photocatalyst Di Paola, Agatino; Bellardita, Marianna; Palmisano, Leonardo Catalysts, Vol. 3, Issue 1 https://doi.org/10.3390/catal3010036	journal	January 2013
Crystallization of TiO ₂ polymorphs from RF-sputtered, amorphous thin-film precursors Agirseven, O.; Rivella, D. T.; Haggerty, J. E. S. AIP Advances, Vol. 10, Issue 2 https://doi.org/10.1063/1.5140368	journal	February 2020

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