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Kinetics of Propylene Epoxidation over Extracrystalline Gold Active Sites on AU/TS-1 Catalysts

Journal Article · · ACS Catalysis
 [1];  [2];  [2];  [3];  [3];  [4]
  1. Charles D. Davidson School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, Indiana 47907, United States; OSTI
  2. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States
  3. Charles D. Davidson School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, Indiana 47907, United States
  4. Department of Chemical and Biological Engineering, The University of Alabama, 3043 H. M. Comer Hall, 245 7th Avenue, Tuscaloosa, Alabama 35487, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Purdue Univ., West Lafayette, IN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-03ER15408
OSTI ID:
1978318
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 16 Vol. 12; ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (50)

Gold Stability and Diffusion in the Au/TS-1 Catalyst journal February 2021
Vapor-Phase Epoxidation of Propene Using H2 and O2 over Au/Ti–MCM-48 journal July 2002
Manipulating Gold Spatial Location on Titanium Silicalite-1 To Enhance the Catalytic Performance for Direct Propene Epoxidation with H 2 and O 2 journal September 2018
Synthesis, characterization, and function of Au nanoparticles within TS-1 zeotypes as catalysts for alkene epoxidation using O2/H2O reactants journal June 2022
The statistics of surface atoms and surface sites on metal crystals journal June 1969
Catalysis at Metal/Oxide Interfaces: Density Functional Theory and Microkinetic Modeling of Water Gas Shift at Pt/MgO Boundaries journal April 2020
Propylene oxide inhibits propylene epoxidation over Au/TS-1 journal September 2018
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects journal April 2010
X-Ray Diffraction and Small Angle X-Ray Scattering book April 2012
Colloidal Gold Nanoparticles as Catalyst for Carbon−Carbon Bond Formation:  Application to Aerobic Homocoupling of Phenylboronic Acid in Water journal December 2004
Optical properties and electronic structure of amorphous Ge and Si journal January 1968
Effects of Hydrogen on the Reactivity of O 2 toward Gold Nanoparticles and Surfaces journal December 2007
Reaction kinetic analysis of the gas-phase epoxidation of propylene over Au/TS-1 journal August 2006
Gold clusters supported on alkaline treated TS-1 for highly efficient propene epoxidation with O2 and H2 journal April 2010
Switching of reactions between hydrogenation and epoxidation of propene over Au/Ti-based oxides in the presence of H2 and O2 journal July 2011
Preparation of Ferrite MFe2O4 (M = Co, Ni) Ribbons with Nanoporous Structure and Their Magnetic Properties journal August 2008
Understanding Polymorphic Phase Transformation Behavior during Growth of Nanocrystalline Aggregates:  Insights from TiO 2 journal April 2000
Synthesis, characterization and catalytic performance of titanium silicalite-1 prepared in micellar media journal July 2002
Particle Size Effects in the Catalytic Electroreduction of CO 2 on Cu Nanoparticles journal May 2014
Decomposition of Hydrogen Peroxide Vapor on Relatively Inert Surfaces journal July 1957
Kinetics of propylene epoxidation using H2 and O2 over a gold/mesoporous titanosilicate catalyst journal May 2007
CO Oxidation on Supported Single Pt Atoms: Experimental and ab Initio Density Functional Studies of CO Interaction with Pt Atom on θ-Al 2 O 3 (010) Surface journal August 2013
Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis journal October 2010
Selective oxidation of propylene over gold deposited on titanium-based oxides journal March 1998
Catalytically active Au-O(OH) x - species stabilized by alkali ions on zeolites and mesoporous oxides journal November 2014
A study of interaction between hydrogen peroxide and silica gel by FTIR spectroscopy and quantum chemistry journal August 2006
Propylene Oxide book October 2012
Effect of composition and promoters in Au/TS-1 catalysts for direct propylene epoxidation using H2 and O2 journal October 2009
Titanium-Beta Zeolites Catalyze the Stereospecific Isomerization of d -Glucose to l -Sorbose via Intramolecular C5–C1 Hydride Shift journal June 2013
Hydrogen-Promoted Oxygen Activation by Free Gold Cluster Cations journal July 2009
The Production of Propene Oxide:  Catalytic Processes and Recent Developments journal May 2006
Selective Propene Epoxidation on Immobilized Au 6-10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity journal February 2009
Properties of adsorbed oxygen on Au/SiO2 journal September 1998
Raman Investigation of Nanosized TiO 2 : Effect of Crystallite Size and Quantum Confinement journal April 2012
Direct propylene epoxidation over barium-promoted Au/Ti-TUD catalysts with H2 and O2: Effect of Au particle size journal September 2007
Epoxidation of propylene with H2 and O2 in the explosive regime in a packed-bed catalytic membrane reactor journal July 2008
Selective Vapor-Phase Epoxidation of Propylene over Au/TiO2Catalysts in the Presence of Oxygen and Hydrogen journal September 1998
The effect of T-atom ratio and TPAOH concentration on the pore structure and titanium position in MFI-Type titanosilicate during dissolution-recrystallization process journal October 2020
Insights into size-dependent activity and active sites of Au nanoparticles supported on TS-1 for propene epoxidation with H2 and O2 journal August 2014
Enhanced reaction rate for gas-phase epoxidation of propylene using H2 and O2 by Cs promotion of Au/TS-1 journal December 2013
Thermophysical and transport properties of humid air at temperature range between 0 and 100°C journal May 2008
Optical Properties and Electronic Structure of Amorphous Germanium journal January 1966
Synthesis and characterization of Ti-MCM-41 and vapor-phase epoxidation of propylene using H2 and O2 over Au/Ti-MCM-41 journal July 2001
Kinetic Study of a Direct Water Synthesis over Silica-Supported Gold Nanoparticles † journal February 2005
Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors journal November 1970
Three-Dimensional Mesoporous Titanosilicates Prepared by Modified Sol−Gel Method:  Ideal Gold Catalyst Supports for Enhanced Propene Epoxidation journal March 2005
Size-Specific Catalytic Activity of Polymer-Stabilized Gold Nanoclusters for Aerobic Alcohol Oxidation in Water journal July 2005
Reproducible preparation of Au/TS-1 with high reaction rate for gas phase epoxidation of propylene journal March 2012
Probing the gold active sites in Au/TS-1 for gas-phase epoxidation of propylene in the presence of hydrogen and oxygen journal December 2012
A Common Single-Site Pt(II)–O(OH) x – Species Stabilized by Sodium on “Active” and “Inert” Supports Catalyzes the Water-Gas Shift Reaction journal March 2015

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Chemistry