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Title: Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements

Journal Article · · ACS Earth and Space Chemistry
ORCiD logo [1];  [2]; ORCiD logo [1];  [2];  [3];  [4];  [5]; ORCiD logo [6]; ORCiD logo [7]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada
  2. Department of Chemistry, University of California Irvine, Irvine, California 92697, United States
  3. Institute of Energy & Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
  4. Institute of Energy & Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, 52428 Jülich, Germany; Institute for Environmental Research & Sustainable Development, National Observatory of Athens, 15236 Palea Penteli, Greece
  5. Dept. of Physics, Portland State University, Portland, Oregon 97201, United States
  6. Department of Chemistry, University of California Irvine, Irvine, California 92697, United States; Department of Ecology and Evolutionary Biology, University of California Irvine, Irvine, California 92697, United States
  7. Atmospheric Chemistry Department, Max Planck Institute for Chemistry, 55128 Mainz, Germany; Climate and Atmosphere Research Center, The Cyprus Institute, 1645 Nicosia, Cyprus

Not provided.

Research Organization:
Univ. of California, Irvine, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0018349; SC0022139
OSTI ID:
1978329
Journal Information:
ACS Earth and Space Chemistry, Vol. 5, Issue 12; ISSN 2472-3452
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (113)

Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies journal January 2011
The formation, properties and impact of secondary organic aerosol: current and emerging issues journal January 2009
Aerosol Health Effects from Molecular to Global Scales journal November 2017
Health Effects of Fine Particulate Air Pollution: Lines that Connect journal June 2006
The contribution of outdoor air pollution sources to premature mortality on a global scale journal September 2015
Clean air in the Anthropocene journal January 2017
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere journal January 2011
Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of α -pinene journal January 2016
Heterogeneous nucleation of ice particles on glassy aerosols under cirrus conditions journal March 2010
Ice cloud processing of ultra-viscous/glassy aerosol particles leads to enhanced ice nucleation ability journal January 2012
The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review journal January 2018
A biogenic secondary organic aerosol source of cirrus ice nucleating particles journal October 2020
Competition between water uptake and ice nucleation by glassy organic aerosol particles journal January 2014
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction journal January 2014
Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol journal January 2018
Size distribution dynamics reveal particle-phase chemistry in organic aerosol formation journal July 2013
Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model journal January 2019
Factors controlling the evaporation of secondary organic aerosol from α‐pinene ozonolysis journal March 2017
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX) journal February 2018
The influence of physical state on shikimic acid ozonolysis: a case for in situ microspectroscopy journal January 2014
Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter journal January 2018
Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol journal January 2018
Gas uptake and chemical aging of semisolid organic aerosol particles journal June 2011
Chemical Reactivity and Liquid/Nonliquid States of Secondary Organic Material journal October 2015
Heterogeneous oxidation of amorphous organic aerosol surrogates by O3, NO3, and OH at typical tropospheric temperatures journal January 2020
Interfacial Dimerization by Organic Radical Reactions during Heterogeneous Oxidative Aging of Oxygenated Organic Aerosols journal November 2019
Experimental determination of chemical diffusion within secondary organic aerosol particles journal January 2013
Effect of varying experimental conditions on the viscosity of α -pinene derived secondary organic material journal January 2016
Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) journal September 2019
Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures journal February 2020
Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations journal January 2019
Diffusivity measurements of volatile organics in levitated viscous aerosol particles journal January 2017
The viscosity of atmospherically relevant organic particles journal March 2018
A predictive group-contribution model for the viscosity of aqueous organic aerosol journal January 2020
Lability of secondary organic particulate matter journal October 2016
Viscosity of  -pinene secondary organic material and implications for particle growth and reactivity journal April 2013
Ultra-slow water diffusion in aqueous sucrose glasses journal January 2011
The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy journal September 2019
Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities journal January 2019
Relative humidity-dependent viscosity of secondary organic material from toluene photo-oxidation and possible implications for organic particulate matter over megacities journal January 2016
An amorphous solid state of biogenic secondary organic aerosol particles journal October 2010
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective journal January 2017
Global distribution of particle phase state in atmospheric secondary organic aerosols journal April 2017
Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model journal January 2020
Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ journal July 2021
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations journal January 2011
Rainforest Aerosols as Biogenic Nuclei of Clouds and Precipitation in the Amazon journal September 2010
An overview of the Amazonian Aerosol Characterization Experiment 2008 (AMAZE-08) journal January 2010
MWH's Water Treatment: Principles and Design book March 2012
Secondary Organic Aerosol Formation from Healthy and Aphid-Stressed Scots Pine Emissions journal August 2019
Multi-layered Scots pine forests in boreal Sweden result from mass regeneration and size stratification journal June 2019
Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems journal January 2020
Secondary organic aerosol from VOC mixtures in an oxidation flow reactor journal July 2017
Secondary organic aerosol reduced by mixture of atmospheric vapours journal January 2019
Terpene Composition Complexity Controls Secondary Organic Aerosol Yields from Scots Pine Volatile Emissions journal February 2018
Relaxation in liquids, polymers and plastic crystals — strong/fragile patterns and problems journal June 1991
Liquid Fragility and the Glass Transition in Water and Aqueous Solutions journal August 2002
Entropy and fragility in supercooling liquids journal March 1997
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition journal January 2018
Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime journal September 2008
Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity journal January 2021
Estimating Secondary Organic Aerosol Production from Toluene Photochemistry in a Megacity of China journal July 2019
Organic Aerosol Mixing Observed by Single-Particle Mass Spectrometry journal November 2013
Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors journal January 2019
Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of organic carbon emissions journal October 2012
The Atmospheric Aerosol-Forming Potential of Whole Gasoline Vapor journal April 1997
Distribution, magnitudes, reactivities, ratios and diurnal patterns of volatile organic compounds in the Valley of Mexico during the MCMA 2002 & 2003 field campaigns journal January 2007
Eddy covariance flux measurements of pollutant gases in urban Mexico City journal January 2009
Temperature dependence of yields of secondary organic aerosols from the ozonolysis of α -pinene and limonene journal January 2009
Second-generation products contribute substantially to the particle-phase organic material produced by β-caryophyllene ozonolysis journal January 2011
Effect of relative humidity on the composition of secondary organic aerosol from the oxidation of toluene journal January 2018
Real-Time Aerosol Density Determination Utilizing a Modified Scanning Mobility Particle Sizer—Aerosol Particle Mass Analyzer System journal June 2009
Formation and chemical aging of secondary organic aerosol during the β-caryophyllene oxidation journal January 2015
Laboratory and Ambient Particle Density Determinations using Light Scattering in Conjunction with Aerosol Mass Spectrometry journal March 2007
Measurements of Secondary Organic Aerosol from Oxidation of Cycloalkenes, Terpenes, and m -Xylene Using an Aerodyne Aerosol Mass Spectrometer journal August 2005
Secondary organic aerosol formation from <i>m</i>-xylene, toluene, and benzene journal January 2007
The Temperature Dependence of the Viscosity of Supercooled Water journal December 1963
ORACLE (v1.0): module to simulate the organic aerosol composition and evolution in the atmosphere journal January 2014
ORACLE 2-D (v2.0): an efficient module to compute the volatility and oxygen content of organic aerosol with a global chemistry–climate model journal January 2018
Molecular corridors and kinetic regimes in the multiphase chemical evolution of secondary organic aerosol journal January 2014
Aerosol mass spectrometer constraint on the global secondary organic aerosol budget journal January 2011
Dynamic viscosity mapping of the oxidation of squalene aerosol particles journal January 2016
Molecular and physical characteristics of aerosol at a remote free troposphere site: implications for atmospheric aging journal January 2018
Volatility and Viscosity Are Correlated in Terpene Secondary Organic Aerosol Formed in a Flow Reactor journal August 2019
Humidity-dependent phase state of SOA particles from biogenic and anthropogenic precursors journal January 2012
Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions journal January 2020
Global combustion sources of organic aerosols: model comparison with 84 AMS factor-analysis data sets journal January 2016
Model of Emissions of Gases and Aerosol from Nature Version 3 (MEGAN3) for Estimating Biogenic Emissions book November 2019
Relative humidity-dependent viscosities of isoprene-derived secondary organic material and atmospheric implications for isoprene-dominant forests journal January 2015
Effects of Molecular-Level Compositional Variability in Organic Aerosol on Phase State and Thermodynamic Mixing Behavior journal September 2019
Sub-micrometre particulate matter is primarily in liquid form over Amazon rainforest journal December 2015
Mixing of secondary organic aerosols versus relative humidity journal October 2016
Phase state of ambient aerosol linked with water uptake and chemical aging in the southeastern US journal January 2016
Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest journal January 2017
Speculations on the movement of polluted air to the Arctic journal January 1981
The Saharan Aerosol Long-Range Transport and Aerosol–Cloud-Interaction Experiment: Overview and Selected Highlights journal July 2017
Aerosol particles at a high-altitude site on the Southeast Tibetan Plateau, China: Implications for pollution transport from South Asia: AEROSOL PARTICLES IN SOUTHEAST TP journal October 2013
Synergy between Secondary Organic Aerosols and Long-Range Transport of Polycyclic Aromatic Hydrocarbons journal November 2012
Temperature effect on phase state and reactivity controls atmospheric multiphase chemistry and transport of PAHs journal March 2018
Global long-range transport and lung cancer risk from polycyclic aromatic hydrocarbons shielded by coatings of organic aerosol journal January 2017
Assessing the Influence of Secondary Organic versus Primary Carbonaceous Aerosols on Long-Range Atmospheric Polycyclic Aromatic Hydrocarbon Transport journal March 2014
Climate Change Effects on Secondary Compounds of Forest Trees in the Northern Hemisphere journal October 2018
Amplification of plant volatile defence against insect herbivory in a warming Arctic tundra journal June 2019
Heat Waves Change Plant Carbon Allocation Among Primary and Secondary Metabolism Altering CO2 Assimilation, Respiration, and VOC Emissions journal August 2020
Testing various mixing rules for calculation of viscosity of petroleum blends journal December 2011
Comparison of Approaches for Measuring and Predicting the Viscosity of Ternary Component Aerosol Particles journal February 2019
Measurements and Predictions of Binary Component Aerosol Particle Viscosity journal October 2016
Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles journal October 2019
Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties journal June 2019
Hygroscopic properties of aerosol particles at high relative humidity and their diurnal variations in the North China Plain journal January 2011
Diurnal variations of cloud and relative humidity profiles across the tropics journal November 2019
Diurnal variation of upper tropospheric humidity and its relations to convective activities over tropical Africa journal January 2007
Diurnal Variation in the Troposphere's Energy Balance journal August 1979