Hydrophilic and hydrophobic carboxamide pincers as anion hosts

Lohrman, Jessica; Pramanik, Subhamay; Kaur, Sandeep; Telikepalli, Hanumaiah; Day, Victor W.; Bowman-James, Kristin

doi:10.1039/d1ob01605a

Hydrophilic and hydrophobic carboxamide pincers as anion hosts

Journal Article · Thu Sep 09 00:00:00 EDT 2021 · Organic and Biomolecular Chemistry

DOI:https://doi.org/10.1039/d1ob01605a· OSTI ID:1978816

Lohrman, Jessica ^[1]; ^[2]; ^[2]; Telikepalli, Hanumaiah ^[2]; Day, Victor W. ^[2]; ^[2]

University of Kansas, Lawrence, KS (United States); OSTI
University of Kansas, Lawrence, KS (United States)

Hydrophobic and hydrophilic, monotopic and ditopic carboxamide pincer hosts containing ethyl, hexyl, 2-hydroxyethyl and 2-hydroxyethyl ethyl ether pendant arms were synthesized. Solubility trends indicated that solubilities in water or hydrocarbon solvents varied depending on the nature of the pendant arms. Binding constants for hydrophilic pincers were larger in general than their hydrophobic analogs. Furthermore, significant synergistic binding effects for the ditopic hosts were not observed.

View Accepted Manuscript (DOE)

Research Organization:: University of Kansas, Lawrence, KS (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0018629

OSTI ID:: 1978816

Alternate ID(s):: OSTI ID: 1821764

Journal Information:: Organic and Biomolecular Chemistry, Journal Name: Organic and Biomolecular Chemistry Journal Issue: 39 Vol. 19; ISSN OBCRAK; ISSN 1477-0520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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