Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Enhancing the Ionic Conductivity of Poly(3,4-propylenedioxythiophenes) with Oligoether Side Chains for Use as Conductive Cathode Binders in Lithium-Ion Batteries

Journal Article · · Chemistry of Materials
 [1];  [2];  [2];  [3];  [4];  [5];  [6];  [5];  [4];  [7];  [2];  [2]
  1. Department of Chemistry and Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, California 90089-1661, United States; OSTI
  2. Department of Chemistry and Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, California 90089-1661, United States
  3. Department of Chemistry and Biochemistry, UCLA, Los Angeles, California 90095-1569, United States
  4. Department of Chemical Engineering, University of California at Santa Barbara, Santa Barbara, California 93106, United States
  5. Department of Materials Science and Engineering, UCLA, Los Angeles, California 90095, United States
  6. Materials Department, University of California, Santa Barbara, California 93106, United States
  7. Department of Chemistry and Biochemistry, UCLA, Los Angeles, California 90095-1569, United States; Department of Materials Science and Engineering, UCLA, Los Angeles, California 90095, United States
Not provided.
Research Organization:
Univ. of California, Los Angeles, CA (United States); Stanford Univ., CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019381; AC02-76SF00515
OSTI ID:
1977794
Journal Information:
Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 6 Vol. 34; ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (90)

Efficient Transport Networks in a Dual Electron/Lithium-Conducting Polymeric Composite for Electrochemical Applications journal April 2018
Effect of PPy/PEG conducting polymer film on electrochemical performance of LiFePO4 cathode material for Li-ion batteries journal January 2013
Dependence of Cell Failure on Cut-Off Voltage Ranges and Observation of Kinetic Hindrance in LiNi 0.8 Co 0.15 Al 0.05 O 2 journal January 2018
UV-to-IR Absorption of Molecularly p-Doped Polythiophenes with Alkyl and Oligoether Side Chains: Experiment and Interpretation Based on Density Functional Theory journal November 2020
Conductivity and mixed conductivity of a novel dense diffusion barrier and the sensing properties of limiting current oxygen sensors journal January 2020
Poly(Ethylene Oxide)-based Electrolyte for Solid-State-Lithium-Batteries with High Voltage Positive Electrodes: Evaluating the Role of Electrolyte Oxidation in Rapid Cell Failure journal March 2020
The rational design of a redox-active mixed ion/electron conductor as a multi-functional binder for lithium-ion batteries journal January 2021
Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes journal September 2011
Achieving high energy density and high power density with pseudocapacitive materials journal October 2019
Replacing Alkyl with Oligo(ethylene glycol) as Side Chains of Conjugated Polymers for Close π–π Stacking journal June 2015
Concentration Gradient-Driven Aluminum Diffusion in a Single-Step Coprecipitation of a Compositionally Graded Precursor for LiNi 0.8 Co 0.135 Al 0.065 O 2 with Mitigated Irreversibility of H2 ↔ H3 Phase Transition journal July 2020
A non-volatile organic electrochemical device as a low-voltage artificial synapse for neuromorphic computing journal February 2017
Preparation and characterization of LiNi0.80Co0.20– x Al x O2 as cathode materials for lithium ion batteries journal December 2006
Degradation Mechanism of Ni-Enriched NCA Cathode for Lithium Batteries: Are Microcracks Really Critical? journal May 2019
Application of Poly(3-hexylthiophene-2,5-diyl) as a Protective Coating for High Rate Cathode Materials journal March 2018
Synergistic, ultrafast mass storage and removal in artificial mixed conductors journal August 2016
The Active Layer Morphology of Organic Solar Cells Probed with Grazing Incidence Scattering Techniques journal February 2014
In Situ Measurement of Ionic and Electronic Conductivities of Conductive Polymers as a Function of Electrochemical Doping in Battery Electrolytes journal March 2021
Balancing Charge Storage and Mobility in an Oligo(Ether) Functionalized Dioxythiophene Copolymer for Organic‐ and Aqueous‐ Based Electrochemical Devices and Transistors journal August 2018
Electronic, Ionic, and Mixed Conduction in Polymeric Systems journal July 2021
Doping-Induced Absorption Bands in P3HT: Polarons and Bipolarons journal October 2016
Morphological effects on polymeric mixed ionic/electronic conductors journal January 2019
Semi-random P3HT analogs via direct arylation polymerization
  • Rudenko, Andrey E.; Wiley, Calvin A.; Stone, Shiloh M.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 50, Issue 18, p. 3691-3697 https://doi.org/10.1002/pola.26175
journal June 2012
Effects of Nanoparticle Geometry and Size Distribution on Diffusion Impedance of Battery Electrodes journal November 2012
Influence of Side-Chain Chemistry on Structure and Ionic Conduction Characteristics of Polythiophene Derivatives: A Computational and Experimental Study journal February 2019
Self-Holding Optical Actuator Based on a Mixed Ionic–Electronic Conductor Material journal April 2019
A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes journal February 2016
Electronic control of Ca2+ signalling in neuronal cells using an organic electronic ion pump journal July 2007
Random Poly(3-hexylthiophene- co -3-cyanothiophene) Copolymers via Direct Arylation Polymerization (DArP) for Organic Solar Cells with High Open-Circuit Voltage journal March 2014
Role of Molecular Architecture on Ion Transport in Ethylene oxide-Based Polymer Electrolytes journal February 2021
Triple ionic–electronic conducting oxides for next-generation electrochemical devices journal December 2020
Toward an Ideal Polymer Binder Design for High-Capacity Battery Anodes journal July 2013
Dopant-Induced Ordering of Amorphous Regions in Regiorandom P3HT journal August 2019
Understanding the Role of π-Conjugated Polymers as Binders in Enabling Designs for High-Energy/High-Rate Lithium Metal Batteries journal November 2021
A Versatile Method to Fabricate Highly In-Plane Aligned Conducting Polymer Films with Anisotropic Charge Transport and Thermoelectric Properties: The Key Role of Alkyl Side Chain Layers on the Doping Mechanism journal May 2017
Controlling the Formation of Charge Transfer Complexes in Chemically Doped Semiconducting Polymers journal March 2021
Tuning Conjugated Polymers for Binder Applications in High-Capacity Magnetite Anodes journal September 2019
Low-Bandgap Near-IR Conjugated Polymers/Molecules for Organic Electronics journal August 2015
Redox States of Long Oligothiophenes: Two Polarons on a Single Chain journal August 1998
Electronic and Vibrational Spectra of Positive Polarons and Bipolarons in Regioregular Poly(3-hexylthiophene) Doped with Ferric Chloride journal March 2015
Side-Chain Conducting and Phase-Separated Polymeric Binders for High-Performance Silicon Anodes in Lithium-Ion Batteries journal February 2015
Charge storage on a conducting polymer in solution journal July 1989
Charge-Transfer Intermediates in the Electrochemical Doping Mechanism of Conjugated Polymers journal December 2020
The Effect of Alkyl Spacers on the Mixed Ionic‐Electronic Conduction Properties of N‐Type Polymers journal January 2021
π-Dimers and π-Stacks in Solution and in Conducting Polymers journal January 1996
Electron/Ion Transport Enhancer in High Capacity Li-Ion Battery Anodes journal September 2016
Simultaneous Conduction of Electronic Charge and Lithium Ions in Block Copolymers journal January 2012
Recent Advances in Conversion-Type Electrode Materials for Post Lithium-Ion Batteries journal June 2021
Coupling of ion and electron transport during impedance measurements on a conducting polymer with similar ionic and electronic conductivities journal January 1993
Material and Structural Design of Novel Binder Systems for High-Energy, High-Power Lithium-Ion Batteries journal October 2017
Charge-Transfer Modeling and Polarization DRT Analysis of Proton Ceramics Fuel Cells Based on Mixed Conductive Electrolyte with the Modified Anode–Electrolyte Interface journal September 2018
Connecting Structural and Transport Properties of Ionic Liquids with Cationic Oligoether Chains journal January 2017
Solid-State Lithium-Sulfur Battery Based on Composite Electrode and Bi-layer Solid Electrolyte Operable at Room Temperature journal November 2020
Regiosymmetric Dibutyl-Substituted Poly(3,4-propylenedioxythiophene)s as Highly Electron-Rich Electroactive and Luminescent Polymers journal June 2002
Ionic and Electronic Conductivity of Poly‐(3‐methylpyrrole‐4‐carboxylic Acid) journal August 1992
Recent Advances of Mesoscale-Structured Cathode Materials for High Energy Density Lithium-Ion Batteries journal April 2021
Networks of Electron-Conducting Polymer in Matrices of Ion-Conducting Polymers Applications to Fast Electrodes journal January 1999
Capacity Fading of Ni-Rich Li[Ni x Co y Mn 1– xy ]O 2 (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? journal January 2018
Ethylene Glycol-Based Side Chain Length Engineering in Polythiophenes and its Impact on Organic Electrochemical Transistor Performance journal July 2020
Recent advances in developing organic electrode materials for multivalent rechargeable batteries journal January 2020
n ‐Type Rigid Semiconducting Polymers Bearing Oligo(Ethylene Glycol) Side Chains for High‐Performance Organic Electrochemical Transistors journal March 2021
Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability journal August 2020
First-order transition to a metallic state in polyacetylene: A strong-coupling polaronic metal journal July 1985
The role of structural and electronic alterations on the lithium diffusion in LixCo0.5Ni0.5O2 journal August 2004
Bipolaron transport in doped conjugated polymers journal April 1984
Batteries and charge storage devices based on electronically conducting polymers journal August 2010
Carboxylated Poly(thiophene) Binders for High-Performance Magnetite Anodes: Impact of Cation Structure journal November 2019
Dihexyl-Substituted Poly(3,4-Propylenedioxythiophene) as a Dual Ionic and Electronic Conductive Cathode Binder for Lithium-Ion Batteries journal October 2020
Mixed Conduction Membranes Suppress the Polysulfide Shuttle in Lithium-Sulfur Batteries journal January 2017
Enhanced Ion Conductivity in Conducting Polymer Binder for High-Performance Silicon Anodes in Advanced Lithium-Ion Batteries journal January 2018
Improving the efficiency and sustainability of catalysts for direct arylation polymerization (DArP) journal September 2021
Doping-induced change of carrier mobilities in poly(3-hexylthiophene) films with different stacking structures journal October 2002
Organic mixed ionic–electronic conductors journal August 2019
A Conductive Binder for High-Performance Sn Electrodes in Lithium-Ion Batteries journal January 2018
Structural control of mixed ionic and electronic transport in conducting polymers journal April 2016
Mixed Ionic-Electronic Transport in Polymers journal July 2021
Review—Conducting Polymer-Based Binders for Lithium-Ion Batteries and Beyond journal January 2020
Conducting Poly(3,4-alkylenedioxythiophene) Derivatives as Fast Electrochromics with High-Contrast Ratios journal February 1998
Diketopyrrolopyrrole-based Conjugated Polymers Bearing Branched Oligo(Ethylene Glycol) Side Chains for Photovoltaic Devices journal June 2016
The chemical and structural origin of efficient p-type doping in P3HT journal May 2013
Role of solvation site segmental dynamics on ion transport in ethylene-oxide based side-chain polymer electrolytes journal January 2021
The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films journal September 2017
Redox-Active Polypyrrole: Toward Polymer-Based Batteries journal July 2006
Enhanced Cyclability of Lithium–Sulfur Batteries by a Polymer Acid-Doped Polypyrrole Mixed Ionic–Electronic Conductor journal August 2012
Capacity Fading of Ni-Rich NCA Cathodes: Effect of Microcracking Extent journal October 2019
Fundamentals of Materials Selection for Light‐Emitting Electrochemical Cells journal March 2020
Spray Coatable Electrochromic Dioxythiophene Polymers with High Coloration Efficiencies journal September 2004
Approaches for improving the sustainability of conjugated polymer synthesis using direct arylation polymerization (DArP) journal January 2020
Mixed Electronic and Ionic Conduction Properties of Lithium Lanthanum Titanate journal January 2020
Structural, Optical, and Electronic Properties of a Series of 3,4-Propylenedioxythiophene Oligomers in Neutral and Various Oxidation States journal June 2011

Similar Records

Related Subjects