Relaxation and darkening of excitonic complexes in electrostatically doped monolayer $$\mathrm{WSe_2}$$: Roles of exciton-electron and trion-electron interactions

Journal Article · Mon Feb 07 00:00:00 EST 2022 · Physical Review. B

DOI:https://doi.org/10.1103/physrevb.105.085302· OSTI ID:1979725

Yang, Min ^[1]; Ren, Lei ^[2]; Robert, Cedric ^[2]; Van Tuan, Dinh ^[3]; Lombez, Laurent ^[2]; Urbaszek, Bernhard ^[2]; Marie, Xavier ^[2]; Dery, Hanan ^[3]

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1. University of Rochester, NY (United States); OSTI
2. University of Toulouse (France)
3. University of Rochester, NY (United States)

Here we present photoluminescence measurements in monolayer $$\mathrm{WSe_2}$$, which point to the importance of the interaction between charged particles and excitonic complexes. The theoretical analysis highlights the key role played by exchange scattering, referring to cases wherein the particle composition of the complex changes after the interaction. For example, exchange scattering renders bright excitonic complexes dark in monolayer $$\mathrm{WSe_2}$$ on accounts of the unique valley-spin configuration in this material. In addition to the ultrafast energy relaxation of hot excitonic complexes following their interaction with electrons or holes, our analysis sheds light on several key features that are commonly seen in the photoluminescence of this monolayer semiconductor. In particular, we can understand why the photoluminescence intensity of the neutral bright exciton is strongest when the monolayer is hole doped rather than charge neutral or electron doped. Similarly, we can understand the reason for the dramatic increase of the photoluminescence intensity of negatively charged excitons (trions) as soon as electrons are added to the monolayer. To self-consistently explain the findings, we further study the photoluminescence spectra at different excitation energies and analyze the behavior of the elusive indirect exciton.

• Research Organization: University of Rochester, NY (United States)
• Sponsoring Organization: Agence Nationale de la Recherche (ANR); Office of Naval Research (ONR); USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Grant/Contract Number: SC0014349
• OSTI ID: 1979725
• Journal Information: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 8 Vol. 105; ISSN 2469-9950
• Publisher: American Physical Society (APS)
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
Trions
excitons
luminescence
transition metal dichalcogenides